Employing a recently developed approach to dynamically emergent quantum thermodynamics, we revisit the thermodynamic behavior of the quantum Otto cycle with a focus on memory effects and strong system-bath couplings. Our investigation is based on an exact treatment of non-Markovianity by means of an exact quantum master equation, modeling the dynamics through the Fano-Anderson model featuring a peaked environmental spectral density. By comparing the results to the standard Markovian case, we find that non-Markovian baths can induce work transfer to the system, and identify specific parameter regions which lead to enhanced work output and efficiency of the cycle. In particular, we demonstrate that these improvements arise when the cycle operates in a frequency interval which contains the peak of the spectral density. This can be understood from an analysis of the renormalized frequencies emerging through the system-bath couplings. Published by the American Physical Society 2024
Employing a recently developed approach to dynamically emergent quantum thermodynamics, we revisit the thermodynamic behavior of the quantum Otto cycle with a focus on memory effects and strong system-bath couplings. Our investigation is based on an exact treatment of non-Markovianity by means of an exact quantum master equation, modeling the dynamics through the Fano-Anderson model featuring a peaked environmental spectral density. By comparing the results to the standard Markovian case, we find that non-Markovian baths can induce work transfer to the system, and identify specific parameter regions which lead to enhanced work output and efficiency of the cycle. In particular, we demonstrate that these improvements arise when the cycle operates in a frequency interval which contains the peak of the spectral density. This can be understood from an analysis of the renormalized frequencies emerging through the system-bath couplings. Published by the American Physical Society 2024
We study finite-time quantum Otto cycles whose working medium is a harmonic oscillator undergoing a quantum Brownian motion described by the Caldeira-Leggett model when the oscillator is in contact with heat baths in isochoric processes. The time evolution of the Otto cycle is studied by analytically solving the exact Heisenberg-Langevin equations for the system variables and the interaction energy between the system and the bath. This enables us to investigate non-Markovian strong-coupling effects on the quantum Otto cycle. We obtain cyclic steady states and study the thermodynamic properties of the Otto cycle for various values of the parameters describing the heat baths and the coupling between the system and the bath. We compare our results with those obtained in the Markovian limit, where the time evolution is described by the Lindblad equation. We find that the change in the interaction energy during the isochoric process contributes to both work and heat and plays a crucial role in determining the thermodynamic behavior of the cycle. This is in contrast to the behavior of the state observables of the working medium, which show relatively small change compared to the Markovian counterparts. We find that non-Markovian effects only become significant when we consider thermodynamic fluxes such as work and heat with the system-bath interaction fully taken into account. We also compare our results with the power-efficiency trade-off relation recently proposed for the Markovian quantum Otto engine.
Quantum thermodynamics explores novel thermodynamic phenomena that emerge when interactions between macroscopic systems and microscopic quantum ones go into action. Among various issues, quantum heat engines, in particular, have attracted much attention as a critical step in theoretical formulation of quantum thermodynamics and investigation of efficient use of heat by means of quantum resources. In the present paper, we focus on heat absorption and emission processes as well as work extraction processes of a quantum Otto cycle. We describe the former as non-Markovian dynamics, and thereby find that the interaction energy between a macroscopic heat bath and a microscopic qubit is not negligible. Specifically, we reveal that the interaction energy is divided into the system and the bath in a region of the short interaction time and remains negative in the region of the long interaction time. In addition, a counterintuitive energy flow from the system and the interaction energy to the hot bath occurs in another region of the short interaction time. We quantify these effects by defining an index of non-Markovianity in terms of the interaction energy. With this behavior of the interaction energy, we show that a non-Markovian quantum Otto cycle can switch functions such as an engine as well as a heater or a heat pump by controlling the interaction time with the heat bath. In particular, the qubit itself loses its energy if we shorten the interaction time, and in this sense, the qubit is cooled through the cycle. This property has a possibility of being utilized for cooling the qubits in quantum computing. We also describe the work extraction from the microscopic system to a macroscopic system like us humans as an indirect measurement process by introducing a work storage as a new reservoir.
We study the thermodynamic performance of a periodic quantum Otto cycle operating on the single-impurity Anderson model. Using a decomposition of the time-evolution generator based on the principle of minimal dissipation, combined with the numerically exact hierarchical equations of motion (HEOM) method, we analyze the operating regimes of the quantum thermal machine and investigate effects of Coulomb interactions, strong system-reservoir coupling, and energy level alignments. Our results show that Coulomb interaction can change the operating regimes and may lead to an enhancement of the efficiency.
The extension of quantum thermodynamics to situations that go beyond standard thermodynamic settings comprises an important and interesting aspect of its development. One such situation is the analysis of the thermodynamic consequences of structured environments that induce a non-Markovian dynamics. We study a quantum Otto refrigerator where the standard Markovian cold reservoir is replaced by a specific engineered cold reservoir which may induce a Markovian or non-Markovian dynamics on the quantum refrigerant system. The two dynamical regimes can be interchanged by varying the coupling between the refrigerant and the reservoir. An increase of non-Markovian effects will be related to an increase of the coupling strength, which in turn will make the energy stored in the interaction Hamiltonian, the interaction energy, increasingly relevant. We show how the figures of merit, the coefficient of performance, and the cooling power change for non-negligible interaction energies, discussing how neglecting this effect would lead to an overestimation of the refrigerator performance. Finally, we also consider a numerical simulation of a spin quantum refrigerator with experimentally feasible parameters to better illustrate the non-Markovian effects induced by the engineered cold reservoir. We argue that a moderate non-Markovian dynamics performs better than either a Markovian or a strong non-Markovian regime of operation.
The focus is on understanding the quantum thermodynamics of strongly coupled non-Markovian quantum systems. To this end, a non-trivial, non-Markovian model of a central spin surrounded by a spin bath is taken up, and its exact evolution is derived for arbitrary system-bath couplings. The fundamental quantum thermodynamic quantities, such as system and bath internal energies, work, heat, entropy production, and ergotropy, are calculated using the dynamics and the original system (bath) Hamiltonian. An explicit expression for the work, a mismatch between the system and bath internal energies, is derived. The thermodynamic entropy of the system at thermal equilibrium is studied using the Hamiltonian of mean force in the strong coupling regime. The role of a canonical Hamiltonian in calculating the above thermodynamic quantities, a recently developed technique, is also investigated. Furthermore, an interesting observation relevant to the spin bath acting as a charger is made in a scenario where the central spin is envisaged as a quantum battery.
In this paper we examine some foundational issues of a class of quantum engines where the system consists of a single quantum parametric oscillator, operating in an Otto cycle consisting of four stages of two alternating phases: the isentropic phase is detached from any bath (thus a closed system) where the natural frequency of the oscillator is changed from one value to another, and the isothermal phase where the system (now rendered open) is put in contact with one or two squeezed baths of different temperatures, whose nonequilibrium dynamics follows the Hu-Paz-Zhang (HPZ) master equation for quantum Brownian motion. The HPZ equation is an exact non-Markovian equation which preserves the positivity of the density operator and is valid for (1) all temperatures, (2) arbitrary spectral density of the bath, and (3) arbitrary coupling strength between the system and the bath. Taking advantage of these properties we examine some key foundational issues of theories of quantum open and squeezed systems for these two phases of the quantum Otto engines. This includes (1) the non-Markovian regimes for non-Ohmic, low-temperature baths, (2) what to expect in nonadiabatic frequency modulations, (3) strong system-bath coupling, as well as (4) the proper junction conditions between these two phases. Our aim here is not to present ways for attaining higher efficiency but to build a more solid theoretical foundation for quantum engines of continuous variables covering a broader range of parameter spaces that we hope are of use for exploring such possibilities.