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arXiv:2504.21727 · Physical Review Letters

Steering Reaction Flux by Coupling Product Channels

Dominik Dorer, Shinsuke Haze, Jing-Lun Li, José Paulo D'Incao, E. Tiemann, Paul S. Julienne, Markus Deiß, Johannes Hecker Denschlag

Published Jan 2, 2026• 2 citations
arXivHTMLPDF

Abstract

We demonstrate a method for controlling the outcome of an ultracold chemical few-body reaction by redirecting a tunable fraction of reaction flux from one selected product channel to another one. In the reaction, three ultracold atoms collide to form a diatomic molecule. This product molecule can be produced in various internal states, characterizing the different product channels of the reaction. Our scheme relies on the coupling between two such product channels at an avoided molecular energy level crossing in the presence of an external magnetic field. The degree of coupling can be set by the magnetic field strength and allows for a widely tunable flux control between the two channels. This scheme is quite general and also holds great promise for a large variety of chemical processes with diverse species, since molecular energy level crossings are ubiquitous in molecular systems and are often easily accessible by standard laboratory equipment.

DOI
10.1103/5mxs-g3z8

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We demonstrate a method for controlling the outcome of an ultracold chemical few-body reaction by redirecting a tunable fraction of reaction flux from one selected product channel to another one. In the reaction, three ultracold atoms collide to form a diatomic molecule. This product molecule can be produced in various internal states, characterizing the different product channels of the reaction. Our scheme relies on the coupling between two such product channels at an avoided molecular energy level crossing in the presence of an external magnetic field. The degree of coupling can be set by the magnetic field strength and allows for a widely tunable flux control between the two channels. This scheme is quite general and also holds great promise for a large variety of chemical processes with diverse species, since molecular energy level crossings are ubiquitous in molecular systems and are often easily accessible by standard laboratory equipment.
Gaining control over chemical reactions on the quantum level is a central goal of the modern field of cold and ultracold chemistry. Here, we demonstrate a novel method to coherently steer reaction flux of a three-body recombination process across different product spin channels. For this, we employ a magnetically-tunable Feshbach resonance to admix, in a controlled way, a specific spin state to the reacting collision complex. This allows for the control of the reaction flux into the admixed spin channel, which can be used to significantly change the reaction products. Furthermore, we also investigate the influence of an Efimov resonance on the reaction dynamics. We find that while the Efimov resonance can be used to globally enhance three-body recombination, the relative flux between the reaction channels remains unchanged. Our control scheme is general and can be extended to other reaction processes. It also provides new opportunities in combination with other control schemes, such as quantum interference of reaction paths.
Gaining control over chemical reactions at the quantum level is a central goal of cold and ultracold chemistry. Here we demonstrate a method for coherently steering the reaction flux across different product spin channels for a three-body recombination process in a cloud of trapped cold atoms. We use a magnetically tunable Feshbach resonance to admix, in a controlled way, a specific spin state to the reacting collision complex. This allows us to control the reaction flux into the admixed spin channel, which can be used to alter the reaction products. We also investigate the influence of an Efimov resonance on the reaction dynamics, observing a global enhancement of three-body recombination without favouring particular reaction channels. Our control scheme can be extended to other reaction processes and could be combined with other methods, such as quantum interference of reaction paths, to achieve further tuning capabilities of few-body reactions.
Abstract Gaining control over chemical reactions at the quantum level is a central goal of cold and ultracold chemistry. Here we demonstrate a method for coherently steering the reaction flux across different product spin channels for a three-body recombination process in a cloud of trapped cold atoms. We use a magnetically tunable Feshbach resonance to admix, in a controlled way, a specific spin state to the reacting collision complex. This allows us to control the reaction flux into the admixed spin channel, which can be used to alter the reaction products. We also investigate the influence of an Efimov resonance on the reaction dynamics, observing a global enhancement of three-body recombination without favouring particular reaction channels. Our control scheme can be extended to other reaction processes and could be combined with other methods, such as quantum interference of reaction paths, to achieve further tuning capabilities of few-body reactions.
We consider ultracold, chemically reactive scattering collisions of the diatomic molecules KRb. When two such molecules collide in an ultracold gas, we find that they are energetically forbidden from reacting to form the trimer species K2Rb{\mathrm{K}}_{2}\mathrm{Rb}K2​Rb or Rb2K{\mathrm{Rb}}_{2}\mathrm{K}Rb2​K, and hence can only react via the bond-swapping reaction $2\mathrm{KRb}\ensuremath{\rightarrow}{\mathrm{K}}_{2}+{\mathrm{Rb}}_{2}$. Moreover, the tiny energy released in this reaction can in principle be set to zero by applying electric or microwave fields, implying a means of controlling the available reaction channels in a chemical reaction.
Abstract Studying chemical reactions on a state-to-state level tests and improves our fundamental understanding of chemical processes. For such investigations it is convenient to make use of ultracold atomic and molecular reactants as they can be prepared in well defined internal and external quantum states. Here, we investigate a single-channel reaction of two Li2-Feshbach molecules where one of the molecules dissociates into two atoms 2AB ⇒ AB + A + B. The process is a prototype for a class of four-body collisions where two reactants produce three product particles. We measure the collisional dissociation rate constant of this process as a function of collision energy/temperature and scattering length. We confirm an Arrhenius-law dependence on the collision energy, an a4 power-law dependence on the scattering length a and determine a universal four body reaction constant.
Entanglement, a defining feature of quantum mechanics, arises naturally from interactions between molecular systems. Yet the precise nature and quantification of entanglement in the products of molecular collisions and reactions remain largely unexplored. Here, we show that coupling between the external (motional) and internal degrees of freedom of the colliding molecules generates diverse forms of product-state entanglement: discrete-discrete, continuum-continuum, and hybrid discrete-continuum. We develop a general theoretical framework to quantify these entanglement forms directly from scattering S-matrix elements and identify a novel class of entangled states-multimode hybrid cat states, that exhibit multimode discrete-continuum entanglement. Although applicable at arbitrary collision energies, the formalism is illustrated in the ultracold and cold regimes for inelastic Rb+SrF and Rb+Sr+^++ collisions, as well as the chemical reaction F+HD →\rightarrow→ HF+D, DF+H. We demonstrate that entanglement can be efficiently controlled near magnetic Feshbach resonances, paving the way for precise magnetic control of product-state entanglement generation in ultracold molecular collisions.