Rydberg atoms as versatile tools for quantum applications are extremely sensitive to electric fields. When utilizing these atoms, it becomes imperative to comprehensively characterize and mitigate ambient electric field noise. Using single Rydberg atoms in optical tweezer arrays, we reveal that the dominant ambient electric field noise originates from electrons bound to the vacuum cell surface. These electrons are found to be generated by the 297-nm light used for single-photon Rydberg excitation. Once the electrons are effectively desorbed from the surface through exposure to ultraviolet or red light, the coherence of the ground-Rydberg transition is enhanced significantly. Furthermore, we demonstrate collective oscillations of four atoms in the full Rydberg blockade regime. Our investigations will advance the control and reliability of Rydberg-atom-based systems for various quantum technologies.
Rydberg atoms as versatile tools for quantum applications are extremely sensitive to electric fields. When utilizing these atoms, it becomes imperative to comprehensively characterize and mitigate ambient electric field noise. Using single Rydberg atoms in optical tweezer arrays, we reveal that the dominant ambient electric field noise originates from electrons bound to the vacuum cell surface. These electrons are found to be generated by the 297-nm light used for single-photon Rydberg excitation. Once the electrons are effectively desorbed from the surface through exposure to ultraviolet or red light, the coherence of the ground-Rydberg transition is enhanced significantly. Furthermore, we demonstrate collective oscillations of four atoms in the full Rydberg blockade regime. Our investigations will advance the control and reliability of Rydberg-atom-based systems for various quantum technologies.
Neurtal atoms in optical tweezer arrays constitute a highly promising platform for quantum computing and quantum simulation. Their operation relies on precise control of the Rydberg excitation, which is highly sensitive to background electric fields. Here, we identify a previously overlooked source of stray electric fields arising from trapped charges within the antireflection coating layers of glass vacuum cells. In contrast to the conventional approach of removing surface charges through ultraviolet-light-induced desorption, we compensate these clamped charges by generating additional charges via photo-ionization of a cold atomic ensemble. We verify the resulting suppression of stray electric fields through Rydberg excitation spectroscopy in an atomic array and further confirm that the residual electric field inside the vacuum cell is effectively eradicated with the aid of external electrodes. Our work identifies and mitigates a previously unrecognized source of residual electric field, providing a practical solution for improving the performance of neutral atomic quantum processors and other Rydberg-based quantum technologies, as well as surface-sensitive atomic systems.
Integrating Rydberg-state control of atom-atom interactions with cavity control of atom-light interactions enables the combination of local entangling operations with photon-mediated long-range coupling, measurement, and communication. Such integration is challenging because electric fields generated by charges on cavity optics and by cavity-stabilizing actuators may disturb Rydberg-state coherence. Here, we couple a Rydberg tweezer array to a high-cooperativity optical cavity, suppressing the electric fields produced by cavity length actuation so that the residual field variation of about 3mV/cm rms does not limit Rydberg coherence. We demonstrate two capabilities that neither system provides alone. First, we use Purcell-enhanced fluorescence to read out atoms directly in the ground-Rydberg basis within 7.5μs, well within the Rydberg-state lifetime, with ground- and Rydberg-state detection infidelities of 3% and 5%, respectively, and with low atom loss. Second, we use Rydberg-Rydberg interactions to control collective light-atom scattering into the cavity mode. Specifically, we drive blockaded Rabi oscillations between a state with two ground-state atoms, which scatter collectively with a superradiant or subradiant rate controlled by the atomic positions, and an entangled state with a single Rydberg excitation, which scatters like a single atom. These capabilities open routes toward networked Rydberg processors, mid-circuit measurements in analog quantum simulators, and many-body quantum optics with entangled emitters coupled collectively to light.
Hybrid quantum platforms based on highly excited Rydberg atoms coupled to nanophotonics devices offer a promising route toward scalable quantum networks and integrated quantum technologies. However, the close proximity of Rydberg atoms to dielectric nanostructures makes these systems particularly susceptible to uncontrolled surface electric fields that can lead to a degradation of the excitation process. Here, we experimentally investigate Rydberg excitation of laser-cooled 87Rb atoms via the evanescent field of an optical nanofiber in the presence of fiber-guided red- and blue-detuned light fields as used to trap ground state atoms in fiber-based dipole traps. We observe a time evolution of the Rydberg excitation spectrum when both the dipole trapping fields are on and the additional spectral features that appear can be suppressed by applying an external oscillating electric field to the system, strongly indicating that surface charge accumulation is responsible for the observed spectral feature. The experimental results are reproduced qualitatively by a model that incorporates DC energy level shifts arising from electric fields generated by charges deposited on the nanofiber surface. We identify Rydberg-ground state collisional ionization, which is enhanced by the dipole trapping fields, as the dominant mechanism for charge generation. These results provide new insight into charge dynamics at dielectric nanophotonic interfaces and establish practical guidelines for mitigating surface charge-induced electric fields in fiber-integrated Rydberg quantum systems.
Coherent control of Rydberg atoms near dielectric surfaces is a major challenge due to the large sensitivity of Rydberg states to electric fields. We demonstrate coherent single-atom operations and two-qubit entanglement as close as 100 μm from a nanophotonic device. Using the individual atom control enabled by optical tweezers to study the spatial and temporal properties of the electric field from the surface, we employ dynamical decoupling techniques to characterize and cancel the electric-field noise with submicrosecond temporal resolution. We further use entanglement-assisted sensing to accurately map magnitude and direction of electric-field gradients on a micrometer scale. Our observations open a path for integration of Rydberg arrays with micro- and nanoscale devices for applications in quantum networking and quantum information science.
Rydberg atoms are highly sensitive to external electric fields due to their exaggerated electronic properties. This unique feature lays the foundation for many of their applications in quantum science. However, an uncontrolled stray electric field can be detrimental, severely degrading their quantum control. In this work, we demonstrate a universal scheme that relies on the efficient creation of an in-vacuum plasma source by photo-ionizing laser-cooled atoms to eliminate detrimental electric fields in a Rydberg-atom tweezer array platform, requiring only readily available resources. With this method, we began with a Stark-ionized Rydberg continuum spectrum caused by a large, unknown stray electric field and ultimately recovered stable, coherent excitation of an individual Rydberg state after fully eliminating the field. Our method is directly applicable to existing Rydberg-atom platforms and can also be useful in other experiments sensitive to stray electric fields.
Highly excited (Rydberg) atoms have exaggerated properties making them extremely sensitive to external electromagnetic fields and interacting strongly with their environment. Atomic vapor cells represent an attractive platform for studying Rydberg atoms and fabricating quantum devices. For example, Rydberg atoms in vapor cells have been used as sensitive detectors of electric fields of frequencies ranging from DC up to the THz range but also as single photon sources for quantum technology applications exploiting collective phenomena due to the Rydberg blockade effect [1]. Rydberg atoms also find applications in fundamental physics, in particular for the measurement of dispersive interactions of the Casimir-Polder type (atom-surface interactions) [2]. One major advantage of Rydberg atoms is that they expose limitations in the traditional perturbative approach of Casimir-Polder (CP) theory [3, 4]. Indeed, in the extreme near-field, the dipole approximation breaks down and higher-order terms need to be considered. We report on extensive experimental measurements of the Rydberg-surface interaction using spectroscopy in cesium vapor nanocells of a thickness ranging roughly from 200-700nm, as well as selective reflection spectroscopy on a macroscopic cesium all-sapphire cell. Atoms are first excited to the Cs(6P) level with a 894nm pump laser and subsequently a green laser ≈ 510nm probes Rydberg nD or nS states, where the principal quantum number n ranges between 15-17. Our experiments evidence the dipole-dipole term of the Casimir-Polder interaction providing a measurement of the C3 coefficient for cesium Rydberg states. Furthermore, our experiment clearly evidences an additional interaction that induces shifts and broadens the linewidth of the probed transitions in the vicinity of the dielectric windows of our cells. We believe that this interaction is due to electric fields that are either generated by patch charges (trapped on the surface or induced by the excitation lasers), or by cesium adsorbants. We show that the different polarizability (of opposing sign) between S and D Rydberg states can be exploited to extract quantitative measurements of the strength and distance scaling (z-dependence) of such parasitic electrostatic interactions.Our experiments suggest that the sensitivity of Rydberg atoms to external electric fields could provide a unique tool for probing electrostatic interactions in the vicinity of surfaces. This could allow systematic error corrections in Casimir-Polder experiments with excited or even ground state atoms that aim at putting bounds on the existence of non-Newtonian gravity [5]. We are currently exploring the possibility of coating the internal window interfaces with conducting 2D material such as graphene to reduce the influence of parasitic charges. This could allow us to probe atoms closer to the surface, where quadrupole interactions could be experimentally attainable for the first time [4].References[1] H. Kubler, J. P. Shaffer, T. Baluktsian, R. Loew, T. Pfau, Nat. Photon., 4, 112–116 (2013).[2] V. Sandoghdar et al., Phys. Rev. Lett 68, 3432–3435 (1993).[3] J. A. Crosse et al., Phys. Rev. A 82, 3010901 (2010).[4] B. Dutta et al., Phys. Rev. Res. 6, L022035 (2024).[5] A. Laliotis, B-S. Lu, M. Ducloy, D. Wilkowski, AVS Quantum Sci. 3, 043501 (2021).