Thermal engines have been one of the principal topics of thermodynamics ever since its beginning. Today, in the era of the second quantum revolution, although the thermal processes in constant temperatures are relatively well understood in the language of resource theories, a framework to describe thermal engines is still in its infancy. In this work we formalize the resource theory of engines, initially put forward in~\cite{KAMIL}, and define such quantities as engine efficiency. Then, we turn to a detailed study of thermal engines based on free operations arising from the resource theory of athermality under different restrictions: thermal operation, semilocal thermal operations and local thermal operation with classical communication. In order to provide analytic lower bounds for thermal engine operation we construct tree-states -- free states, which can be obtained from Gibbs state in simple protocol consisting solely of two-level operations. Furthermore, we derive a full description of the engine based on semilocal thermal operations by describing free states, faithful monotones and catalytic advantages.
Thermal engines have been one of the principal topics of thermodynamics ever since its beginning. Today, in the era of the second quantum revolution, although the thermal processes in constant temperatures are relatively well understood in the language of resource theories, a framework to describe thermal engines is still in its infancy. In this work we formalize the resource theory of engines, initially put forward in~\cite{KAMIL}, and define such quantities as engine efficiency. Then, we turn to a detailed study of thermal engines based on free operations arising from the resource theory of athermality under different restrictions: thermal operation, semilocal thermal operations and local thermal operation with classical communication. In order to provide analytic lower bounds for thermal engine operation we construct tree-states -- free states, which can be obtained from Gibbs state in simple protocol consisting solely of two-level operations. Furthermore, we derive a full description of the engine based on semilocal thermal operations by describing free states, faithful monotones and catalytic advantages.
Thermal engines have been one of the principal topics of thermodynamics ever since its beginning. Today, in the era of the second quantum revolution, although the thermal processes in constant temperatures are relatively well understood in the language of resource theories, a framework to describe thermal engines is still in its infancy. In this work we formalize the resource theory of engines, initially put forward in [Quantum 8, 1222 (2024)], and define such quantities as engine efficiency. Then we turn to a detailed study of thermal engines based on free operations arising from the resource theory of athermality under different restrictions: thermal operation, semilocal thermal operations, and local thermal operation with classical communication. In order to provide analytic lower bounds for thermal engine operation we construct tree states—free states which can be obtained from Gibbs state in simple protocol consisting solely of two-level operations. Furthermore, we derive a full description of the engine based on semilocal thermal operations by describing free states, faithful monotones, and catalytic advantages.
Thermodynamics is one of the main pillars of theoretical physics, and it has a special appeal of having wide applicability to a large variety of different physical systems. However, many assumptions in thermodynamics apply only to systems which are bulk material, i.e. consisting a large number of microscopic classical particles. Due to the advancement of designing nanoscale engines, especially in the light of devices that are used today in the processing of quantum information, is thermodynamics still applicable? Can we refine the core principles of thermodynamics to suit such nanoscale quantum systems as well? The central aim of this thesis is to construct a theory of thermodynamics that holds for nanoscale quantum systems, even those as small and simple as a single qubit. We do this by starting out from the core basics of quantum theory: unitary dynamics on closed quantum systems. We adapt a resource theoretic approach inspired by quantum information theory, which defines the quantum states and operations allowed to be used in a thermodynamic evolution. With this framework that naturally adopts the first law as an energy preserving condition, we show the refinement of both the zeroeth and second law of thermodynamics. The zeroeth law explains the physical significance of the Gibbs thermal state. On the other hand, we show that the second law sees refinement in the quantum nanoregime: instead of having the free energy as the sole quantity dictating the possibility of a thermodynamic state transition, we derive a family of generalized free energies that also constitute necessary conditions for a transition to occur. Moreover, these conditions become sufficient for states which are block-diagonal in the energy eigenbasis. In this thesis, we also brought our approach of thermodynamics to the next step: we apply our findings on the second laws, in order to analyze the maximum achievable efficiency for quantum heat engines. In classical thermodynamics, the Carnot efficiency has been long known as the theoretical maximum which does not depend on the specific structure of the thermal baths used, but only on its temperature. With the additional free energies we discover, we show that although quantum heat engines may achieve the Carnot efficiency, such an achievability is no longer independent of the Hamiltonians of the thermal baths. In other words, we find additional restrictions that surface in the study of quantum nanoscale heat engines, which are a direct consequence of the generalized second laws. This has provided us with a deeper understanding into the fundamental limitations of how efficient devices can be made in the realm of microscopic quantum systems.
Chapter 17 delves into quantum thermodynamics, building on the concepts introduced in the resource theory of nonuniformity. This chapter focuses on thermal states and athermality as resources within the quantum domain, emphasizing the significance of Gibbs states and their role in quantum statistical mechanics. It outlines the operational framework for thermal operations, setting the stage for discussions on energy conservation and the second law of thermodynamics in quantum systems. A key aspect of the chapter is the exploration of quasi-classical athermality, illustrating how quantum states deviate from thermal equilibrium when the state of the system commutes with its Hamiltonian. In the fully quantum domain, the chapter introduces closed formulas for quantifying athermality, such as the athermality cost and distillable athermality, both in the single-shot and the asymptotic domains. These measures provide a quantitative understanding of the efficiency of thermal operations and the potential for work extraction or consumption.
In this paper we aim to push the analogy between thermodynamics and quantum resource theories one step further. Previous inspirations were based predominantly on thermodynamic considerations concerning scenarios with a single heat bath, neglecting an important part of thermodynamics that studies heat engines operating between two baths at different temperatures. Here, we investigate the performance of resource engines, which replace the access to two heat baths at different temperatures with two arbitrary constraints on state transformations. The idea is to imitate the action of a two–stroke heat engine, where the system is sent to two agents (Alice and Bob) in turns, and they can transform it using their constrained sets of free operations. We raise and address several questions, including whether or not a resource engine can generate a full set of quantum operations or all possible state transformations, and how many strokes are needed for that. We also explain how the resource engine picture provides a natural way to fuse two or more resource theories, and we discuss in detail the fusion of two resource theories of thermodynamics with two different temperatures, and two resource theories of coherence with respect to two different bases.
The resource theory of thermal operations explains the state transformations that are possible in a very specific thermodynamic setting: there is only one thermal bath, auxiliary systems can only be in the corresponding thermal state (free states), and the interaction must commute with the free Hamiltonian (free operation). In this paper we study the mildest deviation: the reservoir particles are subject to inhomogeneities, either in the local temperature (introducing resource states) or in the local Hamiltonian (generating a resource operation). For small inhomogeneities, the two models generate the same channel and thus the same state transformations. However, their thermodynamics is significantly different when it comes to work generation or to the interpretation of the ``second laws of thermal operations.''
What are the fundamental limits and advantages of using a catalyst to aid thermodynamic transformations between quantum systems? In this paper, we answer this question by focusing on transformations between energy-incoherent states under the most general energy-conserving interactions among the system, the catalyst, and a thermal environment. The sole constraint is that the catalyst must return unperturbed and uncorrelated with the other subsystems. More precisely, we first upper bound the set of states to which a given initial state can thermodynamically evolve (the catalyzable future) or from which it can evolve (the catalyzable past) with the help of a strict catalyst. Secondly, we derive lower bounds on the dimensionality required for the existence of catalysts under thermal process, along with bounds on the catalyst's state preparation. Finally, we quantify the catalytic advantage in terms of the volume of the catalyzable future and demonstrate its utility in an exemplary task of generating entanglement and cooling a quantum system using thermal resources. Published by the American Physical Society 2024