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arXiv:2507.10471 · SciPost Physics

Resonating valence bond ground states on corner-sharing simplices

Zhao Zhang, Cecilie Glittum

Published Apr 29, 2026• 0 citations
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Abstract

The Hubbard model in the U\to∞ U → ∞ limit has been known to have resonating valence bond (RVB) ground states on certain corner-sharing simplex lattices. Examples include both the quasi-1D sawtooth lattice with open boundary and a larger class of higher dimensional lattices without boundaries. The two types of results were obtained by different approaches which do not apply to one another. In the second class of lattices, the simplest simplex is a tetrahedron. We hereby generalize both results by studying the singly hole-doped system on the quasi-1D lattice of a tetrahedron chain, which can be considered a stripe of the pyrochlore or checkerboard lattices. The energy level ordering of irreducible representations of each tetrahedron shows that a chain of them has exponentially degenerate partial RVB or dimer-monomer ground states where each tetrahedron hosts one spin- 1/2 1 / 2 monomer and one spin- 0 0 dimer. The exact ground states in the infinitely long chain limit are analytically solved by introducing basis transformations between local Hilbert spaces of neighboring tetrahedra, and its energy agrees with the extrapolation of numerical exact diagonalization results of finite sized systems.

DOI
10.21468/scipostphys.20.4.121

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The Hubbard model in the U\to∞ U → ∞ limit has been known to have resonating valence bond (RVB) ground states on certain corner-sharing simplex lattices. Examples include both the quasi-1D sawtooth lattice with open boundary and a larger class of higher dimensional lattices without boundaries. The two types of results were obtained by different approaches which do not apply to one another. In the second class of lattices, the simplest simplex is a tetrahedron. We hereby generalize both results by studying the singly hole-doped system on the quasi-1D lattice of a tetrahedron chain, which can be considered a stripe of the pyrochlore or checkerboard lattices. The energy level ordering of irreducible representations of each tetrahedron shows that a chain of them has exponentially degenerate partial RVB or dimer-monomer ground states where each tetrahedron hosts one spin- 1/2 1 / 2 monomer and one spin- 0 0 dimer. The exact ground states in the infinitely long chain limit are analytically solved by introducing basis transformations between local Hilbert spaces of neighboring tetrahedra, and its energy agrees with the extrapolation of numerical exact diagonalization results of finite sized systems.
We have calculated the energy of the resonating-valence-bond (RVB) state made of nearest-neighbor singlet pairs in the two-dimensional Hubbard model at half filling and the energy of holes in the RVB state near half filling. The energy of the RVB state was obtained by extrapolating the result in a 6\ifmmode\times\else\texttimes\fi{}6 square lattice with the periodic boundary condition to the infinite lattice. The energy of holes was obtained by examining the first five moments of the density of states of holes in the RVB state. We find that the holes are more stabilized in the RVB state than in the N\'eel state for J/t\ensuremath{\gtrsim}0.1, where J and t are the exchange interaction and the nearest-neighbor hopping integral, respectively. We discuss the possibility of the RVB state in the high-Tc{T}_{c}Tc​ Cu oxides.
A fully variational resonance-valence-bond (RVB) study is performed for two-, three- and four-legged isotropic spin-1/2 Heisenberg ladders under periodic boundary conditions along the rungs and periodic/twisted boundary conditions along the chains. By using the full lattice groups of these systems very accurate results have been obtained for the ground-state bulk limit properties in the case of the dimer RVB basis. The results reported here represent the best one can do within the dimer RVB ansatz and should be useful when comparing with results obtained from an a priori fixed structure of the wavefunction. Further results are presented for some finite-sized systems, extending beyond the dimer RVB approach by including RVB functions containing spin pairings between non-nearest-neighbour sites. These results indicate that the three-legged ladder with periodic boundary conditions along the rungs falls into the same universality class of ladders possessing short-range RVB wavefunctions as the two- and four-legged ladders.
An antiferromagnetic spin model (S=1/2) consisting of a chain of octahedra is considered. In a certain parameter regime of the Hamiltonian the exact ground state is a local resonating-valence-bond (RVB) state. We start with the t-J Hamiltonian for this model describing a single hole in the system and derive exact ground and excited states of the Hamiltonian when the hole is static. The local spin distortion around a hole is termed a spin polaron. The dynamics of the hole is studied through construction of exact eigenstates describing spin polarons in extended states. Coherent states for all momentum wave vectors in the chain direction exist for certain spin polarons. In the Nagaoka limit, the RVB polaronic states have energy greater than that of the ferromagnetic state. For exchange interaction J\ensuremath{\ne}0, the RVB states have lower energy. Other exact states obtained include states in which the hole motion is localized. Structural similarity of the present model to the arrangement of Cu spins in La2{\mathrm{La}}_{2}La2​CuO4{\mathrm{CuO}}_{4}CuO4​ is also highlighted.
Resonating valence bond (RVB) states are fundamental for understanding quantum spin liquids in two-dimensional (2D) systems. The RVB state is a collective phenomenon in which spins are uncoupled. 2D lattices such as triangular, honeycomb, and dice lattices were investigated using the Hubbard model and exact diagonalization method. We analyzed the total spin, spin-spin correlation functions, local magnetic moments, and spin and charge gaps as a function of on-site Coulomb repulsion, electron concentration, and electronic hopping parameters. Phase diagrams showed that RVB states can live in half-filled and hole-doped anisotropic triangular lattices. We found two types of RVB states: one in the honeycomb sublattice and the other in the centered hexagons in the triangular lattices. Owing to the novel discovery of exotic magnetic ordering in triangular moiré patterns in twisted bilayer graphene and transition metal dichalcogenide systems, our results provide physical insights into the onset of magnetism and possible spin liquid states in these layered materials.
We study resonating-valence-bond (RVB) states on the square lattice of spins and of dimers, as well as SU ( N )-invariant states that interpolate between the two. These states are ground states of gapless models, although the SU (2)-invariant spin RVB state is also believed to be a gapped liquid in its spinful sector. We show that the gapless behavior in spin and dimer RVB states is qualitatively similar by studying the Rényi entropy for splitting a torus into two cylinders. We compute this exactly for dimers, showing it behaves similarly to the familiar one-dimensional log term, although not identically. We extend the exact computation to an effective theory believed to interpolate among these states. By numerical calculations for the SU (2) RVB state and its SU ( N )-invariant generalizations, we provide further support for this belief. We also show how the entanglement entropy behaves qualitatively differently for different values of the Rényi index n , with large values of n proving a more sensitive probe here, by virtue of exhibiting a striking even/odd effect.