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arXiv:2401.07634 · Symmetry

Time–Energy Uncertainty Relation in Nonrelativistic Quantum Mechanics

Danko Dimchev Georgiev

Published Jan 14, 2024• 3 citations

Abstract

The time–energy uncertainty relation in nonrelativistic quantum mechanics has been intensely debated with regard to its formal derivation, validity, and physical meaning. Here, we analyze two formal relations proposed by Mandelstam and Tamm and by Margolus and Levitin and evaluate their validity using a minimal quantum toy model composed of a single qubit inside an external magnetic field. We show that the ℓ1 norm of energy coherence C is invariant with respect to the unitary evolution of the quantum state. Thus, the ℓ1 norm of energy coherence C of an initial quantum state is useful for the classification of the ability of quantum observables to change in time or the ability of the quantum state to evolve into an orthogonal state. In the single-qubit toy model, for quantum states with the submaximal ℓ1 norm of energy coherence, C<1, the Mandelstam–Tamm and Margolus–Levitin relations generate instances of infinite “time uncertainty” that is devoid of physical meaning. Only for quantum states with the maximal ℓ1 norm of energy coherence, C=1, the Mandelstam–Tamm and Margolus–Levitin relations avoid infinite “time uncertainty”, but they both reduce to a strict equality that expresses the Einstein–Planck relation between energy and frequency. The presented results elucidate the fact that the time in the Schrödinger equation is a scalar variable that commutes with the quantum Hamiltonian and is not subject to statistical variance.

DOI: 10.3390/sym16010100

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The time–energy uncertainty relation in nonrelativistic quantum mechanics has been intensely debated with regard to its formal derivation, validity, and physical meaning. Here, we analyze two formal relations proposed by Mandelstam and Tamm and by Margolus and Levitin and evaluate their validity using a minimal quantum toy model composed of a single qubit inside an external magnetic field. We show that the ℓ1 norm of energy coherence C is invariant with respect to the unitary evolution of the quantum state. Thus, the ℓ1 norm of energy coherence C of an initial quantum state is useful for the classification of the ability of quantum observables to change in time or the ability of the quantum state to evolve into an orthogonal state. In the single-qubit toy model, for quantum states with the submaximal ℓ1 norm of energy coherence, C<1, the Mandelstam–Tamm and Margolus–Levitin relations generate instances of infinite “time uncertainty” that is devoid of physical meaning. Only for quantum states with the maximal ℓ1 norm of energy coherence, C=1, the Mandelstam–Tamm and Margolus–Levitin relations avoid infinite “time uncertainty”, but they both reduce to a strict equality that expresses the Einstein–Planck relation between energy and frequency. The presented results elucidate the fact that the time in the Schrödinger equation is a scalar variable that commutes with the quantum Hamiltonian and is not subject to statistical variance.

In the domain of nondissipative unitary Hamiltonian dynamics, the well-known Mandelstam–Tamm–Messiah time–energy uncertainty relation τ F Δ H ≥ ℏ / 2 provides a general lower bound to the characteristic time τ F = Δ F / | d ⟨ F ⟩ / d t | with which the mean value of a generic quantum observable F can change with respect to the width Δ F of its uncertainty distribution (square root of F fluctuations). A useful practical consequence is that in unitary dynamics the states with longer lifetimes are those with smaller energy uncertainty Δ H (square root of energy fluctuations). Here we show that when unitary evolution is complemented with a steepest-entropy-ascent model of dissipation, the resulting nonlinear master equation entails that these lower bounds get modified and depend also on the entropy uncertainty Δ S (square root of entropy fluctuations). For example, we obtain the time–energy-and–time–entropy uncertainty relation ( 2 τ F Δ H / ℏ ) 2 + ( τ F Δ S / k B τ ) 2 ≥ 1 where τ is a characteristic dissipation time functional that for each given state defines the strength of the nonunitary, steepest-entropy-ascent part of the assumed master equation. For purely dissipative dynamics this reduces to the time–entropy uncertainty relation τ F Δ S ≥ k B τ , meaning that the nonequilibrium dissipative states with longer lifetime are those with smaller entropy uncertainty Δ S .

Non-Hermitian Hamiltonians play a crucial role in describing open quantum systems and nonequilibrium dynamics. In this paper, we derive trade-off relations for systems governed by non-Hermitian Hamiltonians, focusing on the Margolus-Levitin-type and Mandelstam-Tamm-type bounds, which are originally derived as quantum speed limits in isolated quantum dynamics. While the quantum speed limit for the Mandelstam-Tamm bound in general non-Hermitian systems was derived in the literature, we obtain a Mandelstam-Tamm quantum speed limit for continuous measurement using the continuous matrix product state formalism. Moreover, we derive a Margolus-Levitin quantum speed limit in the non-Hermitian setting. We derive additional bounds on the ratio of the standard deviation to the mean of an observable, which take the same form as the thermodynamic uncertainty relation. As an example, we apply these bounds to the continuous measurement formalism in open quantum dynamics, where the dynamics is described by discontinuous jumps and smooth evolution induced by the non-Hermitian Hamiltonian. Our work provides a unified perspective on the quantum speed limit and thermodynamic uncertainty relations in open quantum dynamics from the viewpoint of the non-Hermitian Hamiltonian, extending the results of previous studies.

The quantum-mechanical framework in which observables are associated with Hermitian operators is too narrow to discuss measurements of such important physical quantities as elapsed time or harmonic-oscillator phase. We introduce a broader framework that allows us to derive quantum-mechanical limits on the precision to which a parameter---e.g., elapsed time---may be determined via arbitrary data analysis of arbitrary measurements on N identically prepared quantum systems. The limits are expressed as generalized Mandelstam-Tamm uncertainty relations, which involve the operator that generates displacements of the parameter---e.g., the Hamiltonian operator in the case of elapsed time. This approach avoids entirely the problem of associating a Hermitian operator with the parameter. We illustrate the general formalism, first, with nonrelativistic uncertainty relations for spatial displacement and momentum, harmonic-oscillator phase and number of quanta, and time and energy and, second, with Lorentz-invariant uncertainty relations involving the displacement and Lorentz-rotation parameters of the Poincar\\'e group.

The time-energy uncertainty relation is often invoked as a heuristic explanation for virtual particles in interacting quantum field theories. However, this interpretation breaks down upon closer scrutiny for several reasons, particularly since virtual particles do not have a well-defined temporal extension. Although concrete derivations and interpretations of time-energy uncertainty bounds in quantum mechanics have been established, most famously by Mandelstam and Tamm in 1945, there is no known rigorous connection between these bounds and the concept of virtual particles in quantum field theory. In this work, we use a model in which the vacuum particle content associated with subcycle, spatiotemporally localised modes of a free scalar field can be converted into excitations of a rapidly-switched harmonic-oscillator Unruh-DeWitt detector coupled to the conjugate field. Defining the time uncertainty as the effective duration of the detector-field interaction and identifying the contribution to the energy fluctuations of the detector resulting from the subcycle mode vacuum fluctuations, we show that a time-energy uncertainty relation is satisfied in the deep subcycle regime. Our results provide a concrete operational meaning to the textbook heuristic picture of virtual particles in quantum field theory in terms of the time-energy uncertainty principle.