Abstract Isolated quantum systems follow a reversible unitary evolution, which seems inconsistent with the irreversibility of macroscopic thermodynamics. We notice that such a paradox can be reconciled when focusing on the local relaxation process. Here, we study the exact dynamics of an isolated system, which contains a finite number of three-level systems. When focusing on the dynamics of local states and local observables, irreversible behaviors naturally appear. Though the entropy of the full many-body state always remains unchanged, the total correlation entropy of this system exhibits an irreversibly increasing behavior. Moreover, our variation analysis shows that, the total correlation entropy would achieve its theoretical maximum if each site is in a generalized one-body Boltzmann state, which is not solely determined by the energy but also depends on the onsite pseudo-spins, and such a theoretical correlation maximum is highly coincidental with the exact time evolution. In this sense, the total correlation entropy serves well as a generalized indicator for the dynamical irreversibility of the nonequilibrium relaxation in this isolated system.
Abstract Isolated quantum systems follow a reversible unitary evolution, which seems inconsistent with the irreversibility of macroscopic thermodynamics. We notice that such a paradox can be reconciled when focusing on the local relaxation process. Here, we study the exact dynamics of an isolated system, which contains a finite number of three-level systems. When focusing on the dynamics of local states and local observables, irreversible behaviors naturally appear. Though the entropy of the full many-body state always remains unchanged, the total correlation entropy of this system exhibits an irreversibly increasing behavior. Moreover, our variation analysis shows that, the total correlation entropy would achieve its theoretical maximum if each site is in a generalized one-body Boltzmann state, which is not solely determined by the energy but also depends on the onsite pseudo-spins, and such a theoretical correlation maximum is highly coincidental with the exact time evolution. In this sense, the total correlation entropy serves well as a generalized indicator for the dynamical irreversibility of the nonequilibrium relaxation in this isolated system.
Inside a closed many-body system undergoing the unitary evolution, a small partition of the whole system exhibits a local relaxation. If the total degrees of freedom of the whole system is a large but finite number, such a local relaxation would come across a recurrence after a certain time, namely, the dynamics of the local system suddenly appears random after a well-ordered oscillatory decay process. It is found in this paper, among a collection of N two-level systems (TLSs), the local relaxation of one TLS inside has a hierarchy structure hiding in the randomness after such a recurrence: similar recurrences appear in a periodical way, and the later recurrence brings in stronger randomness than the previous one. Both analytical and numerical results that we obtained well explains such hierarchy recurrences: the population of the local TLS (as an open system) diffuses out and regathers back periodically due to the finite-size effect of the bath [the remaining $(\mathrm{N}\ensuremath{-}1)$ TLSs]. We also find that the total correlation entropy, which sums up the entropy of all the n TLSs, approximately exhibit a monotonic increase; in contrast, the entropy of each single TLS increases and decreases from time to time, and the entropy of the whole n-body system keeps constant during the unitary evolution.
Understanding how macroscopic systems exhibit irreversible thermal behavior has been a longstanding challenge, first brought to prominence by Boltzmann. Recent advances have established rigorous conditions for isolated quantum systems to equilibrate to a maximum entropy state, contingent upon weak assumptions. These theorems, while powerful, applied for a sudden quench. However, natural processes involve finite-time perturbations or quenches, which raises a crucial question: Can these systems still equilibrate under more realistic, finite-time dynamics? In this work, we extend the established results to account for finite-time quenches, demonstrating that, even under finite-time perturbations, the system will equilibrate provided it populates many significant energy levels. While the mathematical proof is more intricate than in the instantaneous case, the physical conclusion remains the same: sufficient perturbation leads to equilibration. Our results provide a broader and more physically realistic framework for understanding thermalization in isolated quantum systems.
The description of the non-equilibrium dynamics of isolated quantum many-body systems within the framework of statistical mechanics is a fundamental open question. Conventional thermodynamical ensembles fail to describe the large class of systems that exhibit nontrivial conserved quantities, and generalized ensembles have been predicted to maximize entropy in these systems. We show experimentally that a degenerate one-dimensional Bose gas relaxes to a state that can be described by such a generalized ensemble. This is verified through a detailed study of correlation functions up to 10th order. The applicability of the generalized ensemble description for isolated quantum many-body systems points to a natural emergence of classical statistical properties from the microscopic unitary quantum evolution.
Understanding how macroscopic thermodynamic behavior emerges from microscopic quantum dynamics remains an open problem. While equilibration of quantum observables is well established, thermodynamics also relies on variables not directly associated with linear operators, but which are defined instead as functions of expectation values. Whether and how such derived quantities inherit equilibration properties is an open question. Here, we establish that any continuously differentiable function of equilibrating expectation values also equilibrates. We apply this result to a bipartite isolated system, showing that the entropy and conjugate variables of each subsystem -- defined through Jaynes' maximum entropy principle -- equilibrate. Moreover, with the assumption that their equilibrium properties depend solely on local conserved quantities, we show the dynamical maximization of the total entropy, enforcing equality of conjugate variables across subsystems. These results provide a direct dynamical justification for entropy maximization and the emergence of thermodynamic equilibrium conditions, showing that fundamental principles of thermodynamics follow from the unitary evolution of quantum systems.
Time-reversal had always been assumed to be a symmetry of physics at the fundamental level. In this paper we will explore the violations of time-reversal symmetry at the fundamental level and the consequence on thermodynamic systems. First, we will argue from current physics that the universe dynamics is not time-reversal invariant. Second, we will argue that any thermodynamic system cannot be isolated completely from the universe. We then discuss how these two make the dynamics of thermodynamics systems very weakly irreversible at the classical and quantum level. Since time-reversal is no longer a symmetry of realistic systems, the problem of how macroscopic irreversibility arises from microscopic reversibility becomes irrelevant because there is no longer microscopic reversibility. At the classical level of a thermodynamic system, we show that the H theorem of Boltzmann is still valid even without microscopic reversibility. We do this by deriving a modified H theorem, which still shows entropy monotonically increasing. At the quantum level, we explicitly show the effect of CP violation, small irreversible changes on the internal states of the nuclear and atomic energy levels of thermodynamic systems. Thus, we remove Loschmidt's objection to Boltzmann's ideas.
We address the longstanding challenge in quantum many-body theory of reconciling unitary dynamics with irreversible relaxation. In classical chaos, the unitary evolution operator develops Ruelle-Pollicott (RP) resonances inside the unit circle in the continuum limit, leading to mixing. In the semiclassical limit, chaotic single-particle quantum systems relax with the same RP resonances. In contrast, the theory of quantum many-body RP resonances and their link to irreversibility remain underdeveloped. Here, we relate the spectral form factor to the sum of autocorrelation functions and, in generic many-body lattice systems without conservation laws, we argue that all quantum many-body RP resonances converge inside the unit disk, highlighting the role of nonunitary and the thermodynamic limit. While we conjecture this picture to be general, we analytically prove the emergence of irreversibility in the random phase model (RPM), a paradigmatic Floquet quantum circuit model, in the limit of large local Hilbert space dimension. To this end, we couple it to local environments and compute the exact time evolution of autocorrelation functions, the dissipative form factor, and out-of-time-order correlation functions (OTOCs). Although valid for any dissipation strength, we then focus on weak dissipation to clarify the origin of irreversibility in unitary systems. When the dissipationless limit is taken after the thermodynamic limit, the unitary quantum map develops an infinite tower of decaying RP resonances-chaotic systems display so-called anomalous relaxation. We identify the exact RP resonances in the RPM and prove that the same RP resonances are obtained from operator truncation. We also show that the OTOC in the RPM can undergo a two-stage relaxation, and that during the second stage, the approach to the stationary value is again controlled by the leading RP resonance. Finally, we demonstrate how conservation laws, many-body localization, and nonlocal interactions merge the leading RP resonance into the unit circle, thereby suppressing anomalous relaxation. Our findings clarify the microscopic origin of macroscopic relaxation in quantum systems and emphasize the role of RP resonances as a largely unexplored signature of many-body quantum chaos.