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arXiv:2406.11404 · American Journal of Physics

Quantum versus classical quenches and the broadening of wave packets

Kurt Schönhammer

Published May 23, 2024• 1 citation
arXivHTMLPDF

Abstract

The time dependence of one-dimensional quantum mechanical probability densities is presented when the potential in which a particle moves is suddenly changed, called a quench. Quantum quenches are mainly addressed, but a comparison with results for the dynamics in the framework of classical statistical mechanics is useful. Analytical results are presented when the initial and final potentials are harmonic oscillators. When the final potential vanishes, the problem reduces to the broadening of wave packets. A simple introduction to the concept of the Wigner function is presented, which allows a better understanding of the dynamics of general wave packets. It is pointed out how special the broadening of Gaussian wave packets is, the only example usually presented in quantum mechanics textbooks.

DOI
10.1119/5.0174441

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The time dependence of one-dimensional quantum mechanical probability densities is presented when the potential in which a particle moves is suddenly changed, called a quench. Quantum quenches are mainly addressed, but a comparison with results for the dynamics in the framework of classical statistical mechanics is useful. Analytical results are presented when the initial and final potentials are harmonic oscillators. When the final potential vanishes, the problem reduces to the broadening of wave packets. A simple introduction to the concept of the Wigner function is presented, which allows a better understanding of the dynamics of general wave packets. It is pointed out how special the broadening of Gaussian wave packets is, the only example usually presented in quantum mechanics textbooks.
The broadening of one-dimensional Gaussian wave packets is presented in all textbooks on quantum mechanics. It is used as an example to elucidate Heisenberg's uncertainty relation. The behaviour on a lattice is drastically different if the amplitude and/or phase of the wave packet varies on the scale of the lattice constant. Important examples are very narrow wavepackets or wavepackets with an average velocity comparable to the maximum velocity on the lattice. The analytical and numerical results for the time dependence of wave packets on a one-dimensional lattice are presented.
A motion of a Gaussian wave packet of a single electron in a harmonic potential is obtained by solving the time dependent Schrödinger equation analytically. The analytic formula of the phase of the wave function which depends on both time and space is also presented explicitly. The probability density of the wave packet moves changing its width and central position periodically. The period of the change of the width is half of that of the central position. The interpretation of these periodic changes in terms of the Green's function which can be derived by the path integration formulation is also discussed.
The dynamics of an initially excital Gaussian wave packet (harmonic oscillator coherent state, HOCS) in a general one-dimensional anharmonic system is studied analytically with the aid of a second quantization formalism for times shorter than a classical oscillation period. The initial state population probability PQ(t), its classical counterpart PC(t), and the overlap probability PQC(t) between a time evolved wave packet and a classically moving Gaussian with stationary shape are calculated in order to analyze the spreading of the wave packet. It was found that, in general, PQ(t) and PC(t) agree very well if the potential energy function has no strongly changing low order derivatives. This agreement is held even if the wave packet spreads drastically within the time scale considered as can be demonstrated by analyzing PQC(t). The analytical expressions for PQ(t), PC(t), and PQC(t) are applied to a dissociative third-order oscillator and a strongly anharmonic fourth-order oscillator. While for a harmonic system, the initial decay time of PQ(t) and PC(t) (which are identical in this case) are only dependent on the energy expectation value 〈H〉 with respect to the initial HOCS, differences up to an order of magnitude occur for HOCS with the same energy in the model systems.
We investigate the quantum and classical wave packet dynamics in an harmonic oscillator that is perturbed by a disorder potential. This perturbation causes the dispersion of a Gaussian wave packet, which is reflected in the coordinate-space and the momentum-space Shannon entropies, the latter being a measure for the amount of information available on a system. Regarding the sum of the two quantities, one arrives at an entropy that is related to the coordinate-momentum uncertainty. Whereas in the harmonic case, this entropy is strictly periodic and can be evaluated analytically, this behavior is lost if disorder is added. There, at selected times, the quantum mechanical probability density resembles that of a classical oscillator distribution function, and the entropy assumes larger values. However, at later times and dependent on the degree of disorder and the chosen initial conditions, quantum mechanical revivals occur. Then, the observed effects are reversed, and the entropy may decrease close to its initial value. This effect cannot be found classically.
This work is a simple example of the quantum dynamics of a particle in a disordered system in one dimension.In particular, we illustrate numerically the phenomenon of Anderson localisation of a wave packet using a basic model constructed with small random rectangular potential barriers.Also, we study the dynamics of a quantum particle in a disordered potential formed by an harmonic oscillator perturbed by random rectangular barriers.To show the effects of disorder on the dynamics of the system, we compare the time evolution of the wave function of the unperturbed harmonic oscillator with the wave function of the disordered system.We do this by taking the scalar product between the unperturbed and perturbed wave functions at each timestep for different values of the perturbation parameters affecting the disordered wave packet.
Physical consequences of the theorem of equivalence among harmonic oscillators of different frequencies, including a free particle as a special case, are explored. A new pictorial way of understanding time-dependent coherent states and squeezed states are presented and contrasted with the standard view. Three-dimensional spherical analogues of squeezed coherent states are constructed. It is also shown as a corollary of the theorem that a free wave packet which coincides initially with any one of the eigenfunctions of a harmonic oscillator maintains its shape, that is, the probability density of position does not change apart from a time-dependent scaling of spatial coordinates. Most of the results are derived without use of any sophisticated techniques but with the knowledge of free wave packets alone.