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arXiv:2409.02187 · Physical review. B./Physical review. B

Late-time ensembles of quantum states in quantum chaotic systems

Souradeep Ghosh, Christopher M. Langlett, Nicholas Hunter-Jones, Joaquin F. Rodriguez-Nieva

Published Aug 13, 2025• 4 citations
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Abstract

Initially unentangled states undergoing quantum chaotic dynamics are expected to evolve into featureless states at late times. While this expectation holds true on an averaged, coarse-grained level, it is unclear if this expectation applies to higher statistical moments, as symmetries present in physical systems constrain the exploration of Hilbert space. Here, we study the universal structure of late-time ensembles obtained from unitary dynamics in quantum chaotic systems with symmetries, such as charge or energy conservation. We find that while quantum states do not ergodically explore the entire Hilbert space at late times, the late-time ensemble typically becomes indistinguishable from Haar random states in the thermodynamic limit and at the level of finite statistical moments. Importantly, our results apply to initial states that are easy to prepare in ongoing experiments---specifically, product states---that lie in the middle of the spectrum of quantum chaotic systems. We show that typically these states not only exhibit the same late-time ensemble average as Haar random states, but also the same state-to-state fluctuations and higher statistical moments. In other words, there is no measurement---whether local or nonlocal---that one can perform at the level of finite statistical moments to tell that states are not exploring the entire Hilbert space. Interestingly, within the class of low-entanglement initial states, we also find atypical initial conditions in the middle of the spectrum of Hamiltonians known to be ``maximally chaotic''. Such atypical initial states have smaller variance of the symmetry operator relative to that of Haar random states, and evolve into nonuniversal ensembles that can be distinguished from the Haar ensemble by simple measurements or subsystem properties. In the limiting case of initial states with negligible variance of the symmetry operator (e.g., states with fixed particle number or energy eigenstates), the late-time ensemble has universal behavior captured by constrained random state ensembles. On the one hand, our results reveal that an extremely high level of quantum state randomness can typically be achieved even when dynamics are constrained by symmetries; on the other hand, our results show that one can still achieve strongly nonergodic dynamics at ``infinite temperature'' within quantum chaotic regimes.

DOI
10.1103/bwr6-vskn

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Initially unentangled states undergoing quantum chaotic dynamics are expected to evolve into featureless states at late times. While this expectation holds true on an averaged, coarse-grained level, it is unclear if this expectation applies to higher statistical moments, as symmetries present in physical systems constrain the exploration of Hilbert space. Here, we study the universal structure of late-time ensembles obtained from unitary dynamics in quantum chaotic systems with symmetries, such as charge or energy conservation. We find that while quantum states do not ergodically explore the entire Hilbert space at late times, the late-time ensemble typically becomes indistinguishable from Haar random states in the thermodynamic limit and at the level of finite statistical moments. Importantly, our results apply to initial states that are easy to prepare in ongoing experiments---specifically, product states---that lie in the middle of the spectrum of quantum chaotic systems. We show that typically these states not only exhibit the same late-time ensemble average as Haar random states, but also the same state-to-state fluctuations and higher statistical moments. In other words, there is no measurement---whether local or nonlocal---that one can perform at the level of finite statistical moments to tell that states are not exploring the entire Hilbert space. Interestingly, within the class of low-entanglement initial states, we also find atypical initial conditions in the middle of the spectrum of Hamiltonians known to be maximally chaotic''. Such atypical initial states have smaller variance of the symmetry operator relative to that of Haar random states, and evolve into nonuniversal ensembles that can be distinguished from the Haar ensemble by simple measurements or subsystem properties. In the limiting case of initial states with negligible variance of the symmetry operator (e.g., states with fixed particle number or energy eigenstates), the late-time ensemble has universal behavior captured by constrained random state ensembles. On the one hand, our results reveal that an extremely high level of quantum state randomness can typically be achieved even when dynamics are constrained by symmetries; on the other hand, our results show that one can still achieve strongly nonergodic dynamics at infinite temperature'' within quantum chaotic regimes.
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Randomness generation through quantum-chaotic evolution underpins foundational questions in statistical mechanics and applications across quantum information science, including benchmarking, tomography, metrology, and demonstrations of quantum computational advantage. While statistical mechanics successfully captures the temporal averages of local observables, understanding randomness at the level of higher statistical moments remains a daunting challenge, with analytic progress largely confined to random quantum circuit models or fine-tuned systems exhibiting space-time duality. Here we study how much randomness can be dynamically generated by generic quantum-chaotic evolution under physical, non-random Hamiltonians. Combining theoretical insights with numerical simulations, we show that for broad classes of initially unentangled states, the dynamics become effectively Haar-random well before the system can ergodically explore the physically accessible Hilbert space. Both local and highly nonlocal observables, including entanglement measures, equilibrate to their Haar expectation values and fluctuations on polynomial timescales with remarkably high numerical precision, and with the fastest randomization occurring in regions of parameter space previously identified as maximally chaotic. Interestingly, this effective randomization can occur on timescales linear in system size, suggesting that the sub-ballistic growth of Renyi entropies typically observed in systems with conservation laws can be bypassed in non-random Hamiltonians with an appropriate choice of initial conditions.
Understanding the emergence of chaos in many-body quantum systems away from semi-classical limits, particularly in spatially local interacting spin Hamiltonians, has been a long-standing problem. In these intrinsically quantum regimes, quantum chaos has been primarily understood through the correspondence between the eigensystem statistics of midspectrum eigenstates and the universal statistics described by random matrix theory (RMT). However, this correspondence no longer holds for finite-temperature eigenstates. Here we show that the statistical properties of finite-temperature eigenstates of quantum chaotic Hamiltonians can be accurately described by pure random states constrained by a local charge, with the average charge density of the constrained random state ensemble playing the same role as the average energy density of the eigenstates. By properly normalizing the energy density using a single Hamiltonian-dependent parameter that quantifies the typical energy per degree of freedom, we find excellent agreement between the entanglement entropy statistics of eigenstates and that of constrained random states. Interestingly, in small pockets of Hamiltonian parameter phase space which we previously identified as `maximally chaotic' [PRX 14, 031014 (2024)], we find excellent agreement not only at the level of the first moment, including O(1) corrections, but also at the level of statistical fluctuations. These results show that notions of maximal chaos -- in terms of how much randomness eigenstates contain -- can still be defined at finite temperature in physical Hamiltonian models away from semi-classical and large-NNN limits.
Our current understanding of quantum chaos in many-body quantum systems hinges on the random matrix theory (RMT) behavior of eigenstates and their energy level statistics. Although RMT has been remarkably successful in describing "coarse" features of many-body quantum Hamiltonians in chaotic regimes, such as the Wigner-Dyson level spacing statistics or the volume-law behavior of eigenstate entanglement entropy, it remains a challenge to describe their "finer" features, particularly those arising from spatial locality. Here, we show that we can accurately describe the statistical behavior of eigenstate ensembles in many-body Hamiltonians by using pure random states with physical constraints that capture the essential features of the Hamiltonian, specifically spatial locality and symmetries. We demonstrate our approach on local spin Hamiltonians with a scalar U(1) charge. By constructing ensembles of constrained random states that account for two commuting scalar charges playing the role of energy and magnetization, we describe the patterns of entanglement of midspectrum eigenstates beyond their average volume-law behavior, including O(1) corrections and fluctuations, analytically and numerically. When defining the correspondence between quantum chaotic eigenstates in many-body Hamiltonians and RMT ensembles, our work highlights the important role played by spatial locality in describing universal features beyond the volume-law behavior.
The eigenstate thermalization hypothesis conjectures that for a thermodynamically large system in one of its energy eigenstates, the reduced density matrix describing any finite subsystem is determined solely by a set of relevant conserved quantities. In a chaotic quantum system, only the energy is expected to play that role and hence eigenstates appear locally thermal. Integrable systems, on the other hand, possess an extensive number of such conserved quantities and therefore the reduced density matrix requires specification of all the corresponding parameters (generalized Gibbs ensemble). However, here we show by unbiased statistical sampling of the individual eigenstates with a given finite energy density that the local description of an overwhelming majority of these states of even such an integrable system is actually Gibbs-like, i.e., requires only the energy density of the eigenstate. Rare eigenstates that cannot be represented by the Gibbs ensemble can also be sampled efficiently by our method and their local properties are then shown to be described by appropriately truncated generalized Gibbs ensembles. We further show that the presence of these rare eigenstates differentiates the model from the chaotic case and leads to the system being described by a generalized Gibbs ensemble at long time under a unitary dynamics following a sudden quench, even when the initial state is a typical (Gibbs-like) eigenstate of the prequench Hamiltonian.
We report universal statistical properties displayed by ensembles of pure states that naturally emerge in quantum many-body systems. Specifically, two classes of state ensembles are considered: those formed by (i) the temporal trajectory of a quantum state under unitary evolution or (ii) the quantum states of small subsystems obtained by partial, local projective measurements performed on their complements. These cases, respectively, exemplify the phenomena of “Hilbert-space ergodicity” and “deep thermalization.” In both cases, the resultant ensembles are defined by a simple principle: The distributions of pure states have maximum entropy, subject to constraints such as energy conservation, and effective constraints imposed by thermalization. We present and numerically verify quantifiable signatures of this principle by deriving explicit formulas for all statistical moments of the ensembles, proving the necessary and sufficient conditions for such universality under widely accepted assumptions, and describing their measurable consequences in experiments. We further discuss information-theoretic implications of the universality: Our ensembles have maximal information content while being maximally difficult to interrogate, establishing that generic quantum state ensembles that occur in nature hide (scramble) information as strongly as possible. Our results generalize the notions of Hilbert-space ergodicity to time-independent Hamiltonian dynamics and deep thermalization from infinite to finite effective temperature. Our work presents new perspectives to characterize and understand universal behaviors of quantum dynamics using statistical and information-theoretic tools. Published by the American Physical Society 2024