Abstract Understanding the dynamical consequences of quantum phase transitions on thermodynamical quantities, such as work statistics and entropy production, is one of the most intriguing aspect of quantum many-body systems, pinpointing the emergence of irreversibility to critical features. In this work, we investigate the critical fingerprints appearing in these key thermodynamical quantities for a mean-field critical system undergoing a finite-time cycle, starting from a thermal state at a generic inverse temperature. In contrast to non-zero dimensional many-body systems, the presence of a mean-field critical point in a finite-time cycle leads to constant irreversible work even in the limit of infinitely slow driving. This links with the fact that a slow finite-time cycle results in a constant amount of squeezing, which enables us to derive analytical expressions for the work statistics and irreversible entropy, depending solely on the mean-field critical exponents and the functional form of the control parameter near the critical point. We find that the probability of observing negative work values, corresponding to negative irreversible entropy, is inversely proportional to the time the system remains near to the critical point, and this trend becomes less pronounced the lower the temperature of the initial thermal state. Finally, we determine the irreversibility traits under squeezing generation at zero-temperature using the relative entropy of coherence.
Abstract Understanding the dynamical consequences of quantum phase transitions on thermodynamical quantities, such as work statistics and entropy production, is one of the most intriguing aspect of quantum many-body systems, pinpointing the emergence of irreversibility to critical features. In this work, we investigate the critical fingerprints appearing in these key thermodynamical quantities for a mean-field critical system undergoing a finite-time cycle, starting from a thermal state at a generic inverse temperature. In contrast to non-zero dimensional many-body systems, the presence of a mean-field critical point in a finite-time cycle leads to constant irreversible work even in the limit of infinitely slow driving. This links with the fact that a slow finite-time cycle results in a constant amount of squeezing, which enables us to derive analytical expressions for the work statistics and irreversible entropy, depending solely on the mean-field critical exponents and the functional form of the control parameter near the critical point. We find that the probability of observing negative work values, corresponding to negative irreversible entropy, is inversely proportional to the time the system remains near to the critical point, and this trend becomes less pronounced the lower the temperature of the initial thermal state. Finally, we determine the irreversibility traits under squeezing generation at zero-temperature using the relative entropy of coherence.
The thermodynamic behavior of out-of-equilibrium quantum systems in finite-time dynamics encompasses the description of energy fluctuations, which dictates a series of the system's physical properties. In addition, strong interactions in many-body systems strikingly affect the energy-fluctuation statistics along a nonequilibrium dynamics. By driving transient currents to oppose the precursor to the metal-Mott-insulator transition in a diversity of dynamical regimes, we show how increasing many-body interactions dramatically affect the statistics of energy fluctuations and, consequently, the extractable work distribution of finite Hubbard chains. Statistical properties of such distributions as its skewness with its impressive change across the transition can be related to irreversibility and entropy production. Even for slow driving rates, the quasi quantum phase transition hinders equilibration, increasing the process irreversibility, and inducing strong features in the work distribution. In the Mott-insulating phase, the work fluctuation-dissipation balance gets modified with the irreversible entropy production dominating over work fluctuations. Because of this, effects of an interaction-driven quantum phase transition on thermodynamic quantities and irreversibility must be considered in the design of protocols in small-scale devices for application in quantum technology. Eventually, such many-body effects can also be employed in work extraction and refrigeration protocols on a quantum scale.
The irreversible work during a driving protocol constitutes one of the most widely studied measures in nonequilibrium thermodynamics, as it constitutes a proxy for entropy production. In quantum systems, it has been shown that the irreversible work has an additional, genuinely quantum mechanical contribution, due to coherence produced by the driving protocol. The goal of this paper is to explore this contribution in systems that undergo a quantum phase transition. Substantial effort has been dedicated in recent years to understanding the role of quantum criticality in work protocols. However, practically nothing is known about how coherence contributes to it. To shed light on this issue, we study the entropy production in infinitesimal quenches of the one-dimensional XY model. We find that coherence plays a significant role in the entropy production and can even account for most of it in certain situations. Moreover, at low temperatures, the coherence presents a finite cusp at the critical point, whereas the entropy production diverges logarithmically. For high temperatures, however, the coherence presents a kink at the critical point indicating the quantum phase transition that occurs only at T=0. Alternatively, if the quench is performed in the anisotropy parameter, then we find that there are situations where all of the entropy produced is due to quantum coherences.
It is a central question in quantum thermodynamics to determine how irreversible is a process that transforms an initial state $\ensuremath{\rho}$ to a final state $\ensuremath{\sigma}$ and whether such irreversibility can be thought of as a useful resource. For example, we might ask how much work can be obtained by thermalizing $\ensuremath{\rho}$ to a thermal state $\ensuremath{\sigma}$ at temperature T of an ambient heat bath. Here, we show that, for different sets of resource-theoretic thermodynamic operations, the amount of entropy produced along a transition is characterized by how reversible the process is. More specifically, this entropy production depends on how well we can return the state $\ensuremath{\sigma}$ to its original form $\ensuremath{\rho}$ without investing any work. At the same time, the entropy production can be linked to the work that can be extracted along a given transition and we explore the consequences that this fact has for our results. We also exhibit an explicit reversal operation in terms of the Petz recovery channel coming from quantum information theory. Our result establishes a quantitative link between the reversibility of thermodynamical processes and the corresponding work gain.
Generic far-away-from-equilibrium many-body dynamics involve entropy production and hence is thermodynamically irreversible. Near quantum critical points, an emergent conformal symmetry can impose strong constraints on entropy production rates and in some cases can completely forbid entropy production, which usually occurs for systems that deviate from quantum critical points. In this article, we illustrate how the vanishing entropy production near a quantum critical point results in reversible far-away-from-equilibrium dynamics at finite temperatures that is otherwise irreversible. Away from the quantum critical point, the quantum dynamics is damped, and our analysis directly relates the thermalization timescale to the hydrodynamic viscosity near quantum critical points with the dynamical critical exponent z=2. We demonstrate how both controllable reversible and irreversible dynamics can be potentially studied in cold gas experiments using Feshbach resonances.
Phase transitions represent fundamental transformations of matter, characterized by abrupt changes in macroscopic properties and often associated with singular behavior at critical points. While equilibrium aspects of phase transitions, particularly universal critical exponents and scaling laws, are well-understood, the non-equilibrium processes occurring near criticality, especially the production of entropy, remain a rich area of investigation. This paper explores the intricate relationship between critical entropy production and the emergence of scaling laws in systems undergoing phase transitions. We delve into how the rate of entropy production diverges or exhibits anomalous scaling near critical points, reflecting the system's attempts to dissipate energy and respond to external perturbations as it approaches a state of macroscopic change. By integrating concepts from non-equilibrium thermodynamics, statistical mechanics, and renormalization group theory, we aim to elucidate the underlying mechanisms that govern entropy generation in these critical regimes. We discuss theoretical frameworks that predict universal scaling behaviors for entropy production rates, analogous to those observed for equilibrium order parameters and susceptibilities. The implications of these scaling laws extend beyond theoretical physics, offering insights into complex systems, far-from-equilibrium dynamics, and the efficiency of energy conversion processes in critical environments. Our analysis highlights the critical entropy production as a unique signature of non-equilibrium dynamics during phase transitions, providing a deeper understanding of the interplay between fluctuations, dissipation, and universality near points of instability.
This thesis reports the results obtained during my PhD research in the field of out of equilibrium quantum many-body systems. Chapter 1 consists in a brief introduction of the field and the introduction of concept that are useful for the following chapters. In Chapter 2 the statistics of the work as a tool for characterizing the dynamics of many-body quantum systems is introduced its general features discussed. Then, such a statistics is computed for generic time-dependent protocols (both global and local) in the quantum Ising chain and in the Gaussian field theory, showing, in particular, that in its low-energy part there are features that are independent of the details of the specific chosen protocol. Chapter 3 is devoted to the study of the dynamical phase transition in the O(N) quantum vector model in the N→∞ limit, whose critical properties in generic dimensions are characterized. Moreover, a strong connection between such a transition and the statistics of excitations produced in a double quench as a function of the waiting time is showed. The chapter ends by studying the fate of the dynamical transition and the its critical properties when a ramp of finite duration τ is applied to the system instead of a sudden quench. In particular, we will show that when τ→∞ the critical point tends to the equilibrium critical point (at zero temperature) in a power-law fashion and that for every finite τ the critical properties are always the same (and different from the equilibrium critical properties). Finally in Chapter 4 we will discuss the emergence of a non adiabatic behavior in the dynamics of the order parameter for a low dimensional quantum system driven within a gapped phase by considering in detail the case of a quantum Ising chain subject to a linear variation in time of the transverse field, showing that, no matter how slowly the ramp is performed, such a change leads eventually to the disruption of the order.