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arXiv:2310.08547 · Journal of Statistical Mechanics Theory and Experiment

Kondo screening cloud scaling: impurity entanglement and magnetization

Erik Schwartz Sørensen

Published Jan 1, 2024• 1 citation
arXivHTMLPDF

Abstract

Abstract The screening of an impurity spin in the Kondo model occurs over a characteristic length scale ξ K , that defines the size of the Kondo screening cloud or ‘mist’. The presence of such a length scale in experimental and numerical results is rather subtle. A consistent way to show the presence of the screening cloud is to demonstrate scaling in the spatial correlations in terms of the single variable, r / ξ K instead of the correlations depending on r and ξ K separately. Here we study the paradigmatic one channel Kondo model using a spin chain representation, with an impurity spin at one end of the chain coupled with a strength J K ′ . Using Fermi liquid theory combined with numerical results, we obtain new high precision estimates of the non-universal terms in the entanglement entropy which leads to a verification of the expected non-integer ground-state degeneracy, g. This then allows us to study the impurity contribution to the entanglement in detail. If the impurity coupling J K ′ is varied, a precise determination of ξ K can then be obtained. The length scale, ξ K , is then shown to characterize the scaling of both the uniform and alternating part of a measure of the magnetization of part of an odd length chain.

DOI
10.1088/1742-5468/ad1d53

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Abstract The screening of an impurity spin in the Kondo model occurs over a characteristic length scale ξ K , that defines the size of the Kondo screening cloud or ‘mist’. The presence of such a length scale in experimental and numerical results is rather subtle. A consistent way to show the presence of the screening cloud is to demonstrate scaling in the spatial correlations in terms of the single variable, r / ξ K instead of the correlations depending on r and ξ K separately. Here we study the paradigmatic one channel Kondo model using a spin chain representation, with an impurity spin at one end of the chain coupled with a strength J K ′ . Using Fermi liquid theory combined with numerical results, we obtain new high precision estimates of the non-universal terms in the entanglement entropy which leads to a verification of the expected non-integer ground-state degeneracy, g. This then allows us to study the impurity contribution to the entanglement in detail. If the impurity coupling J K ′ is varied, a precise determination of ξ K can then be obtained. The length scale, ξ K , is then shown to characterize the scaling of both the uniform and alternating part of a measure of the magnetization of part of an odd length chain.
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We analyze the spatial correlation structure of the spin density of an electron gas in the vicinity of an antiferromagnetically coupled Kondo impurity. Our analysis extends to the regime of spin-anisotropic couplings, where there are no quantitative results for spatial correlations in the literature. We use an original and numerically exact method, based on a systematic coherent-state expansion of the ground state of the underlying spin-boson Hamiltonian. It has not yet been applied to the computation of observables that are specific to the fermionic Kondo model. We also present an important technical improvement to the method that obviates the need to discretize modes of the Fermi sea, and allows one to tackle the problem in the thermodynamic limit. As a result, one can obtain excellent spatial resolution over arbitrary length scales, for a relatively low computational cost, a feature that gives the method an advantage over popular techniques such as the numerical and density-matrix renormalization groups. We find that the anisotropic Kondo model shows rich universal scaling behavior in the spatial structure of the entanglement cloud. First, SU(2) spin-symmetry is dynamically restored in a finite domain in the parameter space in the vicinity of the isotropic line, as expected from poor man's scaling. More surprisingly, we are able to obtain in closed analytical form a set of different, yet universal, scaling curves for strong exchange asymmetry, which are parametrized by the longitudinal exchange coupling. Deep inside the cloud, i.e., for distances smaller than the Kondo length, the correlation between the electron spin density and the impurity spin oscillates between ferromagnetic and antiferromagnetic values at the scale of the Fermi wavelength, an effect that is drastically enhanced at strongly anisotropic couplings. Our results also provide further numerical checks and alternative analytical approximations for the Kondo overlaps that were recently computed by Lukyanov, Saleur, Jacobsen, and Vasseur [Phys. Rev. Lett. 114, 080601 (2015)].
The existence of a length scale ${\ensuremath{\xi}}_{K}\ensuremath{\sim}1/{T}_{K}$ (with TK{T}_{K}TK​ the Kondo temperature) has long been predicted in quantum impurity systems. At low temperatures $T\ensuremath{\ll}{T}_{K}$, the standard interpretation is that a spin-12\frac{1}{2}21​ impurity is screened by a surrounding ``Kondo cloud'' of spatial extent ${\ensuremath{\xi}}_{K}$. We argue that renormalization group (RG) flow between any two fixed points (FPs) results in a characteristic length scale, observed in real space as a crossover between physical behavior typical of each FP. In the simplest example of the Anderson impurity model, three FPs arise, and we show that ``free orbital,'' ``local moment,'' and ``strong coupling'' regions of space can be identified at zero temperature. These regions are separated by two crossover length scales ${\ensuremath{\xi}}_{\text{LM}}$ and ${\ensuremath{\xi}}_{K}$, with the latter diverging as the Kondo effect is destroyed on increasing temperature through TK{T}_{K}TK​. One implication is that moment formation occurs inside the ``Kondo cloud'', while the screening process itself occurs on flowing to the strong coupling FP at distances $\ensuremath{\sim}{\ensuremath{\xi}}_{K}$. Generic aspects of the real-space physics are exemplified by the two-channel Kondo model, where ${\ensuremath{\xi}}_{K}$ now separates local moment and overscreening clouds.
Two electronic channels competing to screen a single impurity spin, as in the two-channel Kondo model, are expected to generate a ground state with a nontrivial entanglement structure. We exploit a spin-chain representation of the two-channel Kondo model to probe the ground-state block entropy, negativity, tangle, and Schmidt gap, using a density matrix renormalization group approach. In the presence of symmetric coupling to the two channels, we confirm field-theory predictions for the boundary entropy difference ln(gUV/gIR)=ln(2)/2ln({g}_{\text{UV}}/{g}_{\text{IR}})=ln(2)/2ln(gUV​/gIR​)=ln(2)/2 between the ultraviolet and infrared limits and the leading ln(x)/xln(x)/xln(x)/x impurity correction to the block entropy. The impurity entanglement Simp{S}_{\text{imp}}Simp​ is shown to scale with the characteristic length ${\ensuremath{\xi}}_{2\text{CK}}$. We show that both the Schmidt gap and the entanglement of the impurity with one of the channels---as measured by the negativity---faithfully serve as order parameters for the impurity quantum phase transition appearing as a function of channel asymmetry, allowing for explicit determination of critical exponents, $\ensuremath{\nu}\ensuremath{\approx}2$ and $\ensuremath{\beta}\ensuremath{\approx}0.2$. Remarkably, we find the emergence of tripartite entanglement only in the vicinity of the critical channel-symmetric point.
Abstract We investigate the boundary phenomena that arise in a finite-size XX spin chain interacting through an XX interaction with a spin − 1 2 impurity located at its edge. Upon Jordan–Wigner transformation, the model is described by a quadratic Fermionic Hamiltonian. Our work displays, within this ostensibly simple model, the emergence of the Kondo effect, a quintessential hallmark of strongly correlated physics. We also show how the Kondo cloud shrinks and turns into a single particle bound state as the impurity coupling increases beyond a critical value. In more detail, using both Bethe Ansatz and exact diagonalization techniques, we show that the local moment of the impurity is screened by different mechanisms depending on the ratio of the boundary and bulk coupling J imp J . When the ratio falls below the critical value 2 , the impurity is screened via the Kondo effect. However, when the ratio between the coupling exceeds the critical value 2 an exponentially localized bound mode is formed at the impurity site which screens the spin of the impurity in the ground state. We show that the boundary phase transition is reflected in local ground state properties by calculating the spinon density of states, the magnetization at the impurity site in the presence of a global magnetic field, and the finite temperature susceptibility of the impurity. We find that the spinon density of states in the Kondo phase has the characteristic Lorentzian peak that moves from the Fermi level to the maximum energy of the spinon as the impurity coupling is increased and becomes a localized bound mode in the bound mode phase. Moreover, the impurity magnetization and the finite temperature impurity susceptibility behave differently in the two phases. When the boundary coupling J imp exceeds the critical value 2 J , the model is no longer boundary conformal invariant as a massive bound mode appears at the impurity site.
When a local impurity spin interacts with conduction electrons whose density of states (DOS) has a (pseudo)gap or diverges at the Fermi energy, a local moment (LM) phase can be favored over a Kondo phase. Theoretically studying quantum entanglement between the impurity and conduction electrons, we demonstrate that conduction electrons form an LM spin cloud in general LM phases, which corresponds to, but has a fundamental difference from, the Kondo cloud screening the impurity spin in the Kondo phase. The LM cloud algebraically decays over the distance from the impurity when the DOS has a pseudogap or divergence, and exponentially when it has a hard gap. We find an LM cloud length, a single length scale characterizing a universal form of the LM cloud. The findings are supported by both analytic theories and numerical computations.