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arXiv:2403.02034 · Physical Review Letters

Nanoparticle Stored with an Atomic Ion in a Linear Paul Trap

Dmitry S. Bykov, Lorenzo Dania, Florian Goschin, Tracy E. Northup

Published Nov 21, 2025• 5 citations
arXivHTMLPDF

Abstract

Radiofrequency (RF) traps enable highly controlled interactions between charged particles, including reactions between cold molecular ions, sympathetic cooling of one ion species with another, and quantum logic spectroscopy. However, the charge-to-mass (Q/m) selectivity of RF traps limits the range of objects that can be confined simultaneously in the same trap. Here, we confine two particles-a nanoparticle and an atomic ion-in the same radiofrequency trap although their charge-to-mass ratios differ by six orders of magnitude. The confinement is enabled by a dual-frequency voltage applied to the trap electrodes. We introduce a robust loading procedure under ultrahigh vacuum and characterize the stability of both particles. It is observed that slow-field micromotion, an effect specific to the dual-field setting, plays a crucial role for ion localization. Our results lay the groundwork for controlled interactions between diverse charged particles, regardless of the difference in their charge or mass, with applications from antimatter synthesis to the generation of macroscopic quantum states of motion.

DOI
10.1103/5lzj-f61x

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Radiofrequency (RF) traps enable highly controlled interactions between charged particles, including reactions between cold molecular ions, sympathetic cooling of one ion species with another, and quantum logic spectroscopy. However, the charge-to-mass (Q/m) selectivity of RF traps limits the range of objects that can be confined simultaneously in the same trap. Here, we confine two particles-a nanoparticle and an atomic ion-in the same radiofrequency trap although their charge-to-mass ratios differ by six orders of magnitude. The confinement is enabled by a dual-frequency voltage applied to the trap electrodes. We introduce a robust loading procedure under ultrahigh vacuum and characterize the stability of both particles. It is observed that slow-field micromotion, an effect specific to the dual-field setting, plays a crucial role for ion localization. Our results lay the groundwork for controlled interactions between diverse charged particles, regardless of the difference in their charge or mass, with applications from antimatter synthesis to the generation of macroscopic quantum states of motion.
We investigate the properties of a radiofrequency (Paul)-trap with a super-imposed magnetic field (combined trap). The regions of stability are significantly larger than those for a Paul-trap for both positive and negative charged ions. As a result ions of different charge sign and large mass difference can be confined simultaneously. This may have some advantages for electron cooling of highly charged ions or for the formation of anti-hydrogen from simultaneously stored positrons and antiprotons.
Paul traps are widely used to confine electrically charged particles like atomic and molecular ions by using an intense radiofrequency (RF) field, typically obtained by a voltage drop on capacitative electrodes placed in vacuum. We present a RF drive realized on a compact printed circuit board and providing a high-voltage RF signal to a quadrupole Paul trap. The circuit is formed by using four interdependent resonant circuits - each of which is connected to an electrode of a Paul trap - fed by low-noise amplifiers, leading to an output voltage of peak-to-peak amplitude up to 200 V at 3.23 MHz. The presence of a single resonant circuit for each electrode ensures a strong control on the voltage drop on each electrode, e.g., by applying a DC field through a bias tee. Additionally, the moderate quality factor Q = 67 of the resonant circuits ensures a fast operation of the drive, which can be turned on and off in less than 10 μs. Finally, the RF lines are equipped with pickups that sample the RF in phase and amplitude, thus providing a signal that can be used to actively control the voltage drop at the trap's electrodes.
We present, and derive analytic expressions for, a fundamental limit to the sympathetic cooling of ions in radio-frequency traps using cold atoms. The limit arises from the work done by the trap electric field during a long-range ion-atom collision and applies even to cooling by a zero-temperature atomic gas in a perfectly compensated trap. We conclude that in current experimental implementations, this collisional heating prevents access to the regimes of single-partial-wave atom-ion interaction or quantized ion motion. We determine conditions on the atom-ion mass ratio and on the trap parameters for reaching the s-wave collision regime and the trap ground state.
Over the past few decades, radiofrequency ion traps have become an attractive platform for studying chemical reactions as they enable a high degree of control over ion-molecule dynamics. In this review, we summarize techniques for the trapping and cooling of atomic and molecular ions in radiofrequency traps, including Doppler and resolved-sideband laser cooling, sympathetic cooling, and cryogenic buffer-gas methods. We discuss strategies for controlling key reaction parameters: the preparation of specific internal quantum states by internal cooling, optical pumping, state-selective photoionization and quantum logic spectroscopy; the manipulation of collision energies through micromotion control, dynamic trapping, and combination with molecular beams; and the selection of molecular structure via isotopic substitution, conformational separation, and isomer-specific ion generation. We illustrate applications of these approaches by discussing studies on quantum-state-dependent kinetics, quantum resonance effects, and structure-sensitive reactivity in ion-neutral collisions. We conclude by outlining future challenges, including full state-to-state reaction mapping, reaching the ultracold quantum regime free of micromotion, and the exploration of complex and chiral systems.
Linear Paul traps use radio frequency fields to confine ions for long times in deep potentials. The simplicity and versatility of these devices has led to their use in a wide variety of fields, from mass spectroscopy to quantum information. Within the past fifteen years, beginning with pioneering work at UConn, Paul traps have been combined with atom traps to form hybrid atom-ion traps. Hybrid traps serve as platforms for measuring ion-atom interaction rates, sympathetically cooling atomic and molecular ions, and studying the behavior of trapped ions. This work discusses simulations, analytical theory, and experiments in a hybrid trap that show a previously unknown dynamical effect in a population of trapped ions. The steady state trapped ion number in a Paul trap is non-monotonic with the loading rate of the Paul trap. This effect is universal to both Linear and 3D Paul traps and is likely to be found in other types of ion traps as well because it is the result of the Coulomb interaction in the presence of a trap. This behavior also affects the decay of ions from the trap. Understanding the loading and decay behavior from a saturated Linear Paul trap is important for the study of ion-atom interactions in a hybrid trap when the ions lack optical transitions.
We actively stabilize the harmonic oscillation frequency of a laser-cooled atomic ion confined in a radiofrequency (rf) Paul trap by sampling and rectifying the high voltage rf applied to the trap electrodes. We are able to stabilize the 1 MHz atomic oscillation frequency to be better than 10 Hz or 10 ppm. This represents a suppression of ambient noise on the rf circuit by 34 dB. This technique could impact the sensitivity of ion trap mass spectrometry and the fidelity of quantum operations in ion trap quantum information applications.