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arXiv:2402.14971 · Physica Scripta

Non-coherent evolution of closed weakly interacting system leads to equidistribution of probabilities of microstates

Aleksandr Meilakhs

Published Mar 12, 2026• 0 citations
arXivHTMLPDF

Abstract

Abstract We introduce a concept of non-coherent evolution of macroscopic quantum systems. We show that for weakly interacting systems such evolution is a Markovian stochastic process. The transition rates between system states, which characterize the process, are determined by Fermi’s golden rule. Such evolution is time-irreversible and leads to the equidistribution of probabilities across every state of the system. Furthermore, we investigate the time dependence of the mean numbers of particles in single-particle states and find that, under the given assumptions, it is governed by the Boltzmann collision integral. The proposed mechanism that transforms time-reversible unitary evolution into time-irreversible stochastic evolution is non-coherence. In the presented theory, the non-coherence is not associated with interaction with a heat bath, but rather with the finite spectral width of quantum states. This understanding of non-coherence is analogous to the one used in wave optics. Thus, we present a novel approach to the famous arrow of time problem.

DOI
10.1088/1402-4896/ae5154

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Abstract We introduce a concept of non-coherent evolution of macroscopic quantum systems. We show that for weakly interacting systems such evolution is a Markovian stochastic process. The transition rates between system states, which characterize the process, are determined by Fermi’s golden rule. Such evolution is time-irreversible and leads to the equidistribution of probabilities across every state of the system. Furthermore, we investigate the time dependence of the mean numbers of particles in single-particle states and find that, under the given assumptions, it is governed by the Boltzmann collision integral. The proposed mechanism that transforms time-reversible unitary evolution into time-irreversible stochastic evolution is non-coherence. In the presented theory, the non-coherence is not associated with interaction with a heat bath, but rather with the finite spectral width of quantum states. This understanding of non-coherence is analogous to the one used in wave optics. Thus, we present a novel approach to the famous arrow of time problem.
The problem of time’s arrow is (roughly) to understand why macroscopic physical processes typically evolve in a specific direction (the one we call “the future”) even though the underlying laws of physics describing the individual microscopic systems are time-reversal invariant. The standard answer to this problem is given by Boltzmann’s explanation of the II law of thermodynamics: a classical system starting in a non-equilibrium state spontaneously (i.e. with a high level of probability) tends towards equilibrium, thus implementing an irreversible process. However, this explanation has two drawbacks: 1. it needs a further assumption on the entropy of the initial state of the universe (past hypothesis); 2. microscopic systems (e.g. molecules in a box) should be represented as quantum states and not classical states. In this talk, I want to propose a different hypothesis to explain the origin of time’s arrow, based on quantum mechanics, specifically on decoherence theory. Differently from isolated systems, open quantum systems described by decoherence theory showirreversible behavior, as they evolve towards decoherence and von Neumann entropy increase. Is this behavior a sign of genuine irreversibility? And, if so, can this be linked to thermodynamic irreversibility?
Quantum mechanics is widely recognised as being incomplete. It is not consistent with the second law of thermodynamics and does not provide a scientifically credible physical account of the measurement process, the means by which coherence is broken and classically observable states are recorded. This has led to many ad hoc assumptions being used to account for various properties of quantum systems, among which is the coherence time of quantum devices that determines their ability to perform computations. Here, we show that all these properties can be accommodated naturally and consistently in the context of mixing quantum systems which exhibit continuous spectra, as arises in the thermodynamic limit in quantum statistical mechanics and quantum gravity. In particular, for isolated systems we show that the time-reversal symmetry associated with unitary time evolution of the quantum state gives rise to time-symmetry breaking and a semi-group evolution which attains thermodynamic equilibrium at long times. Moreover, the emergence of this non-unitary time-asymmetry leads to microcanonical equilibrium states in which all quantum coherence is lost and is accompanied by the transformation of pure states into mixtures, leading in turn to an increase in entropy. Inclusion of a macroscopic measurement apparatus shows how the outcome of a measurement corresponds to the von Neumann projection postulate, arising with probabilities in conformance with the Born rule. The mathematical structure of the theory which applies to quantum systems with continuous spectra is closely analogous to the classical ergodic theory of dynamical systems and the conditions under which they attain equilibrium states.
The connection between the micro and macro-arrow of time is discussed in the frame of the stochastic quantum hydrodynamic analogy. The presence of fluctuations that in the case on non-linear interactions leads to the breaking of the quantum mechanics on large scale and then to the macroscopic irreversibility and arrow of time, gives also rise to the time reversal breaking in the micro-scale quantum stochastic evolution (micro-arrow of time). The quantum irreversibility and the theoretical tools to calculate the time reversal asymmetry in the elementary particle decays are briefly discussed.
The act of measurement on a quantum state is supposed to collapse the state into one of several eigenstates of the operator corresponding to the observable being measured. This measurement process is sometimes described as outside standard quantum-mechanical evolution and not calculable from Schr\odinger's equation. There are two general approaches to the study of wave-function collapse: one called the consistent or decoherent histories approach and the other, the environmental decoherence approach, which studies the effect of the environment upon the quantum system, to explain wave-function collapse. In the environmental decoherence approach, one usually studies a Markovian-approximated Master equation to study the time-evolution of reduced density matrix and obtains the long-term dependence of the off-diagonal elements of this matrix. We do not make a Markovian assumption and study a particularly simple and calculable example. We find, the short-time behavior of a collapsing system, at least the one considered in this paper, is not exponential, which is a new result (the long-term behavior is, of course, still exponential). This allows one to connect the Fermi-golden rule quadratic-in-time behavior of a transition probability to the exponential long-time behavior of a collapsing wave-function.
The connection between the micro and macro-arrow of time is discussed in the frame of the stochastic quantum hydrodynamic analogy (SQHA). The presence of fluctuations that in the case on non-linear interactions leads to the breaking of the quantum mechanics on large scale and then to the macroscopic irreversibility with a defined arrow of time, gives also rise to the time reversal breaking in the micro-scale quantum evolution (micro-arrow of time). The quantum irreversibility with time reversal asymmetry is briefly discussed.
Certain intriguing consequences of the discreteness of time on the time evolution of dynamical systems are discussed. In the discrete-time classical mechanics proposed here, there is an {\\it arrow of time} that follows from the fact that the replacement of the time derivative by the backward difference operator alone can preserve the non-negativity of the phase space density. It is seen that, even for free particles, all the degrees of freedom are {\\it correlated} in principle. The forward evolution of functions of phase space variables by a finite number of time steps, in this discrete-time mechanics, depends on the entire continuous-time history in the interval [0,infty][0, \\infty][0,infty]. In this sense, discrete time evolution is {\\it nonlocal} in time from a continuous-time point of view. A corresponding quantum mechanical treatment is possible {\\it via} the density matrix approach. The interference between non-degenerate quantum mechanical states decays exponentially. This {\\it decoherence} is present, in principle, for all systems; however, it is of practical importance only in macroscopic systems, or in processes involving large energy changes.