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arXiv:2403.18617 · Journal of Statistical Physics

Quantum Concentration Inequalities and Equivalence of the Thermodynamical Ensembles: An Optimal Mass Transport Approach

Giacomo De Palma, Davide Pastorello

Published Jun 14, 2025• 3 citations
arXivHTMLPDF
DOI
10.1007/s10955-025-03464-3

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Abstract We establish Transportation Cost Inequalities (TCIs) with respect to the quantum Wasserstein distance by introducing quantum extensions of well-known classical methods: First, we generalize the Dobrushin uniqueness condition to prove that Gibbs states of 1D commuting Hamiltonians satisfy a TCI at any positive temperature and provide conditions under which this first result can be extended to non-commuting Hamiltonians. Next, using a non-commutative version of Ollivier’s coarse Ricci curvature, we prove that high temperature Gibbs states of commuting Hamiltonians on arbitrary hypergraphs H=(V,E)H=(V,E)H=(V,E) H = ( V , E ) satisfy a TCI with constant scaling as O(|V|). Third, we argue that the temperature range for which the TCI holds can be enlarged by relating it to recently established modified logarithmic Sobolev inequalities. Fourth, we prove that the inequality still holds for fixed points of arbitrary reversible local quantum Markov semigroups on regular lattices, albeit with slightly worsened constants, under a seemingly weaker condition of local indistinguishability of the fixed points. Finally, we use our framework to prove Gaussian concentration bounds for the distribution of eigenvalues of quasi-local observables and argue the usefulness of the TCI in proving the equivalence of the canonical and microcanonical ensembles and an exponential improvement over the weak Eigenstate Thermalization Hypothesis.
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Thermodynamic tradeoff relations quantify the fundamental concept of "no free lunch" in the physical world, suggesting that faster and more precise physical processes come at a higher thermodynamic cost. The key elements in these trade-off relations are the thermodynamic uncertainty relation and speed limit, which are closely tied to information inequalities from which other trade-off relations are derived. Concentration inequalities are relations that complement information inequalities in statistical analyses and have been widely used in various fields. However, their role in thermodynamic trade-off relations remains unclear. This Letter develops thermodynamic concentration inequalities that provide bounds for the distribution of observables in quantum and classical Markov processes. We derive a set of trade-off relations that generalize speed limits and thermodynamic uncertainty relations from the developed thermodynamic concentration inequalities. The derived trade-off relations hold under minimal assumptions of the underlying physical processes. This Letter clarifies the role of concentration inequalities in thermodynamics, paving the way for deriving new trade-off relations.