Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:2406.13410 · Physical Review X

Exploring Atom-Ion Feshbach Resonances below the s -Wave Limit

Fabian Thielemann, Joachim Siemund, Daniel von Schoenfeld, Wei Wu, Pascal Weckesser, Krzysztof Jachymski, Thomas Walker, Tobias Schaetz

Published Mar 7, 2025• 7 citations
arXivHTMLPDF

Abstract

Hybrid systems of single, trapped ions embedded in quantum gases are a promising platform for quantum simulations and the study of long-range interactions in the ultracold regime. Feshbach resonances allow for experimental control over the character and strength of the atom-ion interaction. However, the complexity of atom-ion Feshbach spectra, e.g., due to second-order spin-orbit coupling, requires a detailed experimental understanding of the resonance properties—such as the contributing open-channel partial waves. In this work, we immerse a single barium ( Ba + ) ion in a bath of lithium (Li) atoms spin polarized in their hyperfine ground state to investigate the collision energy dependence of magnetically tunable atom-ion Feshbach resonances. We demonstrate fine control over the kinetic energy of the Ba + ion and employ it to explore three-body recombination in the transition from the many- to the few-partial wave regime, marked by a sudden increase of resonant loss. In a dense spectrum—with on average 0.58(1) resonances per Gauss—we select a narrow, isolated feature and characterize it as an s -wave resonance. We introduce a quantum recombination model that allows us to distinguish it from higher-partial-wave resonances. Furthermore, in a magnetic field range with no significant loss at the lowest collision energies, we identify a higher-partial-wave resonance that appears and peaks only when we increase the energy to around the s -wave limit. Our results demonstrate that hybrid atom-ion traps can reach collision energies well in the ultracold regime and that the ion’s kinetic energy can be employed to tune the collisional complex to resonance, paving the way for fast control over the interaction in settings where magnetic field variations are detrimental to coherence.

DOI
10.1103/physrevx.15.011051

Related papers

Sub-barrier peaks in atom-atom-ion three-body recombination

Fabian Thielemann, Joachim Siemund, Tobias Schaetz +1 more

Hybrid atom-ion experiments have recently entered the few-partial wave regime in which magnetically tunable Feshbach resonances dominate the three-body loss dynamics. This necessitates a treatment of three-body recombination that can incorporate the role of the resonant dimer channel. Here, we develop a two-step Lindemann-type model for resonant atom-atom-ion three-body recombination that combines multichannel quantum-defect theory for the long-range polarization potential with a universal quantum-capture treatment of the inelastic atom-dimer step. We show that within our model, rate competition can lead to a peak in the three-body-recombination cross section of higher partial-wave channels at energies well below their corresponding centrifugal barrier. Investigating the resulting loss rates under numerically obtained non-thermal collision-energy distributions, we find that these effects survive the energy averaging and can be observed in state-of-the-art hybrid experimental setups. Our findings pave the way for a detailed characterization of atom-ion Feshbach resonances via the analysis of inelastic three-body-recombination processes.

arXiv:2609.04106•Sep 3, 2026•0 citations

Quantum control of ion-atom collisions beyond the ultracold regime

Maks Z. Walewski, Matthew D. Frye, Or Katz +3 more

Tunable scattering resonances are crucial for controlling atomic and molecular systems. However, their use has so far been limited to ultracold temperatures. These conditions remain hard to achieve for most hybrid trapped ion-atom systems—a prospective platform for quantum technologies and fundamental research. Here, we measure inelastic collision probabilities for Sr + + Rb and use them to calibrate a comprehensive theoretical model of ion-atom collisions. Our theoretical results, compared with experimental observations, confirm that quantum interference effects persist to the multiple-partial-wave regime, leading to the pronounced state and mass dependence of the collision rates. Using our model, we go beyond interference and identify a rich spectrum of Feshbach resonances at moderate magnetic fields with the Rb atom in its lower ( f = 1) hyperfine state, which persist at temperatures as high as 1 millikelvin. Future observation of these predicted resonances should allow precise control of the short-range dynamics in Sr + + Rb collisions under unprecedentedly warm conditions.

arXiv:2407.06073•Science Advances•Feb 5, 2025•8 citations

Quantum statistics on atom–ion Feshbach resonances

Joachim Siemund

Hybrid atom-ion systems combine the precise control of a single radio-frequency-trapped atomic ion with the rich few- to many-body phenomena of ultracold degenerate quantum gases trapped in light fields. The associated long-range interaction enables studies of impurity physics and the implementation of a single-particle quantum gas microscope, sensitive to quantities beyond the atomic density, including energy distributions, atom-atom couplings, and many-body exchange symmetry. This perspective requires atom-ion coupling, which can be tuned through resonantly enhanced scattering. While atom-ion Feshbach resonances have recently become experimentally accessible, the role of quantum statistics in resonantly enhanced three-body recombination remains largely unexplored. This thesis investigates the role of fermionic quantum statistics in atom-atom-ion three-body recombination. The experiment employs a single 138Ba+ ion immersed in an ultracold two-component Fermi gas of 6Li. An atom-ion Feshbach resonance enables resonantly enhanced recombination for one spin component, while the other component acts as a non-resonant spectating collision partner. This allows a direct comparison between recombination processes involving identical and distinguishable fermions. Experimentally, recombination rates are extracted from bath polarization-dependent ion-loss spectroscopy. Expressing the results as relative rate constants largely detaches them from the total atomic density and results in suppression of recombination in the identical fermion channel. Additional measurements of two-body reactive collisions are combined with simulations of the Fermi gas, demonstrating that density modifications arising from Fermi-Dirac statistics or mutual atom-atom attraction are insufficient to explain the observed recombination behavior. To interpret the measurements, an extension of the conventional two-step model is developed. Using a hyperspherical treatment that includes all pairwise interactions and fermionic exchange symmetry, effective relaxation rates for the loosely-bound atom-ion complex are obtained. The calculations predict a suppression of recombination involving identical fermions relative to distinguishable collision partners. The experimental observations are consistent with this prediction and provide evidence that fermionic exchange symmetry significantly affects resonantly enhanced atom-atom-ion recombination. These results establish three-body recombination as a sensitive probe of short-range quantum correlations in degenerate gases and demonstrate that a single trapped ion can be employed as a localized sensor of many-body quantum statistics.

•Jan 1, 2026•0 citations

Quantum statistics on atom-ion Feshbach resonances

Joachim Siemund, Fabian Thielemann, Jonathan Grieshaber +5 more

We investigate three-body recombination in a hybrid atom-ion system consisting of a single trapped Ba$^+$ ion immersed in a two-component Fermi gas of Li atoms near an atom-ion Feshbach resonance. By tuning the spin composition at constant density and temperature, we isolate the role of quantum statistics in atom-atom-ion collisions. The measured ion loss rate exhibits a pronounced nonlinear dependence on spin polarization, revealing a reduced contribution of recombination pathways involving identical fermions already at the level of experimental observables. The observations are consistent with a two-step recombination picture and an adiabatic hyperspherical approach, where antisymmetrization restricts the available entrance channels and gives rise to interference between indistinguishable recombination pathways. Our work establishes atom-ion systems as a platform for controlling three-body collisions via quantum statistics and demonstrates that exchange-symmetry effects remain robust even under thermal averaging that obscures the underlying threshold-law behavior.

arXiv:2606.26995•Jun 25, 2026•0 citations

Feshbach Resonances in p -Wave Three-Body Recombination within Fermi-Fermi Mixtures of Open-Shell Li6 and Closed-Shell Yb173 Atoms

Alaina Green, Hui Li, Jun Hui See Toh +6 more

We report on the observation of magnetic Feshbach resonances in a Fermi-Fermi mixture of ultracold atoms with extreme mass imbalance and on their unique p-wave dominated three-body recombination processes.Our system consists of open-shell alkali-metal 6 Li and closed-shell 173 Yb atoms, both spin polarized and held at various temperatures between 1 and 20 μK.We confirm that Feshbach resonances in this system are solely the result of a weak separation-dependent hyperfine coupling between the electronic spin of 6 Li and the nuclear spin of 173 Yb.Our analysis also shows that three-body recombination rates are controlled by the identical fermion nature of the mixture, even in the presence of s-wave collisions between the two species and with recombination rate coefficients outside the Wigner threshold regime at our lowest temperature.Specifically, a comparison of experimental and theoretical line shapes of the recombination process indicates that the characteristic asymmetric line shape as a function of applied magnetic field and a maximum recombination rate coefficient that is independent of temperature can only be explained by triatomic collisions with nonzero, p-wave total orbital angular momentum.The resonances can be used to form ultracold doublet ground-state molecules and to simulate quantum superfluidity in mass-imbalanced mixtures.

arXiv:1912.04874•Physical Review X•Aug 14, 2020•55 citations

Exploring Ultracold Collisions in Li6−Cr53 Fermi Mixtures: Feshbach Resonances and Scattering Properties of a Novel Alkali-Transition Metal System

A. Ciamei, Stefano Finelli, A. Trenkwalder +3 more

We investigate ultracold collisions in a novel mixture of ^{6}Li and ^{53}Cr fermionic atoms, discovering more than 50 interspecies Feshbach resonances via loss spectroscopy. Building a full coupled-channel model, we unambiguously characterize the ^{6}Li-^{53}Cr scattering properties and yield predictions for other isotopic pairs. In particular, we identify various Feshbach resonances that enable the controlled tuning of elastic s- and p-wave ^{6}Li-^{53}Cr interactions. Our studies thus make lithium-chromium mixtures emerge as optimally suited platforms for the experimental search of elusive few- and many-body regimes of highly correlated fermionic matter, and for the realization of a new class of ultracold polar molecules possessing both electric and magnetic dipole moments.

arXiv:2203.12965•Physical Review Letters•Aug 26, 2022•26 citations
Hybrid systems of single, trapped ions embedded in quantum gases are a promising platform for quantum simulations and the study of long-range interactions in the ultracold regime. Feshbach resonances allow for experimental control over the character and strength of the atom-ion interaction. However, the complexity of atom-ion Feshbach spectra, e.g., due to second-order spin-orbit coupling, requires a detailed experimental understanding of the resonance properties—such as the contributing open-channel partial waves. In this work, we immerse a single barium ( Ba + ) ion in a bath of lithium (Li) atoms spin polarized in their hyperfine ground state to investigate the collision energy dependence of magnetically tunable atom-ion Feshbach resonances. We demonstrate fine control over the kinetic energy of the Ba + ion and employ it to explore three-body recombination in the transition from the many- to the few-partial wave regime, marked by a sudden increase of resonant loss. In a dense spectrum—with on average 0.58(1) resonances per Gauss—we select a narrow, isolated feature and characterize it as an s -wave resonance. We introduce a quantum recombination model that allows us to distinguish it from higher-partial-wave resonances. Furthermore, in a magnetic field range with no significant loss at the lowest collision energies, we identify a higher-partial-wave resonance that appears and peaks only when we increase the energy to around the s -wave limit. Our results demonstrate that hybrid atom-ion traps can reach collision energies well in the ultracold regime and that the ion’s kinetic energy can be employed to tune the collisional complex to resonance, paving the way for fast control over the interaction in settings where magnetic field variations are detrimental to coherence.
Hybrid atom-ion experiments have recently entered the few-partial wave regime in which magnetically tunable Feshbach resonances dominate the three-body loss dynamics. This necessitates a treatment of three-body recombination that can incorporate the role of the resonant dimer channel. Here, we develop a two-step Lindemann-type model for resonant atom-atom-ion three-body recombination that combines multichannel quantum-defect theory for the long-range polarization potential with a universal quantum-capture treatment of the inelastic atom-dimer step. We show that within our model, rate competition can lead to a peak in the three-body-recombination cross section of higher partial-wave channels at energies well below their corresponding centrifugal barrier. Investigating the resulting loss rates under numerically obtained non-thermal collision-energy distributions, we find that these effects survive the energy averaging and can be observed in state-of-the-art hybrid experimental setups. Our findings pave the way for a detailed characterization of atom-ion Feshbach resonances via the analysis of inelastic three-body-recombination processes.
Tunable scattering resonances are crucial for controlling atomic and molecular systems. However, their use has so far been limited to ultracold temperatures. These conditions remain hard to achieve for most hybrid trapped ion-atom systems—a prospective platform for quantum technologies and fundamental research. Here, we measure inelastic collision probabilities for Sr + + Rb and use them to calibrate a comprehensive theoretical model of ion-atom collisions. Our theoretical results, compared with experimental observations, confirm that quantum interference effects persist to the multiple-partial-wave regime, leading to the pronounced state and mass dependence of the collision rates. Using our model, we go beyond interference and identify a rich spectrum of Feshbach resonances at moderate magnetic fields with the Rb atom in its lower ( f = 1) hyperfine state, which persist at temperatures as high as 1 millikelvin. Future observation of these predicted resonances should allow precise control of the short-range dynamics in Sr + + Rb collisions under unprecedentedly warm conditions.
Hybrid atom-ion systems combine the precise control of a single radio-frequency-trapped atomic ion with the rich few- to many-body phenomena of ultracold degenerate quantum gases trapped in light fields. The associated long-range interaction enables studies of impurity physics and the implementation of a single-particle quantum gas microscope, sensitive to quantities beyond the atomic density, including energy distributions, atom-atom couplings, and many-body exchange symmetry. This perspective requires atom-ion coupling, which can be tuned through resonantly enhanced scattering. While atom-ion Feshbach resonances have recently become experimentally accessible, the role of quantum statistics in resonantly enhanced three-body recombination remains largely unexplored. This thesis investigates the role of fermionic quantum statistics in atom-atom-ion three-body recombination. The experiment employs a single 138Ba+ ion immersed in an ultracold two-component Fermi gas of 6Li. An atom-ion Feshbach resonance enables resonantly enhanced recombination for one spin component, while the other component acts as a non-resonant spectating collision partner. This allows a direct comparison between recombination processes involving identical and distinguishable fermions. Experimentally, recombination rates are extracted from bath polarization-dependent ion-loss spectroscopy. Expressing the results as relative rate constants largely detaches them from the total atomic density and results in suppression of recombination in the identical fermion channel. Additional measurements of two-body reactive collisions are combined with simulations of the Fermi gas, demonstrating that density modifications arising from Fermi-Dirac statistics or mutual atom-atom attraction are insufficient to explain the observed recombination behavior. To interpret the measurements, an extension of the conventional two-step model is developed. Using a hyperspherical treatment that includes all pairwise interactions and fermionic exchange symmetry, effective relaxation rates for the loosely-bound atom-ion complex are obtained. The calculations predict a suppression of recombination involving identical fermions relative to distinguishable collision partners. The experimental observations are consistent with this prediction and provide evidence that fermionic exchange symmetry significantly affects resonantly enhanced atom-atom-ion recombination. These results establish three-body recombination as a sensitive probe of short-range quantum correlations in degenerate gases and demonstrate that a single trapped ion can be employed as a localized sensor of many-body quantum statistics.
We investigate three-body recombination in a hybrid atom-ion system consisting of a single trapped Ba+^++ ion immersed in a two-component Fermi gas of Li atoms near an atom-ion Feshbach resonance. By tuning the spin composition at constant density and temperature, we isolate the role of quantum statistics in atom-atom-ion collisions. The measured ion loss rate exhibits a pronounced nonlinear dependence on spin polarization, revealing a reduced contribution of recombination pathways involving identical fermions already at the level of experimental observables. The observations are consistent with a two-step recombination picture and an adiabatic hyperspherical approach, where antisymmetrization restricts the available entrance channels and gives rise to interference between indistinguishable recombination pathways. Our work establishes atom-ion systems as a platform for controlling three-body collisions via quantum statistics and demonstrates that exchange-symmetry effects remain robust even under thermal averaging that obscures the underlying threshold-law behavior.
We report on the observation of magnetic Feshbach resonances in a Fermi-Fermi mixture of ultracold atoms with extreme mass imbalance and on their unique p-wave dominated three-body recombination processes.Our system consists of open-shell alkali-metal 6 Li and closed-shell 173 Yb atoms, both spin polarized and held at various temperatures between 1 and 20 μK.We confirm that Feshbach resonances in this system are solely the result of a weak separation-dependent hyperfine coupling between the electronic spin of 6 Li and the nuclear spin of 173 Yb.Our analysis also shows that three-body recombination rates are controlled by the identical fermion nature of the mixture, even in the presence of s-wave collisions between the two species and with recombination rate coefficients outside the Wigner threshold regime at our lowest temperature.Specifically, a comparison of experimental and theoretical line shapes of the recombination process indicates that the characteristic asymmetric line shape as a function of applied magnetic field and a maximum recombination rate coefficient that is independent of temperature can only be explained by triatomic collisions with nonzero, p-wave total orbital angular momentum.The resonances can be used to form ultracold doublet ground-state molecules and to simulate quantum superfluidity in mass-imbalanced mixtures.
We investigate ultracold collisions in a novel mixture of ^{6}Li and ^{53}Cr fermionic atoms, discovering more than 50 interspecies Feshbach resonances via loss spectroscopy. Building a full coupled-channel model, we unambiguously characterize the ^{6}Li-^{53}Cr scattering properties and yield predictions for other isotopic pairs. In particular, we identify various Feshbach resonances that enable the controlled tuning of elastic s- and p-wave ^{6}Li-^{53}Cr interactions. Our studies thus make lithium-chromium mixtures emerge as optimally suited platforms for the experimental search of elusive few- and many-body regimes of highly correlated fermionic matter, and for the realization of a new class of ultracold polar molecules possessing both electric and magnetic dipole moments.