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arXiv:2305.11977

Can Schroedingerist Wavefunction Physics Explain Brownian Motion?

W. David Wick

Published May 19, 2023• 0 citations
arXivHTMLPDF

Abstract

Einstein's 1905 analysis of the Brownian Motion of a pollen grain in a water droplet as due to statistical variations in the collisions of water molecules with the grain, followed up by Perrin's experiments, provided one of the most convincing demonstrations of the reality of atoms. But in 1926 Schroedinger replaced classical particles by wavefunctions, which cannot undergo collisions. Can a Schroedingerist wavefunction physics account for Perrin's observations? As systems confined to a finite box can only generate quasiperiodic signals, this seems impossible, but I argue here that the issue is more subtle. I then introduce several models of the droplet-plus-grain; unfortunately, no explicit solutions are available (related is the remarkable fact that the harmonics of a general right triangle are still unknown). But from generic features of the models I conclude that: (a) wavefunction models may generate trajectories resembling those of a stochastic process; (b) diffusive behavior may appear for a restricted time interval; and (c) additional ``Wave Function Energy", by restricting ``cat" formation, can render the observations more ``classical". But completing the Einstein program of linking diffusion to viscosity and temperature in wavefunction models is still challenging.

DOI
10.48550/arxiv.2305.11977

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Einstein's 1905 analysis of the Brownian Motion of a pollen grain in a water droplet as due to statistical variations in the collisions of water molecules with the grain, followed up by Perrin's experiments, provided one of the most convincing demonstrations of the reality of atoms. But in 1926 Schroedinger replaced classical particles by wavefunctions, which cannot undergo collisions. Can a Schroedingerist wavefunction physics account for Perrin's observations? As systems confined to a finite box can only generate quasiperiodic signals, this seems impossible, but I argue here that the issue is more subtle. I then introduce several models of the droplet-plus-grain; unfortunately, no explicit solutions are available (related is the remarkable fact that the harmonics of a general right triangle are still unknown). But from generic features of the models I conclude that: (a) wavefunction models may generate trajectories resembling those of a stochastic process; (b) diffusive behavior may appear for a restricted time interval; and (c) additional Wave Function Energy", by restricting cat" formation, can render the observations more ``classical". But completing the Einstein program of linking diffusion to viscosity and temperature in wavefunction models is still challenging.
In the first paper of this series, I investigated whether a wavefunction model of a heavy particle and a collection of light particles might generate "Brownian-Motion-Like" trajectories of the heavy particle. I concluded that it was possible, but left unsettled the second claim in Einstein's classical program: diffusive motion, proportional to the square-root of time, as opposed to ballistic motion, proportional to the time. In this paper, I derive a criterion for diffusive motion, as well as an expression for the diffusion coefficient. Unfortunately, as in paper I, no exact solutions are available for the models, making checking the criterion difficult. But a virtue of the method employed here is that, given adequate information about model eigenvalues and eigenfunctions, diffusion can be definitively ruled in or out.
In two prior papers of this series, it was proposed that a wavefunction model of a heavy particle and a collection of light particles might generate ``Brownian-Motion-Like" trajectories as well as diffusive motion (displacement proportional to the square-root of time) of the heavy particle, but did not exhibit a concrete instance. Here we introduce a one-space-dimensional model which, granted a finite perturbation series, fulfills the criteria for BML trajectories and diffusion. We note that Planck's constant and the molecular mass of light particles make an appearance in the diffusion coefficient, which further differentiates the present theory from the work of Poincar{é} and Einstein in the previous century.
This paper proposes an interpretation of quantum mechanics, relying on the time-symmetric stochastic dynamics of quantum particles and on non-classical probability theory. Our main purpose is to demonstrate that the wave function and its complex conjugate can be interpreted as complex probability distributions in two complex diffusion equations related to non-real forward and backward in time stochastic motions respectively. We say non-real because Schroedinger forward and backward diffusions describe both reversible (real trajectories) and irreversible trajectories (non-real trajectories). The reversible trajectories are the only real trajectories and are given by the intersection of those forward and backward processes. It turns out that if we translate this intersection using set-theoretic language, we are led to a reversible diffusion described by Born rule probabilities. This proposal is useful also for explaining more about the role of complex numbers in quantum mechanics that produces this so-called "wave-like" nature of quantum reality. Our perspective also challenges the notion of physical superposition and aims at a derivation of superposition principle not based on the linearity of Schroedinger's equation but relying on pure probability theory. Moreover, it is suggested that, embracing the idea of stochastic processes in quantum theory, explains the reasons for the appearance of classical behavior in large objects, in contrast to the quantum behavior of small ones. In other words, we claim that a combination of a probabilistic and no-ontic view (neither epistemic though) of the wave function with a stochastic hidden-variables approach, may provide some insight into the quantum physical reality and potentially establish the groundwork for a novel interpretation of quantum mechanics.
The connection between the Schrödinger equation and Einstein's diffusion theory based on the Brownian motion of independent particles is well known. However, in contrast to diffusion theory, quantum mechanics theory has suffered controversial interpretations due to the counterintuitive concept of wavefunction. Here, while we confirm there is no difference in the mathematical form of these two equations, we derive the imaginary version of displacement. Using the diffusion theory of particles in a medium, as simple as it is, we describe that quantum mechanics is just an elegant and subtle equation to describe the probability of all the trajectories that a particle can take to propagate in time by a predictive wavefunction. Therefore, information on the position of particles through time in quantum theory is embedded in the wavefunction, which predicts the evolution of an ensemble of individual Brownian particles.
In the frames of classical mechanics the generalized Langevin equation is derived for an arbitrary mechanical subsystem coupled to the harmonic bath of a solid. A time-acting temperature operator is introduced for the quantum Klein-Kramers and Smoluchowski equations, accounting for the effect of the quantum thermal bath oscillators. The model of Brownian emitters is theoretically studied and the relevant evolutionary equations for the probability density are derived. The Schrodinger equation is explained via collisions of the target point particles with the quantum force carriers, transmitting the fundamental interactions between the point particles. Thus, electrons and other point particles are no waves and the wavy chapter of quantum mechanics originated for the force carriers. A stochastic Lorentz-Langevin equation is proposed to describe the underlaying Brownian-like motion of the point particles in quantum mechanics. Considering the Brownian dynamics in the frames of the Bohmian mechanics, the density functional Bohm-Langevin equation is proposed, and the relevant Smoluchowski-Bohm equation is derived. A nonlinear master equation is proposed by proper quantization of the classical Klein-Kramers equation. Its equilibrium solution in the exact canonical Gibbs density operator, while the well-known Caldeira-Leggett equation is simply a linearization at high temperature. In the case of a free quantum Brownian particles, a new law for the spreading of the wave packet it discovered, which represents the quantum generalization of the classical Einstein law of Brownian motion. A new projector operator is proposed for the collapse of the wave function of a quantum particle moving in a classical environment. Its application results in dissipative Schrodinger equations, as well as in a new form of dissipative Liouville equation in classical mechanics.