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arXiv:2403.12330 · Physical Review Letters

Exact Thermal Eigenstates of Nonintegrable Spin Chains at Infinite Temperature

Yuuya Chiba, Yasushi Yoneta

Published Oct 24, 2024• 17 citations
arXivHTMLPDF

Abstract

The eigenstate thermalization hypothesis (ETH) plays a major role in explaining thermalization of isolated quantum many-body systems. However, there has been no proof of the ETH in realistic systems due to the difficulty in the theoretical treatment of thermal energy eigenstates of nonintegrable systems. Here, we write down analytically thermal eigenstates of nonintegrable spin chains. We consider a class of theoretically tractable volume-law states, which we call entangled antipodal pair (EAP) states. These states are thermal, in the most fundamental sense that they are indistinguishable from the Gibbs state with respect to all local observables, with infinite temperature. We then identify Hamiltonians having the EAP state as an eigenstate and rigorously show that some of these Hamiltonians are nonintegrable. Furthermore, a thermal pure state at an arbitrary temperature is obtained by the imaginary time evolution of an EAP state. Our results offer a potential avenue for providing a provable example of the ETH.

DOI
10.1103/physrevlett.133.170404

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The eigenstate thermalization hypothesis (ETH) plays a major role in explaining thermalization of isolated quantum many-body systems. However, there has been no proof of the ETH in realistic systems due to the difficulty in the theoretical treatment of thermal energy eigenstates of nonintegrable systems. Here, we write down analytically thermal eigenstates of nonintegrable spin chains. We consider a class of theoretically tractable volume-law states, which we call entangled antipodal pair (EAP) states. These states are thermal, in the most fundamental sense that they are indistinguishable from the Gibbs state with respect to all local observables, with infinite temperature. We then identify Hamiltonians having the EAP state as an eigenstate and rigorously show that some of these Hamiltonians are nonintegrable. Furthermore, a thermal pure state at an arbitrary temperature is obtained by the imaginary time evolution of an EAP state. Our results offer a potential avenue for providing a provable example of the ETH.
Understanding how microscopic few-body interactions give rise to thermal behavior in isolated quantum many-body systems remains a central challenge in nonequilibrium statistical mechanics. While individual energy eigenstates are expected to reproduce thermal equilibrium values, analytic access to highly entangled thermal eigenstates of nonintegrable Hamiltonians remains scarce. In this Letter, we construct exact infinite-temperature eigenstates of generically nonintegrable two-body Hamiltonians using stabilizer states. These states can fully reproduce thermal expectation values for all spatially local observables, extending previously known Bell-pair-based constructions to a broader class. At the same time, we prove a sharp no-go theorem: stabilizer eigenstates of two-body Hamiltonians cannot satisfy microscopic thermal equilibrium for all four-body observables. This bound is tight, as we explicitly construct a translationally invariant Hamiltonian whose stabilizer eigenstate is thermal for all two-body and three-body observables as well as all spatially local observables. Our results suggest that reproducing higher-order thermal correlations requires nonstabilizer degrees of freedom, providing analytic insight into the interplay between interaction locality, microscopic thermal equilibrium, and quantum computational complexity.
Understanding how isolated quantum systems thermalize has recently gathered renewed interest almost 100 years after the first work by von Neumann, thanks to the experimental realizations of such systems. Experimental and numerical pieces of evidence imply that nonintegrability of the system plays an important role in thermalization. Nonintegrable systems that conserve energy alone are expected to be effectively described by the (micro)canonical ensemble due to the so-called eigenstate thermalization hypothesis (ETH) in the thermodynamic limit. In contrast, it is expected that stationary states in integrable systems are described not by the canonical ensemble but by the generalized Gibbs ensemble (GGE) due to the existence of many nontrivial conserved quantities. In this thesis, we study thermalization and its mechanism in nonintegrable systems from two perspectives. We first study how well the ETH and its finite-size corrections can be predicted by random matrix theory (RMT). Next, we present our study on the emergence of the GGE in a nonintegrable system with an extensive number of local symmetries.
Deriving conditions under which a macroscopic system thermalizes directly from the underlying quantum many-body dynamics of its microscopic constituents is a long-standing challenge in theoretical physics. The well-known eigenstate thermalization hypothesis (ETH) is presumed to be a key mechanism, but has defied rigorous verification for generic systems thus far. A weaker variant (weak ETH), by contrast, is provably true for a large variety of systems, including even many integrable models, but its implications with respect to the problem of thermalization are still largely unexplored. Here we analytically demonstrate that systems satisfying the weak ETH exhibit thermalization for two very natural classes of far-from-equilibrium initial conditions: the overwhelming majority of all pure states with a preset nonequilibrium expectation value of some given local observable, and the Gibbs states of a Hamiltonian which subsequently is subject to a quantum quench in the form of a sudden change of some local system properties.
The eigenstate thermalization hypothesis (ETH), which asserts that every eigenstate of a many-body quantum system is indistinguishable from a thermal ensemble, plays a pivotal role in understanding thermalization of isolated quantum systems. Yet, no evidence has been obtained as to whether the ETH holds for all few-body operators in a chaotic system; such few-body operators include key quantities in statistical mechanics, such as the total magnetization, the momentum distributions, and their low-order thermal and quantum fluctuations. Here, we formulate a conjecture that for a generic nonintegrable system the ETH holds simultaneously for all mmm-body operators with m<α∗Nm < α_{\ast} Nm<α∗​N in the thermodynamic limit for some nonzero constant α∗>0α_{\ast} > 0α∗​>0. We first show the existence of such nontrivial constants for idealized (pseudo) random-matrix descriptions of many-body eigenstates. We then verify the conjecture for generic spin, Bose, and Fermi systems with local and few-body interactions by large-scale numerical calculations. Our results imply that generic systems satisfy the ETH simultaneously for all few-body operators, including their thermal and quantum fluctuations.
Exact solutions for excited states in nonintegrable quantum Hamiltonians have revealed novel dynamical phenomena that can occur in quantum many-body systems. This work proposes a method to analytically construct a specific set of volume-law entangled zero-energy exact excited eigenstates in a large class of spin Hamiltonians. In particular, we show that all spin chains that satisfy a simple set of conditions host exact volume law entangled zero-energy eigenstates in the middle of their spectra. Examples of physically relevant spin chains of this type include the transverse-field Ising model, PXP model, spin-S XY model, and spin-S Kitaev chain. Although these eigenstates are highly atypical in their structure, they are thermal with respect to local observables. Our framework also unifies many recent constructions of volume-law entangled eigenstates in the literature. Finally, we show that a similar construction also generalizes to spin models on graphs in arbitrary dimensions.
The eigenstate thermalization hypothesis (ETH) states that for nonintegrable systems, each energy eigenstate accurately gives microcanonical expectation values for a class of observables. In this paper, we explore the ETH in terms of the time-energy uncertainty and an intrinsic thermal nature shared by the majority of quasi eigenstates of operationally defined 'time operator': First, we show that the energy eigenstates are superposition of uncountably many quasi eigenstates of suitably defined 'time operator'. Majority of such quasi eigenstates are thermal for thermodynamic isolated quantum many-body systems and approximately orthogonal in terms of extremely short relaxation time of the fidelity. In this manner, our scenario provides a theoretical explanation of ETH.