Quantum dynamics of atoms in number-theory-inspired potentials
Donatella Cassettari, Oleksandr V. Marchukov, B. Carruthers, Harry C. P. Kendell, Joanna Ruhl, B. De Mitchell Pierre, Catalin Zara, Carrie Ann Weidner, Andrea Trombettoni, Maxim Olshanii, Giuseppe Mussardo
In this paper we study transitions of atoms between energy levels of several number-theory-inspired trapping potentials under the effect of time-dependent perturbations. First, we simulate in detail the case of a trap whose single-particle spectrum is given by the prime numbers. We investigate one-body Rabi oscillations and the excitation line shape for two resonantly coupled energy levels, and we show that quantum control is a faster method for state preparation than periodic perturbation. Next, we investigate cascades of such transitions, particularly whether one can construct a quantum system where the existence of a continuous resonant cascade from a given initial energy eigenstate is predicated by the validity of a given statement in number theory. We find that such resonance cascades, in a suitably designed one-body system, can be used to illustrate that the sequence of natural numbers is closed under multiplication. We further present ideas for two more resonance cascade experiments designed to illustrate certain statements within the Diophantus-Brahmagupta-Fibonacci identity and the Goldbach conjecture.
In this paper we study transitions of atoms between energy levels of several number-theory-inspired trapping potentials under the effect of time-dependent perturbations. First, we simulate in detail the case of a trap whose single-particle spectrum is given by the prime numbers. We investigate one-body Rabi oscillations and the excitation line shape for two resonantly coupled energy levels, and we show that quantum control is a faster method for state preparation than periodic perturbation. Next, we investigate cascades of such transitions, particularly whether one can construct a quantum system where the existence of a continuous resonant cascade from a given initial energy eigenstate is predicated by the validity of a given statement in number theory. We find that such resonance cascades, in a suitably designed one-body system, can be used to illustrate that the sequence of natural numbers is closed under multiplication. We further present ideas for two more resonance cascade experiments designed to illustrate certain statements within the Diophantus-Brahmagupta-Fibonacci identity and the Goldbach conjecture.
We consider the general scenario of an excited level $|i\ensuremath{\rangle}$ of a quantum system that can decay via two channels: (i) via a single-quantum jump to an intermediate, resonant level $|\overline{m}\ensuremath{\rangle}$, followed by a second single-quantum jump to a final level $|f\ensuremath{\rangle}$, and (ii) via a two-quantum transition to a final level $|f\ensuremath{\rangle}$. Cascade processes $|i\ensuremath{\rangle}\ensuremath{\rightarrow}|\overline{m}\ensuremath{\rangle}\ensuremath{\rightarrow}|f\ensuremath{\rangle}$ and two-quantum transitions $|i\ensuremath{\rangle}\ensuremath{\rightarrow}|m\ensuremath{\rangle}\ensuremath{\rightarrow}|f\ensuremath{\rangle}$ compete (in the latter case, $|m\ensuremath{\rangle}$ can be both a nonresonant as well as a resonant level). General expressions are derived within second-order time-dependent perturbation theory, and the cascade contribution is identified. When the one-quantum decay rates of the virtual states are included into the complex resonance energies that enter the propagator denominator, it is found that the second-order decay rate contains the one-quantum decay rate of the initial state as a lower-order term. For atomic transitions, this implies that the differential-in-energy two-photon transition rate with complex resonance energies in the propagator denominators can be used to good accuracy even in the vicinity of resonance poles.
The familiar Rabi model, comprising a two-level system coupled to a quantum harmonic oscillator, continues to produce rich and surprising physics when the coupling strength becomes comparable to the individual subsystem frequencies. We construct approximate solutions for the eigenstates and energies in the regime in which the oscillator frequency is small compared to that of the two-level system and the coupling strength matches or exceeds the oscillator frequency. The resulting oscillator dynamics closely resembles that of a particle tunneling in a classical double-well potential. Relating our calculation to an earlier semiclassical approximation in which coupling to the two-level system creates an effective potential for the oscillator, we examine the extent to which this picture is valid. We find that, for certain parameter regimes, the interpretation of the oscillator dynamics in terms of tunneling holds to a good approximation despite the fundamentally entangled nature of the joint system. We assess the prospects for observation of oscillator tunneling in the context of nano- or micromechanical experiments and find that it should be possible if suitably high coupling strengths can be engineered.
Small (but still containing many, about 10 2 -10 4 , atoms) quantum systems (traditionally termed nano-systems) are dramatically different from their macroscopic or genuine microscopic (atomic) cousins.Microscopic molecular systems (with a few atoms) obey a regular quantum dynamics (described by time dependent Schrodinger equation), whereas in macroscopic systems with continuous energy spectra, one can expect, also regular, although typically relaxation, dynamic behavior.The topic of our paper is in-between these limits.Nano-scale systems are characterized by small (but finite) mean inter-level spacing.In such a case with recurrence periods in pico-second range, Loschmidt echo and double resonance phenomena come into the game.System behavior becomes non-trivial and manifests a sort of transitions between regular and chaotic dynamics.We show that such dynamic transitions occur when the Loschmidt echo time of life exceeds the typical recurrence cycle period.We illustrate this behavior in the frame work of a few versions of the exactly solvable quantum problem, proposed long ago by Zwanzig.It is based on the study of time evolution of the initially prepared vibrational state coupled to a reservoir with dense spectrum of its vibrational states.In the simplest version of the Zwanzig model, the reservoir has an equidistant spectrum, and the system -reservoir coupling matrix elements are independent of the reservoir states.We generalize the model to include into consideration the coupling of the initially prepared single state to system phonon excitations.The coupling results to temperature dependent broadening and decay of the echo components.Another generalization is to replace a single level by two states coupled to the Zwanzig reservoir.We anticipate that the basic ideas inspiring our work can be applied to a large variety of interesting for the applications nano-systems (e.g., dissipative free propagation of excitations along molecular chains, or as a model for exchange reactions).
The multiple-linear-time-scale method is used to construct a perturbation theory for N-level quantum systems subjected to time-dependent perturbations. The secular and small-denominator terms which plague conventional time-dependent perturbation theory are avoided; consequently, the theory is useful for treating long-term behavior and resonant interactions. The introduction of a self-energy operator allows the shifts in energy levels to be displayed explicitly. When the perturbation is the dipole interaction with an electromagnetic field, the successive approximations yield the well-known rotating-wave approximation, corrections due to counter rotating terms, and the Bloch-Siegert frequency shift. The formalism is applicable to arbitrary pulse shapes, provided that $\ensuremath{\parallel}{H}_{1}\ensuremath{\parallel}\ensuremath{\ll}\ensuremath{\hbar}\overline{\ensuremath{\omega}}$, where $\ensuremath{\parallel}{H}_{1}\ensuremath{\parallel}$ represents the inter-action strength and $\overline{\ensuremath{\omega}}$ is a characteristic frequency of the field. Rabi oscillations induced by multiphoton resonances are automatically included, and this effect is demonstrated in the case of a square pulse with frequency approximately one half the resonance frequency for a transition between two vibrational levels of a molecule. These calculations are compared to an exact numerical solution in order to find the limits of validity of the approximation. Even at high intensities ($I\ensuremath{\sim}{10}^{14}$ W/cm2) the shifted resonance frequency is quite accurate; however, the approximate and exact solutions are slightly out of phase, so that the approximate solution can only be trusted for a few Rabi cycles. For much lower intensities ($I\ensuremath{\sim}{10}^{10}$ W/cm2), the approximate solution is valid for many thousands of Rabi cycles.
Abstract Small (but still containing many, about 102–104, atoms) quantum systems (traditionally termed nano-systems) are dramatically different from their macroscopic or genuine microscopic (atomic) cousins. Microscopic molecular systems (with a few atoms) obey a regular quantum dynamics (described by time dependent Schrödinger equation), whereas in macroscopic systems with continuous energy spectra, one can expect, also regular, although typically relaxation, dynamic behavior. The topic of our paper is in between these limits. Nano-scale systems are characterized by small (but finite) mean interlevel spacing. In such a case with recurrence periods in picosecond range, Loschmidt echo and double resonance phenomena come into the game. System behavior becomes nontrivial and manifests a sort of transitions between regular and chaotic dynamics. We show that such dynamic transitions occur when the Loschmidt echo time of life exceeds the typical recurrence cycle period. We illustrate this behavior in the frame work of a few versions of the exactly solvable quantum problem, proposed long ago by Zwanzig. It is based on the study of time evolution of the initially prepared vibrational state coupled to a reservoir with dense spectrum of its vibrational states. In the simplest version of the Zwanzig model, the reservoir has an equidistant spectrum, and the system—reservoir coupling matrix elements are independent of the reservoir states. We generalize the model to include into consideration the coupling of the initially prepared single state to system phonon excitations. The coupling results to temperature dependent broadening and decay of the echo components. Another generalization is to replace a single level by two states coupled to the Zwanzig reservoir. We anticipate that the basic ideas inspiring our work can be applied to a large variety of interesting for the applications nanosystems (e.g., dissipative free propagation of excitations along molecular chains, or as a model for exchange reactions).
We study the nonlinear quantum Rabi model---both in the two-photon and the intensity-dependent coupling scheme---by utilizing the perturbation method in the off- and near-resonance regimes characterized by the field and the atomic transition frequencies. We consider the weak-coupling condition, the perturbation parameter being the ratio between the coupling constant and the atomic frequency. For both models we determine the first- and second-order corrections to energy eigenvalues and eigenstates, disclosing the doublet structure characterizing the energy spectrum. Then we apply our findings to both the coupling schemes in order to calculate the time evolution of a general initial state and the atomic population inversion for an initial state composed by a mixture of excited and unexcited atoms.