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arXiv:2406.09482 · Recent Progress in Materials

Spin Entanglement – A Unifying Principle for Superconductors and Molecular Bonding

Paul O’Hara

Published Jun 3, 2024• 2 citations
arXivHTMLPDF

Abstract

The spin-statistics theorem is generalized to include quantum entanglement. Specifically, within the context of spin entanglement, we prove that isotropically spin-correlated (ISC) states must occur in pairs. This pairing process can be composed of parallel or anti-parallel states. Consequently, the article proposes using ISC states as a unifying principle to explain better Bose-Einstein condensates, the theory of superconductivity, and molecular and atomic orbitals, all of which involve a pairing process. The theoretical framework is established in sections 1 and 2. The other qualitative sections focus primarily on the experimental evidence to support the theory.

DOI
10.21926/rpm.2402012

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The spin-statistics theorem is generalized to include quantum entanglement. Specifically, within the context of spin entanglement, we prove that isotropically spin-correlated (ISC) states must occur in pairs. This pairing process can be composed of parallel or anti-parallel states. Consequently, the article proposes using ISC states as a unifying principle to explain better Bose-Einstein condensates, the theory of superconductivity, and molecular and atomic orbitals, all of which involve a pairing process. The theoretical framework is established in sections 1 and 2. The other qualitative sections focus primarily on the experimental evidence to support the theory.
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Bose-Einstein condensation, superfluidity, and superconductivity are quantum mechanics made visible. They mark the boundary between the classical and the quantum worlds, and they show the macroscopic role of quantum mechanics in condensed matter. This book presents these phenomena in terms of particles, their positions, and their momenta, giving a concrete visualisation and description that is not possible with traditional wave functions. A single approach that bridges the classical-quantum divide provides new insight into the role of particle interactions in condensation, the nature of collisions in superfluid flow, and the physical form of Cooper pairs in high-temperature superconductors. High-temperature superconductivity is explored with quantum statistical mechanics, which links it to Bose-Einstein condensation. Identifying a new mechanism for Cooper pairing, this explains the differences between the low- and high-temperature superconducting regimes and the role of the molecular structure of the conductor. The new perspective offered by this book on Bose-Einstein condensation, superfluidity, and high-temperature superconductivity gives particle-based explanations as well as mathematical and computational methods for these macroscopic quantum phenomena so that readers understand the role of particle interactions and structure in the physics of these phenomena. This book will appeal to undergraduate and graduate students, lecturers, academics, and scientific researchers in the fields of Bose-Einstein condensation and condensates, superfluidity, and superconductivity. It will also be of interest to those working with thermodynamics, statistical mechanics, statistical physics, quantum mechanics, molecular dynamics, materials science, condensed matter physics, and theoretical chemistry. Key Features: · Explores Bose-Einstein condensation with new evidence for multiple condensed states and novel Monte Carlo simulations for interacting bosons · Establishes the thermodynamic nature of condensed bosons from an analysis of fountain pressure measurements, including that they carry energy and entropy, and the thermodynamic principle of superfluid flow · Derives equations of motion for condensed bosons, and performs molecular dynamics simulations of the viscosity with molecular trajectories that give rise to superfluidity · Identifies the mechanism for electron pairing in high-temperature superconductivity
In this article, the rotational invariance of entangled quantum states is investigated as a possible cause of the Pauli exclusion principle. First, it is shown that a certain class of rotationally invariant states can only occur in pairs. This will be referred to as the coupling principle. This in turn suggests a natural classification of quantum systems into those containing coupled states and those that do not. Surprisingly, it would seem that Fermi-Dirac statistics follows as a consequence of this coupling while the Bose-Einstein follows by breaking it. Finally, the experimental evidence to justify the above classification will be discussed. Pacs: 3.65.Bz, 5.30 d, 12.40.Ee
A quantum entangled state is a quantum superposition state. The principle of quantum superposition, and therefore the existence of quantum entanglement, is contingent upon the validity of quantum theory. Thus, the generation of quantum entanglement requires that interactions occur between small-mass particles localized in a confined spatial region, resulting in each particle’s quantum state being a bound state. In other words, the prerequisite for the validity of quantum theory must be satisfied. At the same time, conserved quantities must exist between quantum superposition states, as only quantum states with conserved quantities can undergo superposition, allowing the particle system to generate quantum entangled states. Quantum entangled states can occur between electrons within an atom, between atoms, between molecules, or between atoms and molecules. Within the atomic nucleus, quantum entanglement can exist among protons, neutrons, and the quarks. In superconductivity, superfluidity, and Bose-Einstein condensation, they manifest as macroscopic quantum entanglement, which respectively come from the statistical results of a large amount of microscopic quantum entanglement between electrons, atoms or molecules. For massive macroscopic objects, they exhibit classical properties that cannot be described by quantum theory, and the principle of quantum superposition does not hold. Therefore, no entangled state is generated. It should be particularly emphasized that even for microscopic particle systems, if they exist in a large spatial region, they cannot be described by quantum theory. In such cases, the quantum superposition principle does not hold, and quantum entanglement phenomena do not exist. Therefore, within a large spatial region, multi-electron, multi-photon, and other microscopic systems do not have quantum entangled states; under certain conditions, quantum correlated states can be generated. Consequently, in a large spatial region, the mainstream viewpoints about non-locality—such as the so-called instantaneous collapse of entangled particles during measurement, infinite propagation speed, and the “spooky action at a distance”—are all incorrect. In experiments related to quantum communication and the verification of Bell’s inequality, the quantum states used are quantum correlated states rather than quantum entangled states. Regardless of whether the systems are microscopic or macroscopic, phenomena occurring in a large spatial region must adhere to the principles of causality, realism, and locality. In other words, Einstein’s viewpoint is correct.
This thesis develops the quantitative study of quantum entanglement in systems of identical particles. Understanding this topic is essential for the construction of quantum information processing devices involving identical particles. A brief overview of necessary concepts and methods, such as the density matrix, the entanglement in pure and mixed states of distinguishable particles, and some common applications of entanglement is given in the introduction. Some competing methods of calculating the entanglement in bipartite pure states of indistinguishable particles are examined. It is shown that only the 'site entropy' measure introduced by Zanardi satisfies all the criteria for a correct entanglement measure. A teleportation protocol which utilizes all the entanglement carried (in both the spin and space degrees of freedom) in a doubly- occupied molecular bonding orbital is presented. The output from an interferometer in a thought experiment described by Omar et al. is studied as an example to see whether entanglement can be separated into space-only, spin-only, and space-spin components. A similar exercise is performed for a doubly-occupied molecular bonding orbital. The relationship between these results and the application of superselection rules (SSRs) to the quantification of useful entanglement is discussed. A numerical method for estimating the entanglement of formation of a mixed state of arbitrary dimension by a conjugate gradient algorithm is described. The results of applying an implementation of the algorithm to both random and isotropic states of 2 qutrits (i.e. two three-dimensional systems) is described. Existing work on calculating entanglement between two sites in various spin systems is outlined. New methods for calculating the entanglement between two sites in various types of degenerate quantum gas - a Fermi gas, a Bose condensate, and a BCS superconductor - are described. The results of numerical studies of the entanglement in a normal metal and a BCS superconductor are reported, both with and without the application of superselection rules for local particle number conservation.
As we all know, single microscopic particles such as electrons or atoms do not behave according to the familiar classical (Newtonian) physics which describes the everyday world, but rather according to the prescriptions of quantum mechanics, the outcome is often bizarre and counterintuitive. When a macroscopic number of such particles (say ∼ 10) is assembled under conditions where the effects of quantum mechanics are important, the results can be even more spectacular; they include macroscopic phenomena such as superfluidity and superconductivity, which are completely impossible to explain in classical terms. Most, though not all of these exotic phenomena, are a result of a phenomenon which I shall refer to generically as “quantum condensation,” in which a macroscopic number of particles or pairs of particles—a nonzero fraction of all particles present—occupy a single quantum state; this phenomenon is traditionally referred to as Bose-Einstein condensation (BEC) when it occurs in a system of bosons such as liquid He, and as Cooper pairing when it occurs, for pairs of particles, in a system of fermions such as the electrons in a superconducting metal. As a result of quantum condensation, the characteristically quantum-mechanical behavior which we are used to seeing at the level of single electrons is as it were amplified by the cooperation of condensed particles and can manifest itself at the macroscopic level. The present essay is intended as a general introduction to the subject of quantum condensation and its consequences, as manifested in a variety of physical systems. I will try to review the fundamental physical ideas, usually without de-