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arXiv:2309.12393 · Physical Review Research

Constraining work fluctuations of non-Hermitian dynamics across the exceptional point of a superconducting qubit

Serra Erdamar, Maryam Abbasi, Byung Ha, Weijian Chen, Jacob Muldoon, Yogesh N. Joglekar, Kater W. Murch

Published Apr 16, 2024• 8 citations
arXivHTMLPDF

Abstract

Thermodynamics constrains changes to the energy of a system, both deliberate and random, via its first and second laws. When the system is not in equilibrium, fluctuation theorems such as the Jarzynski equality further restrict the distributions of deliberate work done. Such fluctuation theorems have been experimentally verified in small, nonequilibrium quantum systems undergoing unitary or decohering dynamics. Yet, their validity in systems governed by a non-Hermitian Hamiltonian has long been contentious due to the false premise of the Hamiltonian's dual and equivalent roles in dynamics and energetics. Here we show that work fluctuations in a non-Hermitian qubit obey the Jarzynski equality even if its Hamiltonian has complex or purely imaginary eigenvalues. With postselection on a dissipative superconducting circuit undergoing a cyclic parameter sweep, we experimentally quantify the work distribution using projective energy measurements and show that the fate of the Jarzynski equality is determined by the parity-time symmetry of, and the energetics that result from, the corresponding non-Hermitian, Floquet Hamiltonian. By distinguishing the energetics from non-Hermitian dynamics, our results provide the recipe for investigating the nonequilibrium quantum thermodynamics of such open systems. Published by the American Physical Society 2024

DOI
10.1103/physrevresearch.6.l022013

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Thermodynamics constrains changes to the energy of a system, both deliberate and random, via its first and second laws. When the system is not in equilibrium, fluctuation theorems such as the Jarzynski equality further restrict the distributions of deliberate work done. Such fluctuation theorems have been experimentally verified in small, nonequilibrium quantum systems undergoing unitary or decohering dynamics. Yet, their validity in systems governed by a non-Hermitian Hamiltonian has long been contentious due to the false premise of the Hamiltonian's dual and equivalent roles in dynamics and energetics. Here we show that work fluctuations in a non-Hermitian qubit obey the Jarzynski equality even if its Hamiltonian has complex or purely imaginary eigenvalues. With postselection on a dissipative superconducting circuit undergoing a cyclic parameter sweep, we experimentally quantify the work distribution using projective energy measurements and show that the fate of the Jarzynski equality is determined by the parity-time symmetry of, and the energetics that result from, the corresponding non-Hermitian, Floquet Hamiltonian. By distinguishing the energetics from non-Hermitian dynamics, our results provide the recipe for investigating the nonequilibrium quantum thermodynamics of such open systems. Published by the American Physical Society 2024
As quantum systems are understood better from a fundamental physics perspective, we are gaining more insight and ideas for their many applications. Among them are quantum computation, sensing, and materials. Some difficulties that have been encountered are short lifetimes and coupling to unwanted modes while attempting to control these systems, resulting in error propagation. Previously, physicists have pursued Hermitian descriptions of systems to preserve unitary evolution and real-valued measurements. However, non-Hermitian systems not only provide a realistic description of physical systems within larger environments, but also a rich topological landscape from their complex energy spectrum. In this thesis, we will explore how to control a non-Hermitian qubit to utilize its complex spectrum and the role of its Hamiltonian in energetics and time dynamics. Because superconducting qubits offer flexibility in parameter tuning, we can tune the values of the non-Hermitian Hamiltonian to explore this complex spectrum across regions of both $\PT$-symmetry and $\PT$-symmetry breaking. This complex energy spectrum forms a Riemann surface that has a branch cut and branch points (exceptional points). Encircling these exceptional points adiabatically allows for state transport that can non-trivially convert between eigenstates. Previous experimental studies of this process revealed a chirality: eigenstate conversion occurs when following the state with higher gain, but breaks down when following the state with higher loss. We explore how the interplay between gain and loss in modes of the system results in the breakdown of this adiabaticity and how we can use a method based on shortcuts to adiabaticity to circumvent this. Finally, we leverage this tunability to further investigate how the components of the non-Hermitian Hamiltonian relate to classical thermodynamic notions of internal energy and work in time-dependent protocols via the Jarzynski equality.
The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasistatic process. This fluctuation theorem bears experimental relevance, as it enables the determination of the free energy difference through the measurement of externally applied work in a nonequilibrium process. In the quantum case, the Jarzynski equality only holds if the measurement procedure of the stochastic work is drastically changed: it is replaced by a so-called two-point measurement scheme that requires the knowledge of the initial and final Hamiltonian and therefore lacks the predictive power for the free energy difference that the classical Jarzynski equation is known for. Here, we propose a quantum fluctuation theorem that is valid for externally measurable quantum work determined during the driving protocol. In contrast to the two-point measurement case, the theorem also applies to open quantum systems and the scenario can be realized without knowing the system Hamiltonian. Our fluctuation theorem comes in the form of an inequality and therefore only yields bounds to the true free energy difference. The inequality is saturated in the quasiclassical case of vanishing energy coherences at the beginning and at the end of the protocol. Thus, there is a clear quantum disadvantage.
Symmetry-Enforced Non-Hermitian Jarzynski Equality in an SU(2)-Rotated Family of Hybrid PT\mathcal{PT}PT--APT\mathcal{APT}APT Systems
The Jarzynski equality is a cornerstone of nonequilibrium thermodynamics, linking work statistics to equilibrium free-energy differences. Although it has been extensively verified in classical and quantum Hermitian settings, its status in non-Hermitian dynamics remains under debate. Here we show that, in a postselected no-quantum-jump framework, a conditional non-Hermitian Jarzynski equality holds when the transition probabilities obey a parity-exchange symmetry. We study a constructed family of two-level hybrid Hamiltonians formed as linear combinations of parity-time (PT\mathcal{PT}PT) and anti-parity-time (APT\mathcal{APT}APT) symmetric terms, and demonstrate using complementary geometric and algebraic arguments that the parity-exchange symmetry persists throughout the corresponding SU(2)\mathrm{SU}(2)SU(2)-rotated orbit. Relative to previous PT\mathcal{PT}PT-focused conditional Jarzynski equality results, the advance here is an extension of the symmetry criterion from the isolated PT\mathcal{PT}PT endpoint to a broader PT\mathcal{PT}PT--APT\mathcal{APT}APT hybrid family. Experimentally, we implement three representative points, θk=0,π/4,π/2θ_k = 0, π/4, π/2θk​=0,π/4,π/2, in a single trapped 171Yb+^{171}\mathrm{Yb}^+171Yb+ ion and measure the resulting work distributions under cyclic protocols with ΔF=0ΔF = 0ΔF=0, confirming the predicted symmetry criterion at those points. Our results establish a symmetry-based extension of the conditional non-Hermitian Jarzynski relation within this restricted two-level setting.
We first derive the Jarzynski relation [1] between the average exponential of the thermodynamical work and the exponential of the difference between the initial and final free energy. We then comment on the information-theoretic underpinning of Jarzynski’s reasoning which helps explain why the Jarzynski relation holds identically both quantumly and classically [2]. We then present a scheme to verify the quantum non-equilibrium fluctuation relations as encapsulated by Jarzynski. We show that the characteristic function of the work distribution of a quantum system (which is basically equal to the Wick rotated average exponential of the thermodynamical work) can be extracted from Ramsey interferometry of a single probe qubit (which need not itself be pure, though it must not be fully depolarized) [3,4].We first derive the Jarzynski relation [1] between the average exponential of the thermodynamical work and the exponential of the difference between the initial and final free energy. We then comment on the information-theoretic underpinning of Jarzynski’s reasoning which helps explain why the Jarzynski relation holds identically both quantumly and classically [2]. We then present a scheme to verify the quantum non-equilibrium fluctuation relations as encapsulated by Jarzynski. We show that the characteristic function of the work distribution of a quantum system (which is basically equal to the Wick rotated average exponential of the thermodynamical work) can be extracted from Ramsey interferometry of a single probe qubit (which need not itself be pure, though it must not be fully depolarized) [3,4]. An interesting fact is that while the quantum version of the Jarzynski equality remains satisfied even in the presence of quantum correlations, the individual thermodynamical work moments in the expansion of the free energy are, in fact, sensitive to the genuine quantum correlations [5]. Whether this is a fortuitous coincidence remains to be seen, but it certainly goes towards explaining why the laws of thermodynamics happen to be so robust as to be independent of the underlying micro-physics.We intend to elucidate the subtle connection between Jarzynski’s relation and the “quantum arrow of time”. Finally we comment on the fact that our scheme for measuring the quantum work characteristic function belongs to the computational class known as DCQ1 [6], namely all computations that can be performed with only one pure qubit (and N maximally mixed ones).
The quantum Jarzynski equality and the Crooks relation are fundamental laws connecting equilibrium processes with nonequilibrium fluctuations.They are promising tools to benchmark quantum devices and measure free energy differences.While they are well established theoretically and also experimental realizations for few-body systems already exist, their experimental validity in the quantum many-body regime has not been observed so far.Here, we present results for nonequilibrium protocols in systems with up to 16 interacting degrees of freedom obtained on trapped ion and superconducting qubit quantum computers, which test the quantum Jarzynski equality and the Crooks relation in the many-body regime.To achieve this, we overcome present-day limitations in the preparation of thermal ensembles and in the measurement of work distributions on noisy intermediate-scale quantum devices.We discuss the accuracy to which the Jarzynski equality holds on different quantum computing platforms subject to platformspecific errors.The analysis reveals the validity of Jarzynski's equality in a regime with energy dissipation, compensated for by a fast unitary drive.This provides new insights for analyzing errors in many-body quantum simulators.
Estimation of work at the quantum scale remains a central challenge in quantum thermodynamics. Canonical approaches have a fundamental drawback: they assume classical control of the quantum system, as implicit in a time-dependent Hamiltonian. Yet the energetic cost of implementing this control is omitted and can exceed the system's energy scale by orders of magnitude, calling into question the operational significance of work values. We address this by autonomizing the controlled energy transfer, embedding the driven dynamics into an energy-conserving evolution on a larger quantum system. Work is then unambiguously identified with the energy transferred between the two systems, singling out a unique observable on the driven system: the work operator. We show that the quantum work operator evades a no-go theorem by deriving a quantum fluctuation theorem that recovers the Jarzynski equality in classical scenarios. We incorporate imperfect control and quantify corrections to work statistics. Extending the framework to open quantum systems, we obtain an operatorial first law in which work, heat, and internal-energy changes are represented by distinct operators on the reduced system. Together, these results settle the long-standing debate over whether work is a quantum observable: it is, once the controlling system is included in the description rather than treated as external.