Quantum coherence is one of the fundamental aspects distinguishing classical and quantum theories. Coherence between different energy eigenstates is particularly important, as it serves as a valuable resource under the law of energy conservation. A fundamental question in this setting is how well one can prepare good coherent states from low coherent states and whether a given coherent state is convertible to another one. Here, we show that any low coherent state is convertible to any high coherent state arbitrarily well in two operational settings: asymptotic and catalytic transformations. For a variant of asymptotic coherence manipulation where one aims to prepare desired states in local subsystems, the rate of transformation becomes unbounded regardless of how weak the initial coherence is. In a non-asymptotic transformation with a catalyst, a helper state that locally remains in the original form after the transformation, we show that an arbitrary state can be obtained from any low coherent state. Applying this to the standard asymptotic setting, we find that a catalyst can increase the coherence distillation rate significantly-from zero to infinite rate. We also prove that such anomalous transformation requires small but nonzero coherence in relevant modes, establishing the condition under which a sharp transition of the operational capability occurs. Our results provide a general characterization of the coherence transformability in these operational settings and showcase their peculiar properties compared to other common resource theories such as entanglement and quantum thermodynamics.
Quantum coherence is one of the fundamental aspects distinguishing classical and quantum theories. Coherence between different energy eigenstates is particularly important, as it serves as a valuable resource under the law of energy conservation. A fundamental question in this setting is how well one can prepare good coherent states from low coherent states and whether a given coherent state is convertible to another one. Here, we show that any low coherent state is convertible to any high coherent state arbitrarily well in two operational settings: asymptotic and catalytic transformations. For a variant of asymptotic coherence manipulation where one aims to prepare desired states in local subsystems, the rate of transformation becomes unbounded regardless of how weak the initial coherence is. In a non-asymptotic transformation with a catalyst, a helper state that locally remains in the original form after the transformation, we show that an arbitrary state can be obtained from any low coherent state. Applying this to the standard asymptotic setting, we find that a catalyst can increase the coherence distillation rate significantly-from zero to infinite rate. We also prove that such anomalous transformation requires small but nonzero coherence in relevant modes, establishing the condition under which a sharp transition of the operational capability occurs. Our results provide a general characterization of the coherence transformability in these operational settings and showcase their peculiar properties compared to other common resource theories such as entanglement and quantum thermodynamics.
Quantum resource manipulation may include an ancillary state called a catalyst, which aids the transformation while restoring its original form at the end, and characterizing the enhancement enabled by catalysts is essential to reveal the ultimate manipulability of the precious resource quantity of interest. Here, we show that allowing correlation among multiple catalysts can offer arbitrary power in the manipulation of quantum coherence. We prove that any state transformation can be accomplished with an arbitrarily small error by covariant operations with catalysts that may create a correlation within them while keeping their marginal states intact. This presents a new type of embezzlement-like phenomenon, in which the resource embezzlement is attributed to the correlation generated among multiple catalysts. We extend our analysis to general resource theories and provide conditions for feasible transformations assisted by catalysts that involve correlation, putting a severe restriction on other quantum resources for showing this anomalous enhancement, as well as characterizing achievable transformations in relation to their asymptotic state transformations. Our results provide not only a general overview of the power of correlation in catalysts but also a step toward the complete characterization of the resource transformability in quantum thermodynamics with correlated catalysts.
Entanglement is a fundamental resource in quantum information processing, yet understanding its manipulation and transformation remains a challenge. Many tasks rely on highly entangled pure states, but obtaining such states is often challenging due to the presence of noise. Typically, entanglement manipulation procedures involving asymptotically many copies of a state are considered to overcome this problem. These procedures allow for distilling highly entangled pure states from noisy states, which enables a wide range of applications, such as quantum teleportation and quantum cryptography. When it comes to manipulating entangled quantum systems on a single copy level, using entangled states as catalysts can significantly broaden the range of achievable transformations. Similar to the concept of catalysis in chemistry, the entangled catalyst is returned unchanged at the end of the state manipulation procedure. Our results demonstrate that despite the apparent conceptual differences between the asymptotic and catalytic settings, they are actually strongly connected and fully equivalent for all distillable states. Our methods rely on the analysis of many-copy entanglement manipulation procedures which may establish correlations between different copies. As an important consequence, we demonstrate that using an entangled catalyst cannot enhance the asymptotic singlet distillation rate of a distillable quantum state. Our findings provide a comprehensive understanding of the capabilities and limitations of both catalytic and asymptotic state transformations of entangled states, and highlight the importance of correlations in these processes.
Quantum catalysis, the ability to enable previously impossible transformations by using auxiliary systems without degrading them, has emerged as a powerful tool in various resource theories. Although catalytically enabled state transformations have been formally characterized by the monotonic behavior of entropic quantifiers (e.g., the von Neumann entropy or nonequilibrium free energy), such characterizations often rely on unphysical assumptions, namely, the ability of using catalysts of infinitely large dimension. This approach offers very limited insights into the practical significance of using catalysis for quantum information processing. Here, we address this problem across a broad class of quantum resource theories. Leveraging quantum information tools beyond the asymptotic regime, we establish sufficient conditions for the existence of catalytic transformations with finite-size catalysts. We further unveil connections between finite-size catalysis and multicopy transformations. Notably, we discover a phenomenon of catalytic resonance: by carefully tailoring the catalysts's state, one can drastically reduce the required dimension of the catalyst, thus enabling efficient catalytic transformations with minimal resources. Finally, we illustrate our findings with examples from the resource theories of entanglement and thermodynamics, as well in the context of catalytic unitary transformations.
In 2016, Winter and Yang [A. Winter and D. Yang, Phys. Rev. Lett. 116, 120404 (2016)] provided an operational meaning to relative entropy of coherence and coherence of formation by introducing coherence distillation and dilation protocols in an asymptotic setup. Here we have provided relative entropy of coherence [via incoherent operations (IO)] and coherence of formation (via IO) and quantum incoherent relative entropy [via local quantum incoherent operations with classical communications (LQICC)] as a measure using the concept of a catalyst. We have proved an existential correspondence between asymptotic and catalytic state transformation using IO, local incoherent operations with classical communications, and LQICC. We have also discussed two very important protocols, assisted distillation and quantum incoherent state merging using a catalyst. Monotone properties of relative entropy of coherence, coherence of formation, and quantum incoherent relative entropy under the catalytic transformation are also discussed here.
Understanding the fundamental limits of state convertibility is crucial for establishing the boundaries of quantum information processing and thermodynamic efficiency. While auxiliary systems, catalysts, can facilitate otherwise impossible transformations, standard catalysis rigidly requires the auxiliary system to return to its exact initial state. In this work, we investigate the power of flexible catalysis, where the catalyst evolves through a cycle of states, restoring its initial configuration only after a finite number of steps. Focusing on the regime of fixed, finite dimensions, we analyze the capabilities of flexible catalysis within the resource theories of entanglement and quantum thermodynamics. In the context of entanglement, we derive conditions limiting flexible catalysts, yet show that flexible catalysis can be strictly more powerful than same-dimensional standard catalysis: it enables deterministic transformations achievable by no standard catalyst of the same dimension, and it strictly increases the success probability of stochastic local operations and classical communication. A similar deterministic advantage arises in quantum thermodynamics, where flexible catalysis enables state transformations that are impossible with any standard catalyst of fixed dimension and Hamiltonian but become achievable via flexible catalysis.
The resource theory with covariant Gibbs-preserving operations, also called enhanced thermal operations, is investigated. We prove that with the help of a correlated catalyst, the state convertibility for any coherent state is fully characterized by the free energy defined with the quantum relative entropy. We can extend this result to general resource theories in the form that imposing the covariant condition to a general resource theory does not change the state convertibility, as long as the initial state is coherent and distillable and this resource theory admits the phase estimation and the phase shift. This means that adding a constraint from the law of energy conservation is irrelevant in the correlated-catalytic framework.