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arXiv:2402.06022 · Physical review. E

Fluctuations and persistence in quantum diffusion on regular lattices

Cheng Ma, Omar Malik, G. Korniss

Published Feb 18, 2025• 0 citations
arXivHTMLPDF

Abstract

We investigate quantum persistence by analyzing amplitude and phase fluctuations of the wave function governed by the time-dependent free-particle Schrödinger equation. The quantum system is initialized with local random uncorrelated Gaussian amplitude and phase fluctuations. In analogy with classical diffusion, the persistence probability is defined as the probability that the local (amplitude or phase) fluctuations have not changed sign up to time t. Our results show that the persistence probability in quantum diffusion exhibits exponential-like tails. More specifically, in d=1 the persistence probability decays in a stretched exponential fashion, while in d=2 and d=3 as an exponential. We also provide some insights by analyzing the two-point spatial and temporal correlation functions in the limit of small fluctuations. In particular, in the long-time asymptotic limit, the temporal correlation functions for both local amplitude and phase fluctuations become time-homogeneous. Hence, the zero-crossing events correspond to those governed by a stationary Gaussian process, with an autocorrelation-function power-law tail decaying sufficiently fast to imply an exponential-like tail of the persistence probabilities.

DOI
10.1103/physreve.111.024126

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diffusion in disordered environments, random quantum spin chains Abstract. — We study the first passage time properties of an integrated Brownian curve both in homogeneous and disordered environments. In a disordered medium we relate the scaling properties of this center of mass persistence of a random walker to the average persistence, the latter being the probability P pr(t) that the expectation value 〈x(t) 〉 of the walker’s position after time t has not returned to the initial value. The average persistence is then connected to the statistics of extreme events of homogeneous random walks which can be computed exactly for moderate system sizes. As a result we obtain a logarithmic dependence P pr(t) ∼ ln(t) −θ with a new exponent θ = 0.191 ± 0.002. We note on a complete correspondence between the average persistence of random walks and the magnetization autocorrelation function of the transverse-field Ising chain, in the homogeneous and disordered case. First passage time or persistence problems have a long history in the physical literature [1]. Recently they gained a lot of interest, since the persistence exponents, describing the asymptotic behavior of first passage time probabilities, are shown to be independent dynamical critical exponents, which have been calculated for various models exactly[2, 3]. Not much is known about analogous quantities in systems with quenched disorder, for instance the random walk (or diffusion) in a disordered environment [4], which is in the one-dimensional case the Sinai-model[5]. For this model the first passage / persistence exponent for a single walker has been determined by us in a previous work [6]. In this letter we introduce and study the concept of average persistence of random walks both in homogeneous and random environments. We consider a random walk with nearest neighbor hopping in one dimension defined by the Master equation pi(t = 0) = δi,1,
The exponential decay of an unstable quantum state, as described by standard Markovian theories such as Fermi's Golden Rule, assumes a simple, structureless environment. However, in complex environments characterized by disorder, long-range interactions, or strong fluctuations, local decay rates fluctuate, leading to non-Markovian dynamics and power-law ``long-time tails.'' In this paper, we apply the recently proposed \textit{hyperstatistics} framework to the problem of quantum decay in such complex environments. By considering a γγγ-distribution of local decay rates across mesoscopic domains, we derive a macroscopic survival probability governed by a qqq-exponential function. We then use the qqq-generalized Gamma function, defined via the Mellin transform of the qqq-exponential, to calculate the moments of the decay-time distribution. We show that the mean quantum lifetime is ⟨t⟩=∫0∞P(t) dt=[⟨Γ⟩(2−q)]−1,\langle t\rangle = \int_0^\infty P(t)\,dt= [\langleΓ\rangle(2-q)]^{-1},⟨t⟩=∫0∞​P(t)dt=[⟨Γ⟩(2−q)]−1, and is therefore finite for q<2q<2q<2. The convergence of the second moment, and hence of the lifetime variance, instead requires the stricter condition q<3/2q<3/2q<3/2. These results provide a refined physical interpretation: for 1<q<3/21<q<3/21<q<3/2 both the mean lifetime and its variance are finite; for 3/2≤q<23/2\le q<23/2≤q<2 the mean lifetime remains finite but lifetime fluctuations become infinitely broad; and for q≥2q\ge2q≥2 the mean lifetime itself diverges, corresponding to a truly trapped, localized, or Griffiths-like regime.
The temporal behavior of quantum mechanical systems is reviewed. We mainly focus our attention on the time development of the so-called “survival” probability of those systems that are initially prepared in eigenstates of the unperturbed Hamiltonian, by assuming that the latter has a continuous spectrum. The exponential decay of the survival probability, familiar, for example, in radioactive decay phenomena, is representative of a purely probabilistic character of the system under consideration and is naturally expected to lead to a master equation. This behavior, however, can be found only at intermediate times, for deviations from it exist both at short and long times and can have significant consequences. After a short introduction to the long history of the research on the temporal behavior of such quantum mechanical systems, the short-time behavior and its controversial consequences when it is combined with von Neumann’s projection postulate in quantum measurement theory are critically overviewed from a dynamical point of view. We also discuss the so-called quantum Zeno effect from this standpoint. The behavior of the survival amplitude is then scrutinized by investigating the analytic properties of its Fourier and Laplace transforms. The analytic property that there is no singularity except a branch cut running along the real energy axis in the first Riemannian sheet is an important reflection of the time-reversal invariance of the dynamics governing the whole process. It is shown that the exponential behavior is due to the presence of a simple pole in the second Riemannian sheet, while the contribution of the branch point yields a power behavior for the amplitude. The exponential decay form is cancelled at short times and dominated at very long times by the branch-point contributions, which give a Gaussian behavior for the former and a power behavior for the latter. In order to realize the exponential law in quantum theory, it is essential to take into account a certain kind of macroscopic nature of the total system, since the exponential behavior is regarded as a manifestation of a complete loss of coherence of the quantum subsystem under consideration. In this respect, a few attempts at extracting the exponential decay form on the basis of quantum theory, aiming at the master equation, are briefly reviewed, including van Hove’s pioneering work and his well-known “λ2T” limit. In the attempt to further clarify the mechanism of the appearance of a purely probabilistic behavior without resort to any approximation, a solvable dynamical model is presented and extensively studied. The model describes an ultrarelativistic particle interacting with N two-level systems (called “spins”) and is shown to exhibit an exponential behavior at all times in the weak-coupling, macroscopic limit. Furthermore, it is shown that the model can even reproduce the short-time Gaussian behavior followed by the exponential law when an appropriate initial state is chosen. The analysis is exact and no approximation is involved. An interpretation for the change of the temporal behavior in quantum systems is drawn from the results obtained. Some implications for the quantum measurement problem are also discussed, in particular in connection with dissipation.
The theory of non-dissipative diffusion is constructed on an example of diffusion of a light particle in a dilute medium of heavy particles and it is shown that in low dissipative systems there are specific effects of non-dissipativity similar to quantum effects.In a non-dissipativity region mean energy of the light particle is conserved and processes are described by two non-linear diffusion equations with forward and backward time derivatives.Then these two diffusion equations are linearized and give one linear Schrödinger equation for complex amplitudes of probability.As a result, in the non-dissipative classical diffusion should be added probability amplitudes and there holds the superposition principle for these amplitudes.A mean square length of free passage and a mean square momentum define an elementary phase volume and a diffusion constant and they obey the uncertainty relations.It is shown that the formalism of quantum mechanics describes the classical non-dissipative diffusion with a homogeneous diffusion constant and that quantum mechanics is only a particular case when the elementary phase volume of free passage is universal and equal to the Planck constant.
Exact expressions are derived for the intermediate scattering function (ISF) of a quantum particle diffusing in a harmonic potential and linearly coupled to a harmonic bath. The results are valid for arbitrary strength and spectral density of the coupling. The general, exact non-Markovian result is expressed in terms of the classical velocity autocorrelation function, which represents an accumulated phase during a scattering event. The imaginary part of the exponent of the ISF is proportional to the accumulated phase, which is an antisymmetric function of the correlation time ttt. The expressions extend previous results given in the quantum Langevin framework where the classical response of the bath was taken as Markovian. For a special case of non-Markovian friction, where the friction kernel decays exponentially in time rather than instantaneously, we provide exact results relating to unconfined quantum diffusion, and identify general features that allow insight to be exported to more complex examples. The accumulated phase as a function of the ttt has a universal gradient at the origin, depending only on the mass of the diffusing system particle. At large ttt the accumulated phase reaches a constant limit that depends only on the classical diffusion coefficient and is therefore independent of the detailed memory properties of the friction kernel. Non-Markovian properties of the friction kernel are encoded in the details of how the accumulated phase switches from its $t\ensuremath{\rightarrow}\ensuremath{-}\ensuremath{\infty}$ to its $t\ensuremath{\rightarrow}+\ensuremath{\infty}$ limit, subject to the constraint of the universal gradient. When memory effects are significant, the transition from one limit to the other becomes nonmonotonic, owing to oscillations in the classical velocity autocorrelation. The result is interpreted in terms of a solvent caging effect, in which slowly fluctuating bath modes create transient wells for the system particle.
We address memory effects and diffusive properties of a continuous-time quantum walk on a one-dimensional percolation lattice affected by spatially correlated random telegraph noise. In particular, by introducing spatially correlated time-dependent fluctuations in nearest-neighbor hopping amplitudes, we describe random domains characterized by global noise. The resulting open dynamics of the walker is then unraveled by an ensemble average over all the noise realizations. Our results show that time-dependent noise assisted by spatial correlations leads to strong memory effects in the walker dynamics and to robust diffusive behavior against the detrimental action of uncorrelated noise. We also show that spatially correlated classical noise enhances localization breaking, thus making a quantum particle spread on longer distances across the lattice.