In quantum mechanics, many observables for a quantum system are represented as self-adjoint linear operators (possibly unbounded) on a complex Hilbert space
H. In this paper, we introduce a binary relation
⊥ on
S(H) of all self-adjoint linear operators (including unbounded) on
H. We obtain that
A⊥B implies that
A,B are affiliated with some abelian von Neumann algebra at the same time. Depending on
⊥,S(H) can be constructed to be a generalized orthoalgebra. Then we present the orthoalgebra order
⪯ and the traditional order
≤ on
S(H) and give some properties about these two orders. We prove that for
A,B∈S(H),
A⪯B if and only if
A has a value in
Δ implies that
B has a value in
Δ for every Borel set
Δ not containing
0. Moreover, we study the existence of the infimum
A∧B and supremum
A∨B for
A,B∈S(H) with respect to
⪯. Finally, we prove that
Q∧P=0 where
Q and
P are the significant quantum observables corresponding to the position and momentum.}
Pauli's well known theorem (W. Pauli, Hanbuch der Physik vol. 5/1, ed. S. Flugge, (1926) p.60) asserts that the existence of a self-adjoint time operator canonically conjugate to a given Hamiltonian implies that the time operator and the Hamitlonian posses completely continuous spectra spanning the entire real line. Thus the conclusion that there exists no self-adjoint time operator conjugate to a Hamiltonian with a spectrum which is a proper subspace of the real line. But we challenge this conclusion. We show rigourously the consitency of assuming a bounded, self-adjoint time operator conjugate to a Hamiltonian with an unbounded, or semibounded, or finitely countable point spectrum. Pauli implicitly assumed unconditionally that the domain of the Hamiltonian is invariant under the action of $U_\\beta=\\exp(-i\\beta T)$, where
T is the time operator, for arbitrary real number
betaA. But we show that the
beta's are at most the differences of the eigenvalues of the Hamiltonian. And this happens, under some other conditions, when the Hamiltonian has a non-empty point spectrum extending from negative to positive infinity. For a Hamiltonian with a simibounded or finitely countable point spectrum, we show that no $U_\\beta$. We demonstrate our claim by giving an explicit example.