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arXiv:2402.09380 · Reviews in Mathematical Physics

On the thermodynamic limit of two-time measurement entropy production

Tristan Benoist, Laurent Bruneau, Vojkan Jakšić, Annalisa Panati, Claude‐Alain Pillet

Published Oct 10, 2024• 5 citations
arXivHTMLPDF

Abstract

We provide a justification, via the thermodynamic limit, of the modular formula for entropy production in two-time measurement proposed in [T. Benoist, L. Bruneau, V. Jakšić, A. Panati and C.-A. Pillet, A note on two-times measurement entropy production and modular theory, Lett. Math. Phys. 114:32 (2023), doi:10.1007/s11005-024-01777-0]. We consider the cases of open quantum systems in which all thermal reservoirs are either (discrete) quantum spin systems or free Fermi gases.

DOI
10.1142/s0129055x24610063

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We provide a justification, via the thermodynamic limit, of the modular formula for entropy production in two-time measurement proposed in [T. Benoist, L. Bruneau, V. Jakšić, A. Panati and C.-A. Pillet, A note on two-times measurement entropy production and modular theory, Lett. Math. Phys. 114:32 (2023), doi:10.1007/s11005-024-01777-0]. We consider the cases of open quantum systems in which all thermal reservoirs are either (discrete) quantum spin systems or free Fermi gases.
The celebrated Evans--Searles, respectively Gallavotti--Cohen, fluctuation theorem concerns certain universal statistical features of the entropy production rate of a classical system in a transient, respectively steady, state. In this paper, we review and compare several possible extensions of these fluctuation theorems to quantum systems. We present, in an introductory way, the approach proposed in a recent series of works [Lett. Math. Phys. 114, 32 (2024): doi:10.1007/s11005-024-01777-0], [Rev. Math. Phys 38, 2461006 (2026): doi:10.1142/S0129055X24610063], [Commun. Math. Phys. 406, 201 (2025): 10.1007/s00220-025-05360-z] and [J. Math. Phys. 67, 022101 (2026): doi:10.1063/5.0311182] including a previously missing extension of the Gallavotti--Cohen (steady state) version of the FT to two-time measurement entropy production in the algebraic setting of quantum dynamical systems. We focus on the open quantum systems, where a small system interacts with several (infinitely extended) reservoirs, and discuss the following approaches: naive, two-time measurement, phase space contraction and ancilla state tomography. We review the connection with modular theory. The latter provides a way to extend the classical notions to the quantum domain. We discuss the quantum version of the principle of regular entropic fluctuations, introduced in the classical context in [Nonlinearity 24, 699 (2011): doi:10.1088/0951-7715/24/3/003]. Finally, we relate the statistical properties of these various notions of entropy production to spectral resonances of quantum transfer operators and apply this approach to a paradigmatic model of non-equilibrium statistical mechanics: the spin-fermion model. The results presented here shed a new light on the nature of entropic fluctuations in quantum statistical mechanics.
Abstract The celebrated Evans–Searles, respectively Gallavotti–Cohen, fluctuation theorem concerns certain universal statistical features of the entropy production rate of a classical system in a transient, respectively steady, state. In this paper, we consider and compare several possible extensions of these fluctuation theorems to quantum systems. In addition to the direct two-time measurement approach whose discussion is based on Benoist et al. (Lett Math Phys 114:32, 2024. https://doi.org/10.1007/s11005-024-01777-0 ), we discuss a variant where measurements are performed indirectly on an auxiliary system called ancilla, and which allows to retrieve non-trivial statistical information using ancilla state tomography. We also show that modular theory provides a way to extend the classical notion of phase space contraction rate to the quantum domain, which leads to a third extension of the fluctuation theorems. We further discuss the quantum version of the principle of regular entropic fluctuations, introduced in the classical context in Jakšić et al. (Nonlinearity 24:699, 2011. https://doi.org/10.1088/0951-7715/24/3/003 ). Finally, we relate the statistical properties of these various notions of entropy production to spectral resonances of quantum transfer operators. The obtained results shed a new light on the nature of entropic fluctuations in quantum statistical mechanics.
Thermodynamics is a phenomenological theory describing the energy conversion of work and heat. At its origins thermodynamics was developed in order to understand and improve heat engines. In conventional thermodynamics, however, only such processes are completely describable which are slow enough to keep the system of interest in an equilibrium state with its thermal environment at all times. On the contrary, all real physical processes are accompanied by non-equilibrium phenomena. These are mathematically described with the help of the irreversible entropy production, i.e. the dissipated work divided by the temperature of the bath. The second law of thermodynamics merely states that the irreversible entropy production is on average always positive. The modern trend of miniaturization, however, leads to smaller and smaller devices. On short length scales thermal noise as well as quantum fluctuations become important. Thus, usual thermodynamic quantities as work and heat acquire stochastic nature. Moreover, in the quantum regime a completely new theory had to be invented, since classical notions of work and heat are no longer valid. The present dissertation contributes to this prevailing field by the derivation of analytical expressions for the entropy production in open and closed quantum system far from thermal equilibrium. The theoretical treatment is motivated by an experimental point of view. The obtained results were derived from the reduced dynamics of the quantum mechanical system, which may be coupled to a thermal bath. To this end, it was dealt with methods and approaches of statistical physics, conventional thermodynamics, quantum information theory and the theory of open quantum systems. In this dissertation the most important physical systems are treated. First, an isolated system is considered before later on a heat bath is included. The limit of weak as well as of strong coupling are analyzed in detail. For isolated systems it turns out that a geometric approach is able to capture the thermodynamic properties, completely. To this end, the irreversible entropy production is sharply estimated from below by the angle between the real non-equilibrium state and the corresponding equilibrium one. Further, it is shown that the Heisenberg uncertainty relation for energy and time can be formulated more precisely in terms of that angle. As experimental system cold ion traps are introduced, in which the theoretical predictions can be verified. For weakly coupled systems, then, the irreversible entropy production is identified and a fluctuation theorem is derived by merely thermodynamic arguments. As experimental system we, again, propose the cold ion traps, where the heat bath can be simulated with the help of LASER light. In the limit of strong coupling a semiclassical description of the reduced quantum system is discussed. Again, an analytically exact expression for the entropy production and the corresponding fluctuation theorem is derived. A physical system, in which strong coupling to the environment can be analyzed, is given by Josephson junctions. This dissertation discusses the entropy production for isolated, weakly coupled, and overdamped quantum systems. For these physical regimes analytical relation are derived and experimental systems proposed, with which the predictions can be verified.
A fluctuation theorem for the nonequilibrium entropy production in quantum phase space is derived, which enables the consistent thermodynamic description of arbitrary quantum systems, open and closed. The new treatment naturally generalizes classical results to the quantum domain. As an illustration the harmonic oscillator dragged through a thermal bath is solved numerically. Finally, the significance of the new approach is discussed in detail, and the phase space treatment is opposed to the two-time energy measurement approach.