Abstract The Kirkwood-Dirac quasiprobability distribution, intimately connected with the quantum correlation function of two observables measured at distinct times, is becoming increasingly relevant for fundamental physics and quantum technologies. This quasiprobability distribution can take non-positive values, and its experimental reconstruction becomes challenging when expectation values of incompatible observables are involved. Here, we use an interferometric scheme aided by an auxiliary system to reconstruct the Kirkwood-Dirac quasiprobability distribution. We experimentally demonstrate this scheme in an electron-nuclear spin system associated with a nitrogen-vacancy center in diamond. By measuring the characteristic function, we reconstruct the quasiprobability distribution of work and analyze the behavior of its first and second moments. Our results clarify the physical meaning of the work quasiprobability distribution in the context of quantum thermodynamics. Finally, we study the uncertainty of measuring the Hamiltonian of the system at two times, via the Robertson-Schrödinger uncertainty relation, for different initial states.
Abstract The Kirkwood-Dirac quasiprobability distribution, intimately connected with the quantum correlation function of two observables measured at distinct times, is becoming increasingly relevant for fundamental physics and quantum technologies. This quasiprobability distribution can take non-positive values, and its experimental reconstruction becomes challenging when expectation values of incompatible observables are involved. Here, we use an interferometric scheme aided by an auxiliary system to reconstruct the Kirkwood-Dirac quasiprobability distribution. We experimentally demonstrate this scheme in an electron-nuclear spin system associated with a nitrogen-vacancy center in diamond. By measuring the characteristic function, we reconstruct the quasiprobability distribution of work and analyze the behavior of its first and second moments. Our results clarify the physical meaning of the work quasiprobability distribution in the context of quantum thermodynamics. Finally, we study the uncertainty of measuring the Hamiltonian of the system at two times, via the Robertson-Schrödinger uncertainty relation, for different initial states.
In this tutorial, we present the definition, interpretation, and properties of some of the main quasiprobabilities that can describe the statistics of measurement outcomes evaluated at two or more times. Such statistics incorporate the incompatibility of the measurement observables and the state of the measured quantum system. We particularly focus on Kirkwood-Dirac quasiprobabilities and related distributions. We also discuss techniques to experimentally access a quasiprobability distribution, ranging from the weak two-point measurement scheme, to a Ramsey-like interferometric scheme and procedures assisted by an external detector. Once defined the fundamental concepts following the standpoint of joint measurability in quantum mechanics, we illustrate the use of quasiprobabilities in quantum thermodynamics to describe the quantum statistics of work and heat, and to explain anomalies in the energy exchanges entailed by a given thermodynamic transformation. On the one hand, in work protocols, we show how absorbed energy can be converted to extractable work and vice versa due to Hamiltonian incompatibility at distinct times. On the other hand, in exchange processes between two quantum systems initially at different temperatures, we explain how quantum correlations in their initial state may induce cold-to-hot energy exchanges, which are unnatural between any pair of equilibrium nondriven systems. We conclude the tutorial by giving simple examples where quasiprobabilities are applied to many-body systems: scrambling of quantum information, sensitivity to local perturbations, and quantum work statistics in the quenched dynamics of models that can be mapped onto systems of free fermions, for instance, the Ising model with a transverse field. Throughout the tutorial, we meticulously present derivations of essential concepts alongside straightforward examples, aiming to enhance comprehension and facilitate learning. Published by the American Physical Society 2024
Recent work has revealed the central role played by the Kirkwood-Dirac quasiprobability (KDQ) as a tool to properly account for non-classical features in the context of condensed matter physics (scrambling, dynamical phase transitions) metrology (standard and post-selected), thermodynamics (power output and fluctuation theorems), foundations (contextuality, anomalous weak values) and more. Given the growing relevance of the KDQ across the quantum sciences, our aim is two-fold: First, we highlight the role played by quasiprobabilities in characterizing the statistics of quantum observables and processes in the presence of measurement incompatibility. In this way, we show how the KDQ naturally underpins and unifies quantum correlators, quantum currents, Loschmidt echoes, and weak values. Second, we provide novel theoretical and experimental perspectives by discussing a wide variety of schemes to access the KDQ and its non-classicality features.
We employ the operational quasiprobability (OQ) as a work distribution, which reproduces the Jarzynski equality and yields the average work consistent with the classical definition. The OQ distribution can be implemented through two simple experimental settings: the end-point measurement and the two-point measurement. Using this framework, we demonstrate the explicit contribution of coherence to the work, which can be formulated by the second-law-type relation. In a two-level system, we show that nonjoint measurability, a generalized notion of measurement incompatibility, can increase the amount of extractable work beyond the classical bound imposed by jointly measurable measurements. We further prove that the real part of Kirkwood-Dirac quasiprobability (KDQ) and the OQ are equivalent in two-level systems, and they are non-negative for binary unbiased measurements if and only if the measurements are jointly measurable. In a three-level nitrogen-vacancy center system, the OQ and the KDQ exhibit different amounts of negativities while enabling the same work extraction, implying that the magnitude of negativity is not a faithful indicator of nonclassical work. These results highlight that coherence and nonjoint measurability play fundamental roles in the enhancement of work.
Quantum correlation functions are a natural way to encode multitime information, as they are ubiquitous in analysis from fluctuation theorems to information scrambling. Correlation functions can be identified with quasiprobabilities associated to quantum processes. In this work we show how these can be measured via error-cancellation techniques, using projective measurements only and no ancillae. The scheme is implemented in a nitrogen-vacancy center in diamond undergoing a unitary quantum work protocol. We reconstruct quantum-mechanical time correlations encoded in the Margenau-Hills quasiprobabilities by observing work extraction peaks five times those of sequential projective energy measurement schemes and in violation of newly derived stochastic bounds. We interpret the phenomenon via anomalous energy exchanges due to the underlying negativity of the quasiprobability distribution. Published by the American Physical Society 2024
Kirkwood-Dirac (KD) quasiprobability is a quantum analog of phase space probability of classical statistical mechanics, allowing negative or/and nonreal values. It gives an informationally complete representation of a quantum state. Recent works have revealed the important roles played by the KD quasiprobability in the broad fields of quantum science and quantum technology. In the present work, we use the KD quasiprobability to access the quantum coherence in a quantum state. We show that the l1 norm of the imaginary part of the KD quasiprobability over an incoherent reference basis and a second basis, maximized over all possible choices of the latter, can be used to quantify quantum coherence, satisfying certain desirable properties. It is upper bounded by the quantum uncertainty, i.e., the quantum standard deviation, of the incoherent basis in the state. It gives a lower bound to the l1 norm quantum coherence, and for a single qubit, they are identical. We discuss the measurement of the KD coherence based on the measurement of the KD quasiprobability and an optimization procedure in hybrid quantum-classical schemes, and suggest statistical interpretations. We also discuss its relevance in the physics of linear response regime.
The Kirkwood–Dirac (KD) quasiprobability distribution describes any quantum state with respect to the eigenbases of two incompatible observables. While the KD quasiprobability distribution behaves similarly to a classical probability distribution, it can take on negative or nonreal values. Recently, the framework of the temporal Kirkwood–Dirac quasiprobability distribution has been proposed, generalizing the KD quasiprobability distribution to arbitrary multi-time quantum processes. In this work, we specifically focus on the temporal KD quasiprobability distribution within the context of two-time dynamics. We begin by constructing a nonclassicality measure derived from the real and imaginary parts of the temporal KD quasiprobability distribution. Next, we establish two uncertainty relations closely linked to this nonclassicality measure, one of which shows that the nonclassicality measure is bounded below by the measurement disturbance caused by the first measurement. Finally, we elucidate the relationships among temporal KD nonclassicality, the spatiotemporal Born rule, and spatiotemporal compatibility.