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arXiv:2501.11537 · Journal of Mathematical Physics

Density matrices and entropy operator for non-Hermitian quantum mechanics

Fabio Bagarello, Francesco Gargano, Lidia Saluto

Published Feb 1, 2025• 5 citations
arXivHTMLPDF

Abstract

In this paper we consider density matrices operator related to non-Hermitian Hamiltonians. In particular, we analyze two natural extensions of what is usually called a density matrix operator (DM), of pure states and of the entropy operator: we first consider those operators which are simply similar to a standard DM, and then we discuss those which are intertwined with a DM by a third, non invertible, operator, giving rise to what we call Riesz Density Matrix operator (RDM). After introducing the mathematical framework, we apply the framework to a couple of applications. The first application is related to a non-Hermitian Hamiltonian describing gain and loss phenomena, widely considered in the context of PT-quantum mechanics. The second application is related to a finite-dimensional version of the Swanson Hamiltonian, never considered before, and addresses the problem of deriving a milder version of the RDM when exceptional points form in the system.

DOI
10.1063/5.0231303

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In this paper we consider density matrices operator related to non-Hermitian Hamiltonians. In particular, we analyze two natural extensions of what is usually called a density matrix operator (DM), of pure states and of the entropy operator: we first consider those operators which are simply similar to a standard DM, and then we discuss those which are intertwined with a DM by a third, non invertible, operator, giving rise to what we call Riesz Density Matrix operator (RDM). After introducing the mathematical framework, we apply the framework to a couple of applications. The first application is related to a non-Hermitian Hamiltonian describing gain and loss phenomena, widely considered in the context of PT-quantum mechanics. The second application is related to a finite-dimensional version of the Swanson Hamiltonian, never considered before, and addresses the problem of deriving a milder version of the RDM when exceptional points form in the system.
Hamiltonian Mechanics works for conserved systems and Quantum Mechanics is given in Hamiltonian language. It is considered that complexifying the quantum Hamiltonian, a balanced loss and gain model can be created. The usual mathematics of density operator formalism and entanglement is extrapolated to such systems and the consequences are studied. Namely, a complete formalism using Density operators is created for real eigenvalue regime of these Non- Hermitian systems and correct forms of Von-Neumann and Entanglement Entropy are created. The consequences are studied in this regime and depicted w.r.t recent papers by [9, 20].
A bstract The construction of exactly-solvable models has recently been advanced by considering integrable TT‾ T\overline{T} TT T T ¯ deformations and related Hamiltonian deformations in quantum mechanics. We introduce a broader class of non-Hermitian Hamiltonian deformations in a nonrelativistic setting, to account for the description of a large class of open quantum systems, which includes, e.g., arbitrary Markovian evolutions conditioned to the absence of quantum jumps. We relate the time evolution operator and the time-evolving density matrix in the undeformed and deformed theories in terms of integral transforms with a specific kernel. Non-Hermitian Hamiltonian deformations naturally arise in the description of energy diffusion that emerges in quantum systems from time-keeping errors in a real clock used to track time evolution. We show that the latter can be related to an inverse TT‾ T\overline{T} TT T T ¯ deformation with a purely imaginary deformation parameter. In this case, the integral transforms take a particularly simple form when the initial state is a coherent Gibbs state or a thermofield double state, as we illustrate by characterizing the purity, Rényi entropies, logarithmic negativity, and the spectral form factor. As the dissipative evolution of a quantum system can be conveniently described in Liouville space, we further study the spectral properties of the Liouvillians, i.e., the dynamical generators associated with the deformed theories. As an application, we discuss the interplay between decoherence and quantum chaos in non-Hermitian deformations of random matrix Hamiltonians and the Sachdev-Ye-Kitaev model.
In this paper we review an approach to the dynamics of open quantum systems based of non-Hermitian Hamiltonians. Non-Hermitian Hamiltonians arise naturally when one wish to study a subsystem interacting with a continuum of states. Moreover, quantum subsystems with probability sinks or sources are naturally described by non-Hermitian Hamiltonians. Herein, we discuss a non-Hermitian formalism based on the density matrix. We show both how to derive the equations of motion of the density matrix and how to define statistical averages properly. It turns out that the laws of evolution of the normalized density matrix are intrinsically non-linear. We also show how to define correlation functions and a non-Hermitian entropy with a non zero production rate. The formalism has been generalized to the case of hybrid quantum-classical systems using a partial Wigner representation. The equations of motion and the statistical averages are defined analogously to the pure quantum case. However, the definition of the entropy requires to introduce a non-Hermitian linear entropy functional.
Abstract The fundamentals of the theory of density matrices are reviewed. The density matrix is introduced first in terms of state vectors for pure states over which a probability distribution is given. It is then shown that the applications of the density matrix do not require knowledge of the particular probability distribution over pure states that may have been used for its original determination. It is stressed that density matrices, like state vectors, describe ensembles rather than single systems, as determinism in quantum theory (except for some conservation laws) is of a statistical character only. The entropy of a quantum‐mechanical system is defined as the average per system of the entropy of an ensemble of systems described by the quantum‐mechanical (pure or mixed) state. For pure states this entropy is zero, in agreement with the fact that state vectors constitute the maximal information that can be given about a quantum‐mechanical system. As the entropy should be independent of the particular probability distribution over pure states that may have been used to form the mixed state, it is calculated from statistical considerations about an imaginary ensemble in which the eigenvalues of the density matrix are probabilities over pure states given by the eigenfunctions of the density matrix. The entropy is calculated for a mixture of two nonorthogonal states. The time evolution of the density matrix, in general, is not a unitary transformation, as observable systems are not closed and therefore in the Hamiltonian contain unknown external parameters that are not the same for the entire mixture. Therefore transitions between pure states and mixed states take place. Those from pure to mixed states take place spontaneously and irreversibly under increase of entropy. Transitions from mixed states to pure states can be fabricated; an example is given. As Wigner's thought experiment of mixing coherently the two beams from a Stern‐Gerlach apparatus according to estimates of Bohm should be impossible by loss of coherence in the gradient magnetic field, it is indicated how Wigner's ideas may be realized by using, instead, polarized light beams from birefringent crystals. After a brief review of the quantum theory of measurements and the various arguments usually given for the reducibility of state after the measurement, Wigner's argument against blind use of these arguments is interpreted as a limit of validity of the familiar probability rule of quantum theory, which should not be applied after an unsuccessful measurement. By splitting light beams coherently by glass plates, one can by the same apparatus have measurements both of the relative intensities of two coherent beams, and of interference effects between the two beams. This shows that complementarity applies to the individual systems in the beam, as they reach the glass plate where a choice must be made between two complementary possibilities of future measurement. Finally, by describing Schrödinger's cat by a density matrix and asking about its time dependence, it is shown that, if it were possible to measure the interference effects between living and dead cats used by some people as a justification for writing down a state vector for the cat, then this measurement could be used to revive some dead cats.
Traditional thermodynamics, built upon the foundation of Hermitian quantum mechanics, primarily describes closed or weakly open systems where energy is conserved. However, the ubiquitous presence of dissipation and gain in realistic physical and biological systems necessitates a more generalized framework. Non-Hermitian quantum mechanics, characterized by Hamiltonians with complex eigenvalues, naturally accounts for such open systems and their interaction with the environment. This paper explores the burgeoning field of non-Hermitian thermodynamics, which aims to extend classical and quantum thermodynamic principles to systems exhibiting energy exchange with their surroundings. We delve into how non-Hermiticity provides a natural language for describing processes involving dissipation, gain, and decoherence, thereby offering a unified perspective on these phenomena. Key concepts such as PT-symmetry, exceptional points, and generalized definitions of work, heat, and entropy in non-Hermitian settings are reviewed. The paper discusses the implications for fundamental thermodynamic laws, the performance of non-Hermitian heat engines, and the role of coherence in energy transport. By embracing the mathematical elegance and physical insights of non-Hermitian physics, we propose a comprehensive framework that unifies the seemingly disparate concepts of dissipation and coherence within a consistent thermodynamic theory, paving the way for advanced applications in quantum technologies, materials science, and biological energy transfer.
We present a coherent and consistent framework for explicit time-dependence in non-Hermitian quantum mechanics. The area of non-Hermitian quantum mechanics has been growing rapidly over the past twenty years. This has been driven by the fact that PT\mathcal{PT}PT-symmetric non-Hermitian systems exhibit real energy eigenvalues and unitary time evolution. Historically, the introduction of time into the world of non-Hermitian quantum mechanics has been a conceptually difficult problem to address, as it requires the Hamiltonian to become unobservable. We solve this issue with the introduction of a new observable energy operator and explain why its instigation is a necessary and natural progression in this setting. For the first time, the introduction of time has allowed us to make sense of the parameter regime in which the PT\mathcal{PT}PT-symmetry is spontaneously broken. Ordinarily, in the time-independent setting, the energy eigenvalues become complex and the wave functions are asymptotically unbounded. We demonstrate that in the time-dependent setting this broken symmetry can be mended and analysis on the spontaneously broken PT\mathcal{PT}PT regime is indeed possible. We provide many examples of this mending on a wide range of different systems, beginning with a 2×22\times22×2 matrix model and extending to higher dimensional matrix models and coupled harmonic oscillator systems with infinite Hilbert space. Furthermore, we use the framework to perform analysis on time-dependent quasi-exactly solvable models. We present the "eternal life" of entropy in this thesis. Ordinarily, for entangled quantum systems coupled to the environments, the entropy decays rapidly to zero. However, in the spontaneously broken regime, we find the entropy decays asymptotically to a non-zero value. We create an elegant framework for Darboux and Darboux/Crum transformations for time-dependent non-Hermitian Hamiltonians.