A bstract A classical dynamical system can be viewed as a probability space equipped with a measure-preserving time evolution map, admitting a purely algebraic formulation in terms of the algebra of bounded functions on the phase space. Similarly, a quantum dynamical system can be formulated using an algebra of bounded operators in a non-commutative probability space equipped with a time evolution map. Chaos, in either setting, can be characterized by statistical independence between observables at t = 0 and t → ∞, leading to the vanishing of cumulants involving these observables. In the quantum case, the notion of independence is replaced by free independence, which only emerges in the thermodynamic limit (asymptotic freeness). In this work, we propose a definition of quantum chaos based on asymptotic freeness and investigate its emergence in quantum many-body systems including the mixed-field Ising model with a random magnetic field, a higher spin version of the same model, and the SYK model. The hallmark of asymptotic freeness is the emergence of the free convolution prediction for the spectrum of operators of the form A (0) + B ( t ), implying the vanishing of all free cumulants between A (0) and B ( t ) in the thermodynamic limit for an infinite-temperature thermal state. We systematically investigate the spectral properties of A (0) + B ( t ) in the above-mentioned models, show that fluctuations on top of the free convolution prediction follow universal Wigner-Dyson statistics, and discuss the connection with quantum chaos. Finally, we argue that free probability theory provides a rigorous framework for understanding quantum chaos, offering a unifying perspective that connects many different manifestations of it.
A bstract A classical dynamical system can be viewed as a probability space equipped with a measure-preserving time evolution map, admitting a purely algebraic formulation in terms of the algebra of bounded functions on the phase space. Similarly, a quantum dynamical system can be formulated using an algebra of bounded operators in a non-commutative probability space equipped with a time evolution map. Chaos, in either setting, can be characterized by statistical independence between observables at t = 0 and t → ∞, leading to the vanishing of cumulants involving these observables. In the quantum case, the notion of independence is replaced by free independence, which only emerges in the thermodynamic limit (asymptotic freeness). In this work, we propose a definition of quantum chaos based on asymptotic freeness and investigate its emergence in quantum many-body systems including the mixed-field Ising model with a random magnetic field, a higher spin version of the same model, and the SYK model. The hallmark of asymptotic freeness is the emergence of the free convolution prediction for the spectrum of operators of the form A (0) + B ( t ), implying the vanishing of all free cumulants between A (0) and B ( t ) in the thermodynamic limit for an infinite-temperature thermal state. We systematically investigate the spectral properties of A (0) + B ( t ) in the above-mentioned models, show that fluctuations on top of the free convolution prediction follow universal Wigner-Dyson statistics, and discuss the connection with quantum chaos. Finally, we argue that free probability theory provides a rigorous framework for understanding quantum chaos, offering a unifying perspective that connects many different manifestations of it.
Quantum chaos concerns the emergence of universal statistical and dynamical prop- erties in quantum systems whose classical counterparts exhibit chaotic behavior. Unlike classical chaos, which can be characterized by sensitivity to initial conditions and exponential divergence of trajectories, quantum chaos manifests itself through a variety of indirect diagnostics, including spectral correlations, operator growth, and information scrambling. Understanding how these signatures arise from microscopic dynamics, and how they can be accessed in realistic many-body systems, is a central challenge in modern physics. This thesis investigates quantum chaos from complementary theoretical and practical perspectives. On the theoretical side, it develops effective descriptions of chaotic dy- namics in many-body systems with approximate symmetries, focusing on how weak symmetry breaking controls the exploration of Hilbert space and the crossover to random-matrix universality. Using perturbative arguments, numerical simulations, and a nonlinear sigma-model formulation, we identify a regime of Hilbert-space dif- fusion in which chaotic dynamics unfolds through a slow, collective spreading across nearly decoupled symmetry sectors. On the practical side, the thesis addresses the question of how paradigmatic chaotic models can be realized and probed in controlled experimental platforms. In partic- ular, it explores quantum simulation schemes for Sachdev–Ye–Kitaev (SYK) models using cavity quantum electrodynamics. By employing time-dependent disorder and Trotterized evolution in single-mode optical cavities, we demonstrate how low-rank interactions can be systematically promoted to effective all-to-all randomness, re- producing the spectral and dynamical signatures of SYK physics. Extensions to open-system dynamics are discussed, including Lindbladian realizations and the role of dissipation. The thesis thus highlights the connections between effective descriptions of quantum chaos and their implementation in controlled quantum simulation settings.
A bstract We investigate minimal two-body Hamiltonians with random interactions that generate spectra resembling those of Gaussian random matrices, a phenomenon we term quadratic quantum chaos . Unlike integrable two-body fermionic systems, the corresponding hard-core boson models exhibit genuinely chaotic dynamics, closely paralleling the Sachdev-Ye-Kitaev (SYK) model in its spin representation. This chaotic behavior is diagnosed through spectral statistics and measures of operator growth, including Krylov complexity and the late-time decay of higher-order out-of-time-ordered correlators (OTOCs); the latter reveals the emergence of freeness in the sense of free probability. Moreover, the fractal dimension and Stabilizer Rényi entropy of a representative mid-spectrum eigenstate show finite-size deviations yet converge toward Haar-randomness as the system size increases. This convergence, constrained by local interactions, highlights the “weakly chaotic” character of these eigenstates. Owing to their simplicity and bosonic nature, these minimal models may constitute promising and resource-efficient candidates for probing quantum chaos and information scrambling on near-term quantum devices.
The question of how statistical physics can be seen to emerge from unitary quantum dynamics goes back to Schrödinger and von Neumann, however has been reaffirmed as a topic of importance due to recent advances in experimental capabilities, allowing the observation of the unitary evolution of many-particle systems over long periods of time. Understanding why such a system evolves to the specific thermal equilibrium state, effectively described by a relevant thermodynamic ensemble, has thus seen significantly more interest in recent years. Furthermore, observations of the dynamics of such systems open questions on the route to equilibrium, and subsequent fluctuations. In this thesis I will develop an approach to this problem, taking as a starting point the non-integrability of the system under study, which leads to a generic model in terms of random matrix theory (RMT), and more generally, chaotic wavefunctions. In the formulation of these methods, special attention is paid to the form of local observables of quantum systems, and an approach to their description is developed in terms of correlation functions of chaotic wavefunctions. From this approach a key conjecture in the understanding of thermalization, the eigenstate thermalization hypothesis (ETH), is derived in full, and the dynamical behaviour of such observables is obtained analytically. Further, I will show that emergent classical behaviour can be observed in the form of a fluctuation-dissipation theorem (FDT) of Brownian processes. This is exploited to develop an experimental proposal to measure the ‘complexity’ of a quantum device, by experimentally obtaining its effective Hilbert space dimension in terms of a fully connected system. Finally, quantum jump trajectories, describing stroboscopic projective measurements of local observables are studied, and shown to display classical Brownian dynamics in the form of a Markov process. Throughout this thesis, exact diagonalization calculations of realistic quantum spin systems are used to confirm analytical results.
We study the time-evolution operator in a family of local quantum circuits with random fields in a fixed direction. We argue that the presence of quantum chaos implies that at large times the time-evolution operator becomes effectively a random matrix in the many-body Hilbert space. To quantify this phenomenon, we compute analytically the squared magnitude of the trace of the evolution operator-the generalized spectral form factor-and compare it with the prediction of random matrix theory. We show that for the systems under consideration, the generalized spectral form factor can be expressed in terms of dynamical correlation functions of local observables in the infinite temperature state, linking chaotic and ergodic properties of the systems. This also provides a connection between the many-body Thouless time τ_{th}-the time at which the generalized spectral form factor starts following the random matrix theory prediction-and the conservation laws of the system. Moreover, we explain different scalings of τ_{th} with the system size observed for systems with and without the conservation laws.
Recent work highlighted the importance of higher-order correlations in quantum dynamics for a deeper understanding of quantum chaos and thermalization. The full Eigenstate Thermalization Hypothesis, the framework encompassing correlations, can be formalized using the language of Free Probability theory. In this context, chaotic dynamics at long times are proposed to lead to free independence or "freeness" of observables. In this work, we investigate these issues in a paradigmatic semiclassical model – the kicked top – which exhibits a transition from integrability to chaos. Despite its simplicity, we identify several non-trivial features. By numerically studying 2n-point out-of-time-order correlators, we show that in the fully chaotic regime, long-time freeness is reached exponentially fast. These considerations lead us to introduce a large deviation theory for freeness that enables us to define and analyze the associated time scale. The numerical results confirm the existence of a hierarchy of different time scales, indicating a multifractal approach to freeness in this model. Our findings provide novel insights into the long-time behavior of chaotic dynamics and may have broader implications for the study of many-body quantum dynamics.
A key goal of quantum chaos is to establish a relationship between widely observed universal spectral fluctuations of clean quantum systems and random matrix theory (RMT).Most prominent features of such RMT behavior with respect to a random spectrum, both encompassed in spectral pair correlation function, are statistical suppression of small level spacings (correlation hole) and enhanced stiffness of the spectrum at large spectral ranges.For single particle systems with fully chaotic classical counterparts, the problem has been partly solved by Berry [Proc.R. Soc.London, A400, 229 (1985)] within the so-called diagonal approximation of semiclassical periodic-orbit sums, while the derivation of the full RMT spectral form factor K(t) (Fourier transform of spectral pair correlation function), from semiclassics has been completed by Müller et al. [Phys.Rev. Lett.93, 014103 (2004)].In recent years, the questions of long-time dynamics at high energies, for which the full many-body energy spectrum becomes relevant, are coming at the forefront even for simple many-body quantum systems, such as locally interacting spin chains.Such systems display two universal types of behaviour which are termed as the 'many-body localized phase' and 'ergodic phase'.In the ergodic phase, the spectral fluctuations are excellently described by RMT, even for very simple interactions and in the absence of any external source of disorder.Here we provide a clear theoretical explanation for these observations.We compute K(t) in the leading two orders in t and show its agreement with RMT for non-integrable, time-reversal invariant many-body systems without classical counterparts, a generic example of which are Ising spin 1/2 models in a periodically kicking transverse field.In particular, we relate K(t) to partition functions of a class of twisted classical Ising models on a ring of size t, hence the leading order RMT behavior K(t)2t is a consequence of translation and reflection symmetry of the Ising partition function.