We investigate the role of a statistical complexity measure to assign equilibration in isolated quantum systems. While unitary dynamics preserve global purity, expectation values of observables often exhibit equilibration-like behavior, raising the question of whether a measure of complexity can track this process. In addition to examining observable equilibration, we extend our analysis to study how the complexity of the quantum states evolves, providing insight into the transition from initial coherence to equilibrium. We define a classical statistical complexity measure based on observable entropy and deviation from equilibrium, which captures the dynamical progression towards equilibration and effectively distinguishes between complex and non-complex trajectories. In particular, our measure is sensitive to non-complex dynamics. Such dynamics include the quasi-periodic behavior exhibited by low-dimensional initial states, where the system explores a limited region of Hilbert space while preserving coherence. Numerical simulations of an Ising-like non-integrable Hamiltonian spin-chain model support these findings. Our work provides new insight into the emergence of equilibrium behavior from unitary dynamics and advances complexity as a meaningful tool in the study of the emergence of classicality in microscopic systems.
We investigate the role of a statistical complexity measure to assign equilibration in isolated quantum systems. While unitary dynamics preserve global purity, expectation values of observables often exhibit equilibration-like behavior, raising the question of whether a measure of complexity can track this process. In addition to examining observable equilibration, we extend our analysis to study how the complexity of the quantum states evolves, providing insight into the transition from initial coherence to equilibrium. We define a classical statistical complexity measure based on observable entropy and deviation from equilibrium, which captures the dynamical progression towards equilibration and effectively distinguishes between complex and non-complex trajectories. In particular, our measure is sensitive to non-complex dynamics. Such dynamics include the quasi-periodic behavior exhibited by low-dimensional initial states, where the system explores a limited region of Hilbert space while preserving coherence. Numerical simulations of an Ising-like non-integrable Hamiltonian spin-chain model support these findings. Our work provides new insight into the emergence of equilibrium behavior from unitary dynamics and advances complexity as a meaningful tool in the study of the emergence of classicality in microscopic systems.
The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schrödinger equation, which preserves the von Neumann entropy. Nonetheless, one finds that with respect to many observables, expectation values approach a fixed value—their equilibrium value. This ultimately raises the question: ? For classical systems, one introduces the assumption of a low-entropy initial state along with the concept of ignorance about the microscopic details of the physical system, leading to a statistical interpretation of the second law. By considering the observables through which we examine quantum systems, both these assumptions can be incorporated, building upon recent studies of the of observables. While the statistical behavior of observable expectation values is well established, a quantitative connection to entropy increase has been lacking so far. In deriving novel bounds for the equilibration of observables, and considering the entropy of the system relative to observables, we recover a variant of the second law: the entropy with respect to a given observable tends toward its equilibrium value in the course of the system’s unitary evolution. These results also support recent findings that question the necessity of nonintegrability for equilibration in quantum systems. We further illustrate our bounds using numerical results from the paradigmatic example of a quantum Ising model on a chain of spins. There, we observe entropy increasing up to equilibrium values, as well as fluctuations, which expose the underlying reversible evolution in accordance with the derived bounds.
The question of how statistical physics can be seen to emerge from unitary quantum dynamics goes back to Schrödinger and von Neumann, however has been reaffirmed as a topic of importance due to recent advances in experimental capabilities, allowing the observation of the unitary evolution of many-particle systems over long periods of time. Understanding why such a system evolves to the specific thermal equilibrium state, effectively described by a relevant thermodynamic ensemble, has thus seen significantly more interest in recent years. Furthermore, observations of the dynamics of such systems open questions on the route to equilibrium, and subsequent fluctuations. In this thesis I will develop an approach to this problem, taking as a starting point the non-integrability of the system under study, which leads to a generic model in terms of random matrix theory (RMT), and more generally, chaotic wavefunctions. In the formulation of these methods, special attention is paid to the form of local observables of quantum systems, and an approach to their description is developed in terms of correlation functions of chaotic wavefunctions. From this approach a key conjecture in the understanding of thermalization, the eigenstate thermalization hypothesis (ETH), is derived in full, and the dynamical behaviour of such observables is obtained analytically. Further, I will show that emergent classical behaviour can be observed in the form of a fluctuation-dissipation theorem (FDT) of Brownian processes. This is exploited to develop an experimental proposal to measure the ‘complexity’ of a quantum device, by experimentally obtaining its effective Hilbert space dimension in terms of a fully connected system. Finally, quantum jump trajectories, describing stroboscopic projective measurements of local observables are studied, and shown to display classical Brownian dynamics in the form of a Markov process. Throughout this thesis, exact diagonalization calculations of realistic quantum spin systems are used to confirm analytical results.
In this work we revisit the problem of equilibration in isolated many-body interacting quantum systems. We pay particular attention to quantum chaotic Hamiltonians, and rather than focusing on the properties of the asymptotic states and how they adhere to the predictions of the Eigenstate Thermalization Hypothesis, we focus on the equilibration process itself, i.e., the road to equilibrium. Along the road to equilibrium the diagonal ensembles obey an emergent form of the second law of thermodynamics and we provide an information theoretic proof of this fact. With this proof at hand we show that the road to equilibrium is nothing but a hierarchy in time of diagonal ensembles. Furthermore, introducing the notions of statistical complexity and the entropy-complexity plane, we investigate the uniqueness of the road to equilibrium in a generic many-body system by comparing its trajectories in the entropy-complexity plane to those generated by a random Hamiltonian. Finally, by treating the random Hamiltonian as a perturbation we analyzed the stability of entropy-complexity trajectories associated with the road to equilibrium for a chaotic Hamiltonian and different types of initial states.
Understanding how macroscopic thermodynamic behavior emerges from microscopic quantum dynamics remains an open problem. While equilibration of quantum observables is well established, thermodynamics also relies on variables not directly associated with linear operators, but which are defined instead as functions of expectation values. Whether and how such derived quantities inherit equilibration properties is an open question. Here, we establish that any continuously differentiable function of equilibrating expectation values also equilibrates. We apply this result to a bipartite isolated system, showing that the entropy and conjugate variables of each subsystem -- defined through Jaynes' maximum entropy principle -- equilibrate. Moreover, with the assumption that their equilibrium properties depend solely on local conserved quantities, we show the dynamical maximization of the total entropy, enforcing equality of conjugate variables across subsystems. These results provide a direct dynamical justification for entropy maximization and the emergence of thermodynamic equilibrium conditions, showing that fundamental principles of thermodynamics follow from the unitary evolution of quantum systems.
Out-of-equilibrium quantum many-body systems stand at the forefront of modern theoretical physics, addressing fundamental questions on thermalization, transport, and universal phenomena. These fields, already well established in condensed matter, statistical physics, quantum optics, and quantum information theory, are progressively gaining even greater relevance with the rapid development of quantum technologies and simulation, which inherently operate in dynamical regimes. In recent years, the traditional paradigm of unitary quantum evolution has been expanded to include measurements, opening new directions in out-of-equilibrium physics. At the core of these advances lie measurement-induced phase transitions (MIPTs), which have emerged as a new class of dynamical critical phenomena characterizing the general behavior of monitored quantum dynamics. When external monitoring intertwines with unitary evolution, many-body quantum correlations change their structure, giving rise to distinct entanglement phases of matter. This discovery has sparked enormous interest in MIPTs, leading to significant advances in open quantum systems, entanglement theory, and more broadly quantum complexity. Despite much progress, a full understanding of monitored many-body dynamics is far from complete, leaving several open questions on the nature of MIPTs, their experimental observability, and the possibilities offered by measurements to enhance control over synthetic quantum matter. These issues persist due to the intrinsic complexity of the problem and the lack of efficient tools to study it, mainly caused by the stochastic character of monitored evolution. This thesis addresses these challenges by expanding the investigation of measurement-induced phenomena in new settings and introducing innovative probes of entanglement and many-body quantum complexity for MIPTs. A core question we investigate is the role of symmetries, non-ergodicity, and especially integrability in measurement-induced criticality, which dramatically affect the non-equilibrium phases. We further explore how these phenomena extend beyond bipartite quantum correlations to multipartite entanglement and quantum non-stabilizerness, highlighting the non-trivial interplay between measurements and complexity notions rooted in quantum information theory. Finally, we focus on the compelling problem of decoherence, modeling how noise spoils entanglement structures. These findings, supported by advanced numerical simulations and theoretical analysis, deepen the current understanding of entanglement, complexity, and integrability in monitored quantum many-body systems, offering new perspectives on their rich behavior. In parallel, we address the experimental problem of dissipation in MIPTs, which is of key relevance for practical implementations. We anticipate the present investigation to foster future research on the nature of monitored dynamical critical phenomena and, more broadly, the applications of measurements in quantum state evolution.
The emergence of classical behavior and the origin of thermal equilibrium are two central problems in the foundations of physics. In the standard accounts, both phenomena are typically explained through interactions with an external environment: decoherence suppresses quantum interference, while coupling to a thermal bath drives relaxation toward equilibrium. Over the last decades, however, it has become clear that equilibration and thermalization can arise even in fully isolated quantum systems, in the operational sense that the expectation values of relevant observables remain close to equilibrium values for most of the time. Here, we ask whether the same intrinsic equilibration mechanism can also account for the emergence of classical behavior. Using rigorous bounds on equilibration in closed systems, we derive sufficient conditions under which a time-evolved pure state becomes, for most times, operationally indistinguishable from a classical mixture associated with a chosen physical property. We identify two complementary routes to such operational classicality: either the chosen property almost commutes with the system Hamiltonian or the observables used to probe the system lose access to the remaining coherence after equilibration. Our results show that classical behavior need not be confined to the energy basis and may emerge even when substantial coherence remains present in the equilibrium state. This establishes a direct connection between two foundational questions: the origin of thermalization in isolated quantum systems and the quantum-to-classical transition