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arXiv:2405.01946 · Physical review. E

Shortcuts to adiabaticity in harmonic traps: A quantum-classical analog

Vincent Hardel, Giovanni Manfredi, Paul-Antoine Hervieux, Rémi Goerlich

Published Nov 26, 2024• 1 citation
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Abstract

We present a technique for efficiently transitioning a quantum system from an initial to a final stationary state in less time than is required by an adiabatic (quasistatic) process. Our approach makes use of Nelson's stochastic quantization, which represents the quantum system as a classical Brownian process. Thanks to this mathematical analogy, known protocols for classical overdamped systems can be translated into quantum protocols. In particular, one can use classical methods to find optimal quantum protocols that minimize both the time duration and some other cost function to be freely specified. We have applied this method to the time-dependent harmonic oscillator and tested it on two different cost functions: (i) the cumulative energy of the system over time and (ii) the dynamical phase of the wave function. In the latter case, it is possible to construct protocols that are "adiabatically optimal," i.e., they minimize their distance from an adiabatic process for a given duration.

DOI
10.1103/physreve.110.054138

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We present a technique for efficiently transitioning a quantum system from an initial to a final stationary state in less time than is required by an adiabatic (quasistatic) process. Our approach makes use of Nelson's stochastic quantization, which represents the quantum system as a classical Brownian process. Thanks to this mathematical analogy, known protocols for classical overdamped systems can be translated into quantum protocols. In particular, one can use classical methods to find optimal quantum protocols that minimize both the time duration and some other cost function to be freely specified. We have applied this method to the time-dependent harmonic oscillator and tested it on two different cost functions: (i) the cumulative energy of the system over time and (ii) the dynamical phase of the wave function. In the latter case, it is possible to construct protocols that are "adiabatically optimal," i.e., they minimize their distance from an adiabatic process for a given duration.
The expansion of a harmonic potential that holds a quantum particle may be realized without any final particle excitation but much faster than adiabatically via "shortcuts to adiabaticity" (STA). While ideally the process time can be reduced to zero, practical limitations and constraints impose minimal finite times for the externally controlled time-dependent frequency protocols. We examine the role of different time-averaged energies (total, kinetic, potential, nonadiabatic) and of the instantaneous power in characterizing or selecting different protocols. Specifically, we prove a virial theorem for STA processes, set minimal energies (or times) for given times (or energies), and discuss their realizability by means of Dirac impulses or otherwise.
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Abstract. For systems in an externally controllable time-dependent potential, the optimal protocol minimizes the mean work spent in a finite-time transition between given initial and final values of a control parameter. For an initially thermalized ensemble, we consider both Hamiltonian evolution for classical systems and Schrödinger evolution for quantum systems. In both cases, we show that for harmonic potentials, the optimal work is given by the adiabatic work even in the limit of short transition times. This result is counter-intuitive because the adiabatic work is substantially smaller than the work for an instantaneous jump. We also perform numerical calculations of the optimal protocol for Hamiltonian dynamics in an anharmonic quartic potential. For a two-level spin system, we give examples where the adiabatic work can be reached in either a finite or an arbitrarily short transition time depending on the allowed parameter space. PACS numbers: 05.70.-aOptimal protocols for Hamiltonian and Schrödinger dynamics 2 1.
The second law of thermodynamics sets a lower bound on the work required to drive a system between thermal equilibrium states, with equality attained in the quasistatic limit. For finite-time processes, work in excess of this bound is inevitably dissipated, motivating the search for driving protocols that minimize this excess work. While classical stochastic systems have been extensively explored, quantum analyses remain limited and often rely on Markovian master equations valid only in the weak-coupling regime. Here, we study minimal work protocols for representative two-level systems coupled to a harmonic-oscillator bath using a numerically exact method. Inspired by known optimal solutions for Brownian oscillators, we introduce an impulse ansatz that incorporates possible boundary impulses and test it across a wide range of bath parameters. We find that impulse-like features remain nearly optimal in the quantum, non-Markovian regime at short times. We also identify cases in which the widely used Markovian master equation fails even at weak coupling, highlighting the necessity of going beyond standard approximations in the quantum regime for finite-time thermodynamic optimization.
Adiabatic invariants -- quantities that are preserved under the slow driving of a system's external parameters -- are important in classical mechanics, quantum mechanics and thermodynamics. Adiabatic processes allow a system to be guided to evolve to a desired final state. However, the slow driving of a quantum system makes it vulnerable to environmental decoherence, and for both quantum and classical systems, it is often desirable and time-efficient to speed up a process. {\it Shortcuts to adiabaticity} are strategies for preserving adiabatic invariants under rapid driving, typically by means of an auxiliary field that suppresses excitations, otherwise generated during rapid driving. Several theoretical approaches have been developed to construct such shortcuts. In this dissertation we focus on two different approaches, namely {\it counterdiabatic} driving and {\it fast-forward} driving, which were originally developed for quantum systems. The counterdiabatic approach introduced independently by Dermirplak and Rice [{\it J. Phys. Chem. A}, 107:9937, 2003], and Berry [{\it J. Phys. A: Math. Theor.}, 42:365303, 2009] formally provides an exact expression for the auxiliary Hamiltonian, which however is abstract and difficult to translate into an experimentally implementable form. By contrast, the fast-forward approach developed by Masuda and Nakamura [{\it Proc. R. Soc. A}, 466(2116):1135, 2010] provides an auxiliary potential that may be experimentally implementable but generally applies only to ground states. The central theme of this dissertation is that classical shortcuts to adiabaticity can provide useful physical insights and lead to experimentally implementable shortcuts for analogous quantum systems. We start by studying a model system of a tilted piston to provide a proof of principle that quantum shortcuts can successfully be constructed from their classical counterparts. In the remainder of the dissertation, we develop a general approach based on {\it flow-fields} which produces simple expressions for auxiliary terms required for both counterdiabatic and fast-forward driving. We demonstrate the applicability of this approach for classical, quantum as well as stochastic systems. We establish strong connections between counterdiabatic and fast-forward approaches, and also between shortcut protocols required for classical, quantum and stochastic systems. In particular, we show how the fast-forward approach can be extended to highly excited states of quantum systems.
In quantum physics the free particle and the harmonically trapped particle are arguably the most important systems a physicist needs to know about. It is little known that, mathematically, they are one and the same. This knowledge helps us to understand either from the viewpoint of the other. Here we show that all general time-dependent solutions of the free-particle Schrödinger equation can be mapped to solutions of the Schrödinger equation for harmonic potentials, both the trapping oscillator and the inverted “oscillator”. This map is fully invertible and therefore induces an isomorphism between both types of system, they are equivalent. A composition of the map and its inverse allows us to map from one harmonic oscillator to another with a different spring constant and different center position. The map is independent of the state of the system, consisting only of a coordinate transformation and multiplication by a form factor, and can be chosen such that the state is identical in both systems at one point in time. This transition point in time can be chosen freely, the wave function of the particle evolving in time in one system before the transition point can therefore be linked up smoothly with the wave function for the other system and its future evolution after the transition point. Such a cut-and-paste procedure allows us to describe the instantaneous changes of the environment a particle finds itself in. Transitions from free to trapped systems, between harmonic traps of different spring constants or center positions, or, from harmonic binding to repulsive harmonic potentials are straightforwardly modelled. This includes some time-dependent harmonic potentials. The mappings introduced here are computationally more efficient than either state-projection or harmonic oscillator propagator techniques conventionally employed when describing instantaneous (non-adiabatic) changes of a quantum particle’s environment.