Unitary designs have become a vital tool for investigating pseudorandomness, since they approximate the statistics of the uniform Haar ensemble. Despite their central role in quantum information, their relations to quantum chaotic evolution and, in particular, to the eigenstate thermalization hypothesis (ETH) are still largely debated issues. This work provides a bridge between the latter and k designs through free probability theory. First, by introducing the more general notion of k -freeness, we show that it can be used as an alternative probe to designs. In turn, free probability theory comes with several tools, useful, for instance, for the calculation of mixed moments or the so-called k -fold quantum channels. Our second result is the connection to quantum dynamics. Quantum ergodicity and, correspondingly, ETH apply to a restricted class of physical observables, as already discussed in the literature. In this spirit, we show that unitary evolution with generic Hamiltonians always leads to freeness at sufficiently long times but only when the operators considered are restricted within the ETH class. Our results provide a direct link between unitary designs, quantum chaos, and the eigenstate thermalization hypothesis and shed new light on the universality of late-time quantum dynamics.
Unitary randomness underpins both fundamental tasks in quantum information and the modern theory of quantum chaos. On one side, a central concept is that of approximate unitary designs: circuits that look random according to small moments and for forward-in-time protocols. In a distinct setting, out-of-time-ordered correlators (OTOCs), intensely studied as a measure of information scrambling, have recently been shown to probe freeness between Heisenberg operators, the noncommutative generalization of statistical independence. Bridging these two concepts, we study the emergence of freeness in a random matrix product unitary ensemble. We prove that, with only polynomial bond dimension, these unitaries reproduce Haar values of higher-order OTOCs for local, finite-trace observables, while traceless observables instead require exponential resources. Indeed, local observables are precisely those predicted to thermalize in chaotic many-body systems according to the eigenstate thermalization hypothesis. Moreover, adding to previous literature, we show how random matrix product unitaries constitute approximate designs: we exactly compute the frame potential of the ensemble, showing convergence to the Haar value with polynomial deviations and so indicating that global observables are freely independent on-average. Our results highlight the need to refine previous notions of unitary design in the context of operator dynamics, guiding us towards protocols for quantum advantage and shedding light on the emergent complexity of chaotic many-body systems.
A bstract The eigenstate thermalization hypothesis (ETH) is the leading conjecture for the emergence of statistical mechanics in generic isolated quantum systems and is formulated in terms of the matrix elements of operators. An analog known as the ergodic bipartition (EB) describes entanglement and locality and is formulated in terms of the components of eigenstates. In this paper, we significantly generalize the EB and unify it with the ETH, extending the EB to study higher correlations and systems out of equilibrium. Our main result is a diagrammatic formalism that computes arbitrary correlations between eigenstates and operators based on a recently uncovered connection between the ETH and free probability theory. We refer to the connected components of our diagrams as generalized free cumulants. We apply our formalism in several ways. First, we focus on chaotic eigenstates and establish the so-called subsystem ETH and the Page curve as consequences of our construction. We also improve known calculations for thermal reduced density matrices and comment on an inherently free probabilistic aspect of the replica approach to entanglement entropy previously noticed in a calculation for the Page curve of an evaporating black hole. Next, we turn to chaotic quantum dynamics and demonstrate the ETH as a sufficient mechanism for thermalization, in general. In particular, we show that reduced density matrices relax to their equilibrium form and that systems obey the Page curve at late times. We also demonstrate that the different phases of entanglement growth are encoded in higher correlations of the EB. Lastly, we examine the chaotic structure of eigenstates and operators together and reveal previously overlooked correlations between them. Crucially, these correlations encode butterfly velocities, a well-known dynamical property of interacting quantum systems.
The eigenstate thermalization hypothesis (ETH) is the leading interpretation in our current understanding of quantum thermalization. Recent results uncovered strong connections between quantum correlations in thermalizing systems and the structure of free probability theory, leading to the notion of full ETH. However, most studies have been performed for ergodic systems and it is still unclear whether or how full ETH manifests in ergodicity-breaking models. We fill this gap by studying standard probes of full ETH in ergodicity-breaking quantum circuits, presenting numerical and analytical results for interacting integrable systems. These probes can display distinct behavior and undergo a different scaling than the ones observed in ergodic systems. For the analytical results we consider an interacting integrable dual-unitary model and present the exact eigenstates, allowing us to analytically express common probes for full ETH. We discuss the underlying mechanisms responsible for these differences and show how the presence of solitons dictates the behavior of ETH-related quantities in the dual-unitary model. We show numerical evidence that this behavior is sufficiently generic away from dual-unitarity when restricted to the appropriate symmetry sectors.
Complexity of dynamics is at the core of quantum many-body chaos and exhibits a hierarchical feature: higher-order complexity implies more chaotic dynamics. Conventional ergodicity in thermalization processes is a manifestation of the lowest-order complexity, which is represented by the eigenstate thermalization hypothesis (ETH) stating that individual energy eigenstates are thermal. Here, we propose a higher-order generalization of the ETH, named the
k-ETH ($k=1,2,\ensuremath{\cdots}$), to quantify higher-order complexity of quantum many-body dynamics at the level of individual energy eigenstates, where the lowest-order ETH (1-ETH) is the conventional ETH. The explicit condition of the
k-ETH is obtained by comparing Hamiltonian dynamics with the Haar random unitary of the
k-fold channel. As a nontrivial contribution of the higher-order ETH, we show that the
k-ETH with $k\ensuremath{\ge}2$ implies a universal behavior of the
kth R\'enyi entanglement entropy of individual energy eigenstates. In particular, the Page correction of the entanglement entropy originates from the higher-order ETH, while, as is well known, the volume law can be accounted for by the 1-ETH. We numerically verify that the 2-ETH approximately holds for a nonintegrable system, but does not hold in the integrable case. To further investigate the information-theoretic feature behind the
k-ETH, we introduce a concept named a partial unitary
k-design (PU
k-design), which is an approximation of the Haar random unitary up to the
kth moment, where ``partial'' means that only a limited number of observables are accessible. The
k-ETH is a special case of a PU
k-design for the ensemble of Hamiltonian dynamics with random-time sampling. In addition, we discuss the relationship between the higher-order ETH and information scrambling quantified by out-of-time-ordered correlators. Our framework provides a unified view on thermalization, entanglement entropy, and unitary
k-designs, leading to deeper characterization of higher-order quantum complexity.
Despite its long history, a canonical formulation of quantum ergodicity that applies to general classes of quantum dynamics, including driven systems, has not been fully established. Here we introduce and study a notion of quantum ergodicity for closed systems with time-dependent Hamiltonians, defined as statistical randomness exhibited in their longtime dynamics. Concretely, we consider the temporal ensemble of quantum states (time-evolution operators) generated by the evolution, and investigate the conditions necessary for them to be statistically indistinguishable from uniformly random states (operators) in the Hilbert space (space of unitaries). We find that the number of driving frequencies underlying the Hamiltonian needs to be sufficiently large for this to occur. Conversely, we show that statistical —indistinguishability up to some large but finite moment—can already be achieved by a quantum system driven with a single frequency, i.e., a Floquet system, as long as the driving period is sufficiently long. Our work relates the complexity of a time-dependent Hamiltonian and that of the resulting quantum dynamics, and offers a fresh perspective to the established topics of quantum ergodicity and chaos from the lens of quantum information. Published by the American Physical Society 2024
Quantum thermalization is well understood via the eigenstate thermalization hypothesis (ETH). The general form of ETH, describing all the relevant correlations of matrix elements, may be derived on the basis of a "typicality" argument of invariance with respect to local rotations involving nearby energy levels. In this Letter, we uncover the close relation between this perspective on ETH and free probability theory, as applied to a thermal ensemble or an energy shell. This mathematical framework allows one to reduce in a straightforward way higher-order correlation functions to a decomposition given by minimal blocks, identified as free cumulants, for which we give an explicit formula. This perspective naturally incorporates the consistency property that local functions of ETH operators also satisfy ETH. The present results uncover a direct connection between the eigenstate thermalization hypothesis and the structure of free probability, widening considerably the latter's scope and highlighting its relevance to quantum thermalization.