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arXiv:2312.08239

The Derivation of the Boltzmann Equation from Quantum Many-body Dynamics

Xuwen Chen, Justin Holmer

Published Dec 13, 2023• 0 citations
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Abstract

We consider the quantum many-body dynamics at the weak-coupling scaling. We derive rigorously the quantum Boltzmann equation, which contains the classical hard sphere model and, effectively, the inverse power law model, from the many-body dynamics assuming a physical and optimal regularity bound. The regularity bound we find, on the one hand, is satisfied by quasi-free solutions and comes from calculations regarding the local Maxwellian solution, in which we also prove that 2-body molecular chaos never happens unless $N=+\infty$; on the other hand, it arises from the well-posedness threshold of the limiting Boltzmann equation below which we prove ill-posedness. That is, the regularity cannot be higher at the $N$-body level, cannot be lower in the limit, and is hence a double criticality. To work with this borderline case, we analyze all four sides, with respect to the Fourier transform, of the BBGKY hierarchy sequence with new tools and techniques. We prove well-definedness, compactness, convergence, and uniqueness of hierarchies right at the criticality to complete an optimal derivation. In particular, we have proved that, for physical $N$-particle solutions, the Boltzmann equation emerges as the mean-field limit and time is hence irreversible, from first principles of quantum mechanics.

DOI
10.48550/arxiv.2312.08239

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We consider the quantum many-body dynamics at the weak-coupling scaling. We derive rigorously the quantum Boltzmann equation, which contains the classical hard sphere model and, effectively, the inverse power law model, from the many-body dynamics assuming a physical and optimal regularity bound. The regularity bound we find, on the one hand, is satisfied by quasi-free solutions and comes from calculations regarding the local Maxwellian solution, in which we also prove that 2-body molecular chaos never happens unless N=+∞N=+\inftyN=+∞; on the other hand, it arises from the well-posedness threshold of the limiting Boltzmann equation below which we prove ill-posedness. That is, the regularity cannot be higher at the NNN-body level, cannot be lower in the limit, and is hence a double criticality. To work with this borderline case, we analyze all four sides, with respect to the Fourier transform, of the BBGKY hierarchy sequence with new tools and techniques. We prove well-definedness, compactness, convergence, and uniqueness of hierarchies right at the criticality to complete an optimal derivation. In particular, we have proved that, for physical NNN-particle solutions, the Boltzmann equation emerges as the mean-field limit and time is hence irreversible, from first principles of quantum mechanics.
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This thesis is about the derivation of effective mean field equations and their next-order corrections starting from nonrelativistic many-body quantum theory. Mean field equations provide an approximate ansatz for the description of interacting many-particle systems. In this ansatz the interaction between the particles is replaced by a self-consistent external potential leading to an effective one-body description of the many-particle system. Next-order corrections provide an approximation which goes one step further and tries to capture also subleading effects that are not resolved by the mean field ansatz. We present mathematical proofs for the validity of such effective theories for different models that are motivated, e.g., from the theory of ultracold atoms (the bosonic Hartree equation and the corresponding Bogoliubov theory) and from plasma physics (the motion of a tracer particle through a degenerate and dense electron gas). Starting from a many-body Schrödinger equation, our goal is to show that the solutions converge in a particular limit to the solutions to an effective mean field equation and its next-order corrections. After a short introduction and a summary in Chapter one, we present the main part of this work in three self-contained chapters. In Chapter two we analyze the dynamics of a large number N of nonrelativistic bosons in the weak coupling limit, i.e., for a coupling constant g_N=1/N. It is well known that in the limit of infinite particle number, the Hartree equation emerges as an effective one-particle theory of the Bose gas. This is closely related to the remarkable physical phenomenon of Bose-Einstein condensation at low temperature, namely that the majority of particles in a Bose gas occupies the same copy of a single one-particle quantum state. Our emphasis lies in the description of the few particles that fluctuate around the Bose-Einstein condensate. We show convergence of the fully interacting dynamics to an auxiliary time evolution in the norm of the N-particle space. This result allows us to prove several other assertions. Among other things, it is used to derive the Hartree equation with optimal speed of convergence 1/N for initial states that are close to ground states of interacting systems and also to prove convergence of the N-particle solution towards a time evolution obtained from the Bogoliubov Hamiltonian on Fock space. Chapter three is about the low energy properties of the weakly interacting homogeneous Bose gas. Here, we derive a novel estimate for low energy eigenfunctions stating that the probability for finding lll particles out of their total number N not in the condensate is exponentially small in the number lll. Using this bound, we then prove that the ground state wave function of the microscopic model satisfies certain quasifree type properties. The exponential decay is moreover used to provide an alternative proof for the validity of Bogoliubov's approximation for the low-lying energy eigenvalues. Bogoliubov theory states that the excitation energies of the Bose gas are given by excitations of free quasiparticles obeying an effective energy-momentum dispersion relation which is linear for small momentum. The linearity of the effective dispersion relation is an essential ingredient for the explanation of the superfluid character of the Bose gas. In Chapter four we study the time evolution of a single particle coupled through a pair potential to a dense and homogeneous ideal Fermi gas in two spatial dimensions. This type of model is well known in plasma physics where it is used to describe the energy loss of ions moving through a dense and degenerate electron gas. We analyze the model for a coupling parameter g=1 and prove closeness of the time evolution to an effective dynamics for large densities of the gas and for long time scales of the order of some power of the density. The effective dynamics is generated by the free Hamiltonian with a large but constant energy shift. To leading order, this energy shift is given by the spatially homogeneous mean field potential produced by the gas particles, whereas at next-to-leading order, one has to consider an additional correction to the mean field energy which is due to so-called recollision processes.
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