Quantum coherence, encoded in the off-diagonal elements of a system's density matrix, is a key resource in quantum thermodynamics, fundamentally limiting the maximum extractable work known as ergotropy. While previous experiments have isolated coherence-related contributions to work extraction, it remains unclear how coherence can be harnessed in a controllable and energy-efficient manner. Here, we experimentally investigate the role of initial-state coherence in work extraction from a superconducting transmon qubit. By preparing a variety of pure states and implementing three complementary extraction protocols, we reveal how coherence governs the partitioning of ergotropy. We find that the choice of initial state depends on the dominant decoherence channel-energy relaxation or dephasing. By further accounting for thermodynamic costs, we identify optimal initial states that maximize the efficiency. Our results demonstrate that the initial-state design provides a scalable approach to coherence control and advances the development of efficient quantum thermodynamic devices.
Quantum coherence, encoded in the off-diagonal elements of a system's density matrix, is a key resource in quantum thermodynamics, fundamentally limiting the maximum extractable work known as ergotropy. While previous experiments have isolated coherence-related contributions to work extraction, it remains unclear how coherence can be harnessed in a controllable and energy-efficient manner. Here, we experimentally investigate the role of initial-state coherence in work extraction from a superconducting transmon qubit. By preparing a variety of pure states and implementing three complementary extraction protocols, we reveal how coherence governs the partitioning of ergotropy. We find that the choice of initial state depends on the dominant decoherence channel-energy relaxation or dephasing. By further accounting for thermodynamic costs, we identify optimal initial states that maximize the efficiency. Our results demonstrate that the initial-state design provides a scalable approach to coherence control and advances the development of efficient quantum thermodynamic devices.
Constraints on work extraction are fundamental to our operational understanding of the thermodynamics of both classical and quantum systems. In the quantum setting, finite-time control operations typically generate coherence in the instantaneous energy eigenbasis of the dynamical system. Thermodynamic cycles can, in principle, be designed to extract work from this nonequilibrium resource. Here, we isolate and study the quantum coherent component to the work yield in such protocols. Specifically, we identify a coherent contribution to the ergotropy (the maximum amount of unitarily extractable work via cyclical variation of Hamiltonian parameters). We show this by dividing the optimal transformation into an incoherent operation and a coherence extraction cycle. We obtain bounds for both the coherent and incoherent parts of the extractable work and discuss their saturation in specific settings. Our results are illustrated with several examples, including finite-dimensional systems and bosonic Gaussian states that describe recent experiments on quantum heat engines with a quantized load.
The amount of extractable work from a physical system is fundamentally connected to the information available about its state, as illustrated by Maxwell's demon and the Gibbs paradox. In standard thermodynamic protocols involving system--bath interactions, the maximum work is given by the free-energy difference between the initial state and the corresponding Gibbs state at the bath temperature. This motivates a natural question: does information also limit work extraction in closed quantum systems that do not involve a heat bath and where work is obtained through unitary operations generated by a time-dependent Hamiltonian? While ergotropy quantifies the maximum work extractable via unitary operations, it assumes complete knowledge of the quantum state, typically requiring full state tomography. In realistic scenarios, however, only partial information is accessible. In this case, the relevant figure of merit is observational ergotropy, which depends explicitly on the measurement used to probe the system. We show that observational ergotropy decreases under classical post-processing of measurement outcomes, implying that fine-grained measurements allow greater work extraction than coarse-grained ones. Moreover, maximizing observational ergotropy over all possible measurements recovers standard ergotropy, which decomposes into incoherent (classical) and coherent (quantum) contributions. Our results demonstrate that coherence in the measurement projectors constitutes the key resource, enabling work extraction beyond the incoherent limit and establishing coherence as the origin of quantum advantage in observational ergotropy extraction.
Ergotropy is defined as the maximum amount of work that can be extracted through a unitary cyclic evolution. It plays a crucial role in assessing the work capacity of a quantum system. Recently, the significance of quantum coherence in work extraction has been theoretically identified, revealing that quantum states with more coherence possess more ergotropy compared to their dephased counterparts. However, an experimental study of the coherent ergotropy remains absent. Here, we report an experimental investigation of the coherent ergotropy in a single spin system. Based on the method of measuring ergotropy with an ancilla qubit, both the coherent and incoherent components of the ergotropy for the nonequilibrium state were successfully extracted. The increase in ergotropy induced by the increase in the coherence of the system was observed by varying the coherence of the state. Our work reveals the interplay between quantum thermodynamics and quantum information theory, future investigations could further explore the role other quantum attributes play in thermodynamic protocols.
We analyze the geometric phase and dynamic phase acquired by a qubit coupled to an environment through pure dephasing, establishing a direct connection between phase accumulation and ergotropy. We show that the dynamic phase depends solely on the incoherent ergotropy, reflecting its purely energetic origin. In contrast, the geometric phase exhibits a nontrivial dependence on both the coherent and incoherent contributions to the total ergotropy, encoding the interplay between coherence, dissipation, and energy extraction. By performing a perturbative expansion in the qubit-environment coupling strength, we demonstrate that, in the weak-coupling and long-time regime, the geometric phase becomes determined exclusively by the incoherent ergotropy, which coincides with the asymptotic value of the total ergotropy reached under decoherence. These results provide a clear physical distinction between dynamic and geometric phases in open quantum systems and establish geometric phases as sensitive probes of energetic resources. Furthermore,~in superconducting circuit implementations, our findings suggest that the ergotropy of a two-level system could be inferred indirectly from geometric-phase measurements using standard techniques such as quantum state tomography.
We investigate the decomposition of ergotropy into incoherent and coherent contributions for quantum systems subject to typical Markovian noise channels. The incoherent part originates from population inversion in the energy eigenbasis after dephasing, while the coherent part captures the role of quantum coherence in work extraction. For single-qubit systems, we derive explicit conditions for freezing and enhancement of coherent ergotropy and obtain an analytical upper bound, showing that it cannot exceed one half of the state's quantum coherence. We then study two classes of separable two-qubit states under local noise. For Bell-diagonal states, which are locally completely passive and possess no local coherence, we prove that the total extractable work equals the average of geometric quantum and classical correlations. In this case, coherent ergotropy cannot be enhanced, although freezing occurs under specific noise conditions. By contrast, for separable states with local coherence, coherent ergotropy can increase under all considered noise channels, including phase-flip and depolarizing noise. Extending the analysis to multipartite systems, we show that both the magnitude and range of noise-induced enhancement grow with the number of qubits, indicating collective reinforcement. Finally, we demonstrate through an explicit example that entanglement does not prevent this enhancement: coherent ergotropy may increase under noise even for entangled states. Our results reveal that noise can assist energy storage, challenging the conventional view of noise as purely detrimental and suggesting compatibility between noise-assisted enhancement and fast entanglement-based charging mechanisms in quantum batteries.
We analyze the geometric phase and dynamic phase acquired by a qubit coupled to an environment through pure dephasing, establishing a direct connection between phase accumulation and ergotropy. We show that the dynamic phase depends solely on the incoherent ergotropy, reflecting its purely energetic origin. In contrast, the geometric phase exhibits a nontrivial dependence on both the coherent and incoherent contributions to the total ergotropy, encoding the interplay between coherence, dissipation, and energy extraction. By performing a perturbative expansion in the qubit–environment coupling strength, we demonstrate that, in the weak-coupling and long-time regime, the geometric phase becomes determined exclusively by the incoherent ergotropy, which coincides with the asymptotic value of the total ergotropy reached under decoherence. These results provide a clear physical distinction between dynamic and geometric phases in open quantum systems and establish geometric phases as sensitive probes of energetic resources. Furthermore, in superconducting circuit implementations, our findings suggest that the ergotropy of a two-level system could be inferred indirectly from geometric-phase measurements using standard techniques such as quantum state tomography.