Quantum coherence has been shown to impact the operational capabilities of quantum systems performing thermodynamic tasks in a significant way, and yet the possibility and conditions for genuine coherence-enhanced thermodynamic operation remain unclear. Introducing a comparison with classical machines using the same set of thermodynamic resources, we show that for steady-state quantum thermal machines – both autonomous and externally driven – that interact weakly with thermal reservoirs and work sources, the presence of coherence induced by perturbations in the machine Hamiltonian guarantees a genuine thermodynamic advantage under mild conditions. This advantage applies to both cases where the induced coherence is between levels with different energies or between degenerate levels. On the other hand, we show that engines subjected to noise-induced coherence can be outperformed by classical stochastic engines using exactly the same set of (incoherent) resources. We illustrate our results with three prototypical models of heat engines and refrigerators: the three-level amplifier, the three-qubit autonomous refrigerator, and a noise-induced-coherence machine.
Quantum coherence has been shown to impact the operational capabilities of quantum systems performing thermodynamic tasks in a significant way, and yet the possibility and conditions for genuine coherence-enhanced thermodynamic operation remain unclear. Introducing a comparison with classical machines using the same set of thermodynamic resources, we show that for steady-state quantum thermal machines – both autonomous and externally driven – that interact weakly with thermal reservoirs and work sources, the presence of coherence induced by perturbations in the machine Hamiltonian guarantees a genuine thermodynamic advantage under mild conditions. This advantage applies to both cases where the induced coherence is between levels with different energies or between degenerate levels. On the other hand, we show that engines subjected to noise-induced coherence can be outperformed by classical stochastic engines using exactly the same set of (incoherent) resources. We illustrate our results with three prototypical models of heat engines and refrigerators: the three-level amplifier, the three-qubit autonomous refrigerator, and a noise-induced-coherence machine.
The performance enhancements observed in various models of continuous quantum thermal machines have been linked to the buildup of coherences in a preferred basis. But is this connection always an evidence of "quantum-thermodynamic supremacy"? By force of example, we show that this is not the case. In particular, we compare a power-driven three-level continuous quantum refrigerator with a four-level combined cycle, partly driven by power and partly by heat. We focus on the weak driving regime and find the four-level model to be superior since it can operate in parameter regimes in which the three-level model cannot and it may exhibit a larger cooling rate and, simultaneously, a better coefficient of performance. Furthermore, we find that the improvement in the cooling rate matches the increase in the stationary quantum coherences exactly. Crucially, though, we also show that the thermodynamic variables for both models follow from a classical representation based on graph theory. This implies that we can build incoherent stochastic-thermodynamic models with the same steady-state operation or, equivalently, that both coherent refrigerators can be emulated classically. More generally, we prove this for any N-level weakly driven device with a "cyclic" pattern of transitions. Therefore, even if coherence is present in a specific quantum thermal machine, it is often not essential to replicate the underlying energy conversion process.
Abstract The introduction of the quantum analogue of a Carnot engine based on a bath comprising of particles with a small amount of coherence initiated an active line of research on the harnessing of different quantum resources for the enhancement of thermal machines beyond the standard reversible limit, with an emphasis on non-thermal baths containing quantum coherence. In our work, we investigate the impact of coherence on the thermodynamic tasks of a collision model which is composed of a system interacting, in the continuous time limit, with a series of coherent ancillas of two baths at different temperatures. Our results show the advantages of utilising coherence as a resource in the operation of the machine, and allows it: (a) to exhibit unconventional behaviour such as the appearance of a hybrid refrigerator, capable of simultaneous refrigeration and generation of work, and (b) to function as an engine or a refrigerator with efficiencies larger than the Carnot bound. Moreover, we find an effective upper bound to the efficiency of the thermal machine operating as an engine in the presence of a coherent reservoir.
The thermodynamic uncertainty relation, originally derived for classical Markov-jump processes, provides a tradeoff relation between precision and dissipation, deepening our understanding of the performance of quantum thermal machines. Here, we examine the interplay of quantum system coherences and heat current fluctuations on the validity of the thermodynamics uncertainty relation in the quantum regime. To achieve the current statistics, we perform a full counting statistics simulation of the Redfield quantum master equation. We focus on steady-state quantum absorption refrigerators where nonzero coherence between eigenstates can either suppress or enhance the cooling power, compared with the incoherent limit. In either scenario, we find enhanced relative noise of the cooling power (standard deviation of the power over the mean) in the presence of system coherence, thereby corroborating the thermodynamic uncertainty relation. Our results indicate that fluctuations necessitate consideration when assessing the performance of quantum coherent thermal machines.
The thermodynamic uncertainty relation (TUR) imposes a fundamental constraint between current fluctuations and entropy production, providing a refined formulation of the second law for micro- and nanoscale systems. Quantum violations of the classical TUR reveal genuinely quantum thermodynamic effects, which are essential for improving performance and enabling optimization in quantum technologies. In this work, we analyze the TUR in a class of paradigmatic quantum thermal-machine models whose operation is enabled by coherent coupling between two energy levels forming a virtual qubit. Steady-state coherences are confined to this virtual-qubit subspace, while in the absence of coherent coupling the system satisfies detailed balance with the thermal reservoirs and supports no steady-state heat currents. We show that the steady-state currents and entropy production can be fully reproduced by an effective classical Markov process, whereas current fluctuations acquire an additional purely quantum correction originating from coherence. As a result, the thermodynamic uncertainty naturally decomposes into a classical (diagonal) contribution and a coherent contribution. The latter becomes negative under resonant conditions and reaches its minimum at the coupling strength that maximizes steady-state coherence. We further identify the conditions for minimizing the thermodynamic uncertainty, and the criteria for surpassing the classical TUR bound in the vicinity of the reversible limit.
Abstract The characterization and control of quantum effects in the performance of thermodynamic tasks may open new avenues for small thermal machines working in the nanoscale. We study the impact of coherence in the energy basis in the operation of a small thermal machine which can act either as a heat engine or as a refrigerator. We show that input coherence may enhance the machine performance and allow it to operate in otherwise forbidden regimes. Moreover, our results also indicate that, in some cases, coherence may also be detrimental, rendering optimization of particular models a crucial task for benefiting from coherence-induced enhancements.
Conventional continuous quantum heat engines with incoherent heat transfer perform poorly as they exploit two-body interactions between the system and hot or cold baths, thus having limited capability to outperform their classical counterparts. We introduce distinct continuous quantum heat engines that utilize coherent heat transfer with baths, yielding genuine quantum enhancement in performance. These coherent engines consist of one qutrit system and two photonic baths and enable coherent heat transfer via two-photon transitions involving three-body interactions between the system and hot and cold baths. We demonstrate that coherent engines deliver significantly higher power output with much greater reliability, i.e., lower signal-to-noise ratio of the power, by hundreds of folds over their incoherent counterparts. Importantly, coherent engines can operate close to or at the maximal achievable reliability allowed by the quantum thermodynamic uncertainty relation. Moreover, coherent engines manifest more nonclassical features than incoherent engines because they violate the classical thermodynamic uncertainty relation by a greater amount and for a wider range of parameters. These genuine enhancements in the performance of coherent engines are directly attributed to their capacity to harness higher energetic coherence for the resonant driving case. The experimental feasibility of coherent engines and the improved understanding of how quantum properties can enhance performance may find applications in quantum enabled technologies.