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arXiv:2406.09715 · PRX Quantum

Contextuality in Anomalous Heat Flow

Naim Elias Comar, Danilo Cius, Luís Ferreira dos Santos, Rafael Wagner, Bárbara Amaral

Published Aug 19, 2025• 13 citations
arXivHTMLPDF

Abstract

In classical thermodynamics, heat must spontaneously flow from hot to cold systems. In quantum thermodynamics, the same law applies when considering multipartite product thermal states evolving unitarily. If initial correlations are present, anomalous heat flow can happen, temporarily making cold thermal states colder and hot thermal states hotter. Such an effect can happen due to entanglement but also because of classical randomness, hence lacking a direct connection with nonclassicality. In this work, we introduce scenarios in which anomalous heat flow have a direct link to nonclassicality, defined as the failure of noncontextual models to explain experimental data. We start by extending known noncontextuality inequalities to a setup in which sequential transformations are considered. We then show a class of quantum prepare-transform-measure protocols, characterized by a time interval ( 0 , τ c ) for a given critical time τ c , where anomalous heat flow happens only if a noncontextuality inequality is violated. We also analyze a recent experiment from and find the critical time τ c based on the authors’ experimental parameters. We conclude by investigating heat flow in the evolution of two-qudit systems, showing that our findings are not an artifact of using two-qubit systems.

DOI
10.1103/f68k-cjx4

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In classical thermodynamics, heat must spontaneously flow from hot to cold systems. In quantum thermodynamics, the same law applies when considering multipartite product thermal states evolving unitarily. If initial correlations are present, anomalous heat flow can happen, temporarily making cold thermal states colder and hot thermal states hotter. Such an effect can happen due to entanglement but also because of classical randomness, hence lacking a direct connection with nonclassicality. In this work, we introduce scenarios in which anomalous heat flow have a direct link to nonclassicality, defined as the failure of noncontextual models to explain experimental data. We start by extending known noncontextuality inequalities to a setup in which sequential transformations are considered. We then show a class of quantum prepare-transform-measure protocols, characterized by a time interval ( 0 , τ c ) for a given critical time τ c , where anomalous heat flow happens only if a noncontextuality inequality is violated. We also analyze a recent experiment from and find the critical time τ c based on the authors’ experimental parameters. We conclude by investigating heat flow in the evolution of two-qudit systems, showing that our findings are not an artifact of using two-qubit systems.
In classical thermodynamics energy always flows from the hotter system to the colder one. However, if these systems are initially correlated, the energy flow can reverse, making the cold system colder and the hot system hotter. This intriguing phenomenon is called "anomalous energy flow" and shows the importance of initial correlations in determining physical properties of thermodynamic systems. Here we investigate the fundamental limits of this effect. Specifically, we find the optimal amount of energy that can be transferred between quantum systems under closed and reversible dynamics, which then allows us to characterize the anomalous energy flow. We then explore a more general scenario where the energy flow is mediated by an ancillary quantum system that acts as a catalyst. We show that this approach allows for exploiting previously inaccessible types of correlations, ultimately resulting in an energy transfer that surpasses our fundamental bound. To demonstrate these findings, we use a well-studied quantum optics setup involving two atoms coupled to an optical cavity.
The standard approach to deriving fluctuation theorems fails to capture the effect of quantum correlation and coherence in the initial state of the system.Here, we overcome this difficulty and derive the heat-exchange-fluctuation theorem in the full quantum regime by showing that the energy exchange between two locally thermal states in the presence of initial quantum correlations is faithfully captured by a quasiprobability distribution.Its negativities, being associated with proofs of contextuality, are proxies of nonclassicality.We discuss the thermodynamic interpretation of negative probabilities and provide heat-flow inequalities that can only be violated in their presence.Remarkably, testing these fully quantum inequalities, at an arbitrary dimension, is no more difficult than testing traditional fluctuation theorems.We test these results on data collected in a recent experiment studying the heat transfer between two qubits and give examples for the capability of witnessing negative probabilities at higher dimensions.
Anomalous heat transfer (AHT), a process by which heat spontaneously flows from a cold system into a hot one, superficially contradicts the Clausius statement of the second law of thermodynamics. Here we provide a full classification of mechanisms of AHT in nonequilibrium quantum systems from a quantum-information perspective. For initial states in local equilibrium, we find that AHT can arise from three resources: initial correlation, intrasystem interaction, and intrasystem temperature inhomogeneity. In particular, for qubit systems, we prove that initial quantum coherence is necessary for AHT if the intersystem interactions are limited to the two-body type. We explicitly show AHT dominated by each of the mechanisms in a three-qubit system. Our classification scheme may offer a guideline for developing high-efficiency quantum autonomous thermal machines.
By the standard second law of thermodynamics, heat spontaneously flows from a hotter body to a colder body. However, quantum systems in which quantum correlations play a prominent role can exhibit a non-classical reversal of such heat flow. We propose a quantum system consisting of a chain of qubits, each in local Gibbs states, where only adjacent qubits are allowed to thermally interact. By controlling initial quantum correlations along the chain, we then demonstrate non-classical heat reversal for the special case of a three-qubit chain on a quantum computer. We explore multiple initial conditions for the spin chain to showcase exotic behaviour such as the preferential pumping of heat afforded by unequal initial correlations between adjacent pairs of qubits, reinforcing the role that initial correlations play in influencing the dynamics of heat flow.
Gate-based quantum computers are an innovative tool for experimentally studying the core principles of quantum mechanics. This work presents the first observation of quantum anomalous heat flow between two qubits and investigates the role of mid-circuit measurements in this context. Using mid-circuit measurements, we designed quantum circuits that violate the semi-classical heat flow bound, witnessing negativities in the underlying Kirkwood-Dirac quasiprobability distribution, which indicates the presence of quantum correlations between the subsystems. Mid-circuit measurements, crucial for probing qubits during the experiment, enabled these observations but also introduced disturbances, such as energy leakage, leading to deviations from theoretical predictions. We modeled these noise effects, providing insight into the limitations of current mid-circuit measurement techniques.
Recent research on the thermodynamic arrow of time, at the microscopic scale, has questioned the universality of its direction. Theoretical studies showed that quantum correlations can be used to revert the natural heat flow (from the hot body to the cold one), posing an apparent challenge to the second law of thermodynamics. Such an "anomalous" heat current was observed in a recent experiment (K. Micadei et al., arXiv:1711.03323), by employing two spin systems initially quantum correlated. Nevertheless, the precise relationship between this intriguing phenomenon and the initial conditions that allow it is not fully evident. Here, we address energy transfer in a wider perspective, identifying a nonclassical contribution that applies to the reversion of the heat flow as well as to more general forms of energy exchange. We derive three theorems that describe the energy transfer between two microscopic systems, for arbitrary initial bipartite states. Using these theorems, we obtain an analytical bound showing that certain type of quantum coherence can optimize such a process, outperforming incoherent states. This genuine quantum advantage is corroborated through a characterization of the energy transfer between two qubits. For this system, it is shown that a large enough amount of coherence is necessary and sufficient to revert the thermodynamic arrow of time. As a second crucial consequence of the presented theorems, we introduce a class of nonequilibrium states that only allow unidirectional energy flow. In this way, we broaden the set where the standard Clausius statement of the second law applies.