The maximum unitarily extractable work from a quantum system---ergotropy---is the basic principle behind quantum batteries, a rapidly emerging field. This work studies ergotropy in two quantum chaotic systems, the quantum kicked top and the kicked Ising spin chain, to illustrate the effects of chaotic dynamics. In an ancilla-assisted scenario, chaos enhances ergotropy when the state is known, a consequence of large entanglement production in the chaotic regime. When the state is unknown, we need to at least partially characterize the state using coarse-grained measurements for useful extraction of work. In this case, chaos impedes ergotropy by suppressing information gained from coarse-grained measurements, while entanglement with an ancilla still facilitates ergotropy. In this scenario, we study the interplay between chaos and entanglement and find a sweet spot in the chaos parameter for optimal work. Our results point to the potential of quantum chaos-assisted batteries for better work extraction.
The maximum unitarily extractable work from a quantum system---ergotropy---is the basic principle behind quantum batteries, a rapidly emerging field. This work studies ergotropy in two quantum chaotic systems, the quantum kicked top and the kicked Ising spin chain, to illustrate the effects of chaotic dynamics. In an ancilla-assisted scenario, chaos enhances ergotropy when the state is known, a consequence of large entanglement production in the chaotic regime. When the state is unknown, we need to at least partially characterize the state using coarse-grained measurements for useful extraction of work. In this case, chaos impedes ergotropy by suppressing information gained from coarse-grained measurements, while entanglement with an ancilla still facilitates ergotropy. In this scenario, we study the interplay between chaos and entanglement and find a sweet spot in the chaos parameter for optimal work. Our results point to the potential of quantum chaos-assisted batteries for better work extraction.
Energy extraction is a central task in thermodynamics. In quantum physics, ergotropy measures the amount of work extractable under cyclic Hamiltonian control. As its full extraction requires perfect knowledge of the initial state, however, it does not characterize the work value of unknown or untrusted quantum sources. Fully characterizing such sources would require quantum tomography, which is prohibitively costly in experiments due to the exponential growth of required measurements and operational limitations. Here, we therefore derive a new notion of ergotropy applicable when nothing is known about the quantum states produced by the source, apart from what can be learned by performing only a single type of coarse-grained measurement. We find that in this case the extracted work is defined by the Boltzmann and observational entropy in cases where the measurement outcomes are, or are not, used in the work extraction, respectively. This notion of ergotropy represents a realistic measure of extractable work, which can be used as the relevant figure of merit to characterize a quantum battery.
We investigate the dynamics of quantum ergotropy in a multipartite system of two-level atoms interacting with a quantized field. The role of multipartite quantum mutual information and quantum relative entropy is analyzed to understand how correlations and the distinguishability between the passive state and the product of local states affect the extractable work. Numerical results for systems containing two to five atoms show that the maximum ergotropy does not increase linearly with the system size, while the intervals of zero ergotropy are gradually modified and suppressed for larger systems. We also study the effect of the average thermal photon number and different initial atomic states. Increasing the thermal photon number mainly reduces the relative-entropy contribution, whereas the initial state strongly influences both the magnitude and persistence of ergotropy. Among the considered states, the partially entangled state provides the largest and more persistent extractable work, while the mixed GHZ state gives the smallest ergotropy. These results highlight the importance of multipartite correlations, thermal effects, and state preparation in controlling quantum work extraction and may be useful for future studies of quantum batteries and quantum power.
The amount of work that can be extracted from a quantum system can be increased by exploiting the information obtained from a measurement performed on a correlated ancillary system. The concept of daemonic ergotropy has been introduced to properly describe and quantify this work extraction enhancement in the quantum regime. We here explore the application of this idea in the context of continuously monitored open quantum systems, where information is gained by measuring the environment interacting with the energy-storing quantum device. We first show that the corresponding daemonic ergotropy takes values between the ergotropy and the energy of the corresponding unconditional state. The upper bound is achieved by assuming an initial pure state and a perfectly efficient projective measurement on the environment, independently of the kind of measurement performed. On the other hand, if the measurement is inefficient or the initial state is mixed, the daemonic ergotropy is generally dependent on the measurement strategy. This scenario is investigated via a paradigmatic example of an open quantum battery: a two-level atom driven by a classical field and whose spontaneously emitted photons are continuously monitored via either homodyne, heterodyne, or photodetection.
Going beyond isolated system dynamics, we examine how local and spatially correlated reservoirs influence the work extraction in quantum batteries. By employing a one-dimensional spin-1/2 model coupled to baths via dephasing and amplitude-damping noise, we demonstrate that correlations in reservoirs can significantly enhance battery's performance compared to local noise. In the dephasing scenario, we prove that correlated reservoirs produce a finite amount of extractable work, or ergotropy, during the transient regime when a two-cell battery is initialized in a product state while local noise yields vanishing ergotropy at all times, despite nonvanishing stored energy in both cases. Numerical simulations confirm that this advantage persists across larger system sizes and for both entangled and product initial states. We also find that the dynamics of quantum coherence closely mirror those of ergotropy, highlighting coherence as a key resource underlying the enhanced performance of quantum batteries. Further, we observe that the fraction of stored energy extracted from quantum batteries displays a sharper contrast between the correlated and local reservoirs. Moreover, for dephasing noise, this fraction remains independent of system size, whereas in the amplitude damping case, it exhibits a clear system-size dependence within the transient regime, highlighting distinct operational behaviors under different noise models. In addition, we reveal that when the battery dynamics is governed by an effective Hamiltonian with long-range interactions, it yields higher ergotropy compared to short-range interactions, emphasizing the advantages of reservoir engineering for efficient device design.
Maximum quantum work extraction is generally defined in terms of the ergotropy functional, no matter how experimentally complicated is the implementation of the optimal unitary allowing for it, especially in the case of multipartite systems. In this framework, we consider a quantum battery made up of many interacting subsystems and study the maximum extractable work via concurrent local unitary operations on each subsystem. We call the resulting functional parallel ergotropy. Focusing on the bipartite case, we first observe that parallel ergotropy outperforms work extraction via egoistic strategies, in which the first agent A extracts locally on its part the maximum available work and the second agent B, subsequently, extracts what is left on the other part. For the agents, this showcases the need of cooperating for an overall benefit. Second, from the informational point of view, we observe that the parallel capacity of a state can detect entanglement and compare it with the statistical entanglement witness that exploits fluctuations of stochastic work extraction. Additionally, we face the technical problem of computing parallel ergotropy. We derive analytical upper bounds for specific classes of states and Hamiltonians and provide recipes to obtain numerical upper bounds via semidefinite programming in the generic case. Finally, extending the concept of parallel ergotropy, we demonstrate that system's free-time evolution and application of local unitaries allow one to saturate the gap with the ergotropy of the whole system.
In this paper, we investigate the effects of spin squeezing on two-coupled quantum kicked tops, which have been previously shown to exhibit a quantum signature of chaos in terms of entanglement dynamics. Our results show that initial spin squeezing can lead to an enhancement in both the entanglement rate and the asymptotic entanglement for kicked tops when the initial state resides in the regular islands within a mixed classical phase space. On the other hand, we found a reduction in these two quantities if we were to choose the initial state deep inside the chaotic sea. More importantly, we have uncovered that an application of periodic spin squeezing can yield the maximum attainable entanglement entropy, albeit this is achieved at a reduced entanglement rate.