Structured light offers a powerful approach to tailor light--matter interactions in quantum systems with chiral properties. While chirality has been extensively studied in passive platforms, the role of optical gain in controlling chiral quantum dynamics remains largely unexplored. In this work, we develop a general theoretical framework to describe the dynamics of an atomic system interacting with structured gain environments, where amplification depends on the light's polarization or momentum. By quantizing the electromagnetic field in linear bianisotropic media with gain and extending the Lindblad formalism to these settings, we derive a master equation governing the atom's irreversible evolution. We show that chiral gain can break time-reversal symmetry and drive the system toward a symmetry-broken steady state with nonreciprocal properties. This effect is illustrated in detail for moving plasmonic substrates, which exhibit inherently chiral gain that selectively amplifies transitions of a given handedness. Our results establish chiral gain as a novel mechanism for engineering nonreciprocal quantum steady states.
Structured light offers a powerful approach to tailor light--matter interactions in quantum systems with chiral properties. While chirality has been extensively studied in passive platforms, the role of optical gain in controlling chiral quantum dynamics remains largely unexplored. In this work, we develop a general theoretical framework to describe the dynamics of an atomic system interacting with structured gain environments, where amplification depends on the light's polarization or momentum. By quantizing the electromagnetic field in linear bianisotropic media with gain and extending the Lindblad formalism to these settings, we derive a master equation governing the atom's irreversible evolution. We show that chiral gain can break time-reversal symmetry and drive the system toward a symmetry-broken steady state with nonreciprocal properties. This effect is illustrated in detail for moving plasmonic substrates, which exhibit inherently chiral gain that selectively amplifies transitions of a given handedness. Our results establish chiral gain as a novel mechanism for engineering nonreciprocal quantum steady states.
Conventional optical materials are characterized by either a dissipative response, which results in polarization-independent absorption, or by a gain response that leads to wave amplification. In this work, we study a peculiar class of materials with chiral-gain properties, where gain selectively amplifies waves of one polarization handedness, while dissipation suppresses the opposite handedness. We uncover a novel phenomenon, gain-momentum locking, at the boundary of chiral-gain media, where surface plasmons are amplified or attenuated based on their direction of propagation. This effect, driven by the interplay between spin-momentum locking and polarization-sensitive non-Hermitian responses, enables precise control over unidirectional wave propagation. Our findings open the door to photonic devices with unprecedented capabilities, such as lossless unidirectional edge-wave propagation and the generation of light with intrinsic orbital angular momentum.
Summary form only given. Controlling the interaction of light and matter is the basis for diverse applications ranging from light technology to quantum information processing. Nowadays, many of these applications are based on nanophotonic structures. It turns out that the confinement of light in such nanostructures imposes an inherent link between its local polarization and its propagation direction, also referred to as spin-momentum locking of light [1]. Remarkably, this leads to chiral, i.e., propagation direction-dependent effects in the emission and absorption of light, and elementary processes of light-matter interaction are fundamentally altered. For example, when coupling plasmonic particles or atoms to evanescent fields, the intrinsic mirror symmetry of the particles' emission can be broken. In our group, we observed this effect in the interaction between single rubidium atoms and the evanescent part of a light field that is confined by continuous total internal reflection in a whispering-gallery-mode microresonator [2]. In the following, this allowed us to realize chiral nanophotonic interfaces in which the emission direction of light into the structure is controlled by the polarization of the excitation light [3] or by the internal quantum state of the emitter [4], respectively. Moreover, we employed this chiral interaction to demonstrate an integrated optical isolator [5] as well as an integrated optical circulator [6] which operate at the single-photon level and which exhibit low loss. The latter are the first two examples of a new class of nonreciprocal nanophotonic devices which exploit the chiral interaction between single quantum emitters and transversally confined photons.
Detecting and controlling the chirality of matter play an essential role in exploring nature, providing previously unexplored avenues for matter discrimination and quantum manipulation. In such tasks, chiral probes are essential in defining or enhancing the chiral dichroism response. However, overlooking their influence on the symmetry of the medium hampers the ability to deterministically induce electromagnetic chirality. Here, we propose a simple yet versatile all-optical chirality transfer method to generate and manipulate the electromagnetic chirality of a neutral atomic medium. By inducing chirality-dependent dispersion in the atomic system, our method enables deterministic and tunable control of chirality transfer via a helical field. We theoretically analyze the mechanism of this optically induced symmetry breaking and experimentally demonstrate the helicity-dependent response of the medium. Our results show that the induced chirality can be effectively suppressed or enhanced, enabling deterministic electromagnetic enantioselection. This approach opens an efficient pathway for manipulating chiral symmetry breaking in light-matter interactions.
We show that the conventional multipolar Hamiltonian is qualitatively modified when the photonic vacuum breaks inversion or time-reversal symmetry. By explicitly applying the Power-Zienau-Woolley transformation, we derive the resulting multipolar Hamiltonians for two idealized chiral photonic environments: a spatial-chiral vacuum, which breaks inversion symmetry, and a temporal-chiral vacuum, which breaks time-reversal symmetry. In the spatial-chiral case, the transformation generates an inversion-breaking self-energy, whereas in the temporal-chiral case it produces an additional Zeeman-like energy. Using a trapped hydrogen-like atom and a charged harmonic oscillator in cavities as minimal examples, we show that these symmetry-dependent terms lead to characteristic spectral shifts. Our work provides a general framework for describing light-matter interactions in chiral quantum electrodynamics and identifying the associated symmetry-dependent effects on cavity-embedded atoms, molecules, and quantum materials.
We present a theoretical study of the interaction between an atom characterized by a degenerate ground state and a reciprocal environment, such as a semiconductor nanoparticle, without the presence of external bias. Our analysis reveals that the combined influence of the electron's intrinsic spin magnetic moment on the environment and the chiral atomic dipolar transitions may lead to either the spontaneous breaking of time-reversal symmetry or the emergence of time-crystal-like states with remarkably long relaxation times. The different behavior is ruled by the handedness of the precession motion of the atom's spin vector, which is induced by virtual chiral-dipolar transitions. Specifically, when the relative orientation of the precession angular velocity and the electron spin vector is as in a spinning top, the system manifests time-crystal-like states. Conversely, with the opposite relative orientation, the system experiences spontaneous symmetry breaking of time-reversal symmetry. Our findings introduce a novel mechanism for the spontaneous breaking of time-reversal symmetry in atomic systems, and unveil an exciting opportunity to engineer a nonreciprocal response at the nanoscale, exclusively driven by the quantum vacuum fluctuations.
We demonstrate that light propagation in reciprocal chiral photonic media admits a unified description in terms of an emergent Dirac structure in helicity space. Starting from Maxwell's equations, we reformulate the electromagnetic field as a four-component spinor governed by an effective non-Hermitian optical Dirac equation. In this representation, the magnetoelectric response of the chiral medium appears as a helicity-dependent background that modifies the spectrum and eigenmodes, while the breaking of the spin-degenerate condition generates the intrinsic spin-orbit coupling between helicity and orbital degrees of freedom. After projection onto the positive-frequency sector, the theory reduces to an exact two-level helicity-orbital model. This model is found to have an analytical solution and describes coherent Rabi-like oscillations between spin-orbit-coupled vector modes. Chirality controls the helicity splitting and detuning, whereas the electromagnetic mismatch of the medium determines the coupling strength responsible for oscillatory spin-orbit conversion. The resulting dynamics is constrained by exact conservation of the total angular momentum, leading to reversible conversion between spin and orbital angular momentum with well-defined selection rules. Our work establishes an optical Dirac framework for structured light in chiral media, and provides experimentally accessible predictions for chirality-controlled oscillations, polarization dynamics, and orbital angular momentum conversion in structured optical fields.