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arXiv:2305.06008 · Quantum Science and Technology

A thermodynamic approach to optimization in complex quantum systems

Alberto Imparato, Nicholas Chancellor, Gabriele De Chiara

Published Feb 6, 2024• 4 citations
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Abstract

Abstract We consider the problem of finding the energy minimum of a complex quantum Hamiltonian by employing a non-Markovian bath prepared in a low energy state. The energy minimization problem is thus turned into a thermodynamic cooling protocol in which we repeatedly put the system of interest in contact with a colder auxiliary system. By tuning the internal parameters of the bath, we show that the optimal cooling is obtained in a regime where the bath exhibits a quantum phase transition in the thermodynamic limit. This result highlights the importance of collective effects in thermodynamic devices. We furthermore introduce a two-step protocol that combines the interaction with the bath with a measure of its energy. While this protocol does not destroy coherence in the system of interest, we show that it can further enhance the cooling effect.

DOI
10.1088/2058-9565/ad26b3

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Abstract We consider the problem of finding the energy minimum of a complex quantum Hamiltonian by employing a non-Markovian bath prepared in a low energy state. The energy minimization problem is thus turned into a thermodynamic cooling protocol in which we repeatedly put the system of interest in contact with a colder auxiliary system. By tuning the internal parameters of the bath, we show that the optimal cooling is obtained in a regime where the bath exhibits a quantum phase transition in the thermodynamic limit. This result highlights the importance of collective effects in thermodynamic devices. We furthermore introduce a two-step protocol that combines the interaction with the bath with a measure of its energy. While this protocol does not destroy coherence in the system of interest, we show that it can further enhance the cooling effect.
Heat-Bath Algorithmic Cooling is a technique for producing pure quantum systems by utilizing a surrounding heat-bath. Here we connect the study of these cooling techniques to the resource theory of thermal operations, enabling us to derive provably optimal cooling protocols under a variety of experimental restrictions on the available control. For qubit systems, we find that a surprisingly simple, optimal protocol consisting of repeated application of a Pauli XXX unitary and a thermal operation can achieve purity converging exponentially quickly to one. What is more, this thermal operation can be well approximated using a Jaynes Cummings interaction between the system and a single thermal bosonic mode and we consider experimental implementations of this. In addition, we investigate the role of quantum coherence and non-Markovianity in cooling protocols and extend our results to higher dimensional systems. Finally, by considering the role of correlations with auxiliary systems in cooling, we show that purity arbitrary close to one can be achieved in a fixed number of operations. Our results serve to find practical applications for the resource theoretic approach to quantum thermodynamics and suggest relevant experimental implementations.
Heat-Bath Algorithmic Cooling is a set of techniques for producing highly pure quantum systems by utilizing a surrounding heat-bath and unitary interactions. These techniques originally used the thermal environment only to fully thermalize ancillas at the environment temperature. Here we extend HBAC protocols by optimizing over the thermalization strategy. We find, for any d -dimensional system in an arbitrary initial state, provably optimal cooling protocols with surprisingly simple structure and exponential convergence to the ground state. Compared to the standard ones, these schemes can use fewer or no ancillas and exploit memory effects to enhance cooling. We verify that the optimal protocols are robusts to various deviations from the ideal scenario. For a single target qubit, the optimal protocol can be well approximated with a Jaynes-Cummings interaction between the system and a single thermal bosonic mode for a wide range of environmental temperatures. This admits an experimental implementation close to the setup of a micromaser, with a performance competitive with leading proposals in the literature. The proposed protocol provides an experimental setup that illustrates how non-Markovianity can be harnessed to improve cooling. On the technical side we 1. introduce a new class of states called maximally active states and discuss their thermodynamic significance in terms of optimal unitary control, 2. introduce a new set of thermodynamic processes, called β-permutations , whose access is sufficient to simulate a generic thermalization process, 3. show how to use abstract toolbox developed within the resource theory approach to thermodynamics to perform challenging optimizations, while combining it with open quantum system dynamics tools to approximate optimal solutions within physically realistic setups.
Landauer's limit on heat dissipation during information erasure is critical as devices shrink, requiring optimal pure-state preparation to minimize errors. However, Nernst's third law states this demands infinite resources in energy, time, or control complexity. We address the challenge of cooling quantum systems with finite resources. Using Markovian collision models, we explore resource trade-offs and present efficient cooling protocols (that are optimal for qubits) for coherent and incoherent control. Leveraging thermodynamic length, we derive bounds on heat dissipation for swap-based strategies and discuss the limitations of preparing pure states efficiently.
Practical implementations of quantum technologies require preparation of states with a high degree of purity---or, in thermodynamic terms, very low temperatures. Given finite resources, the third law of thermodynamics prohibits perfect cooling; nonetheless, attainable upper bounds for the asymptotic ground-state population of a system repeatedly interacting with quantum thermal machines have been derived. These bounds apply within a memoryless (Markovian) setting, in which each refrigeration step proceeds independently of those previous. Here, we expand this framework to study the effects of memory on quantum cooling. By introducing a memory mechanism through a generalized collision model that permits a Markovian embedding, we derive achievable bounds that provide an exponential advantage over the memoryless case. For qubits, our bound coincides with that of heat-bath algorithmic cooling, which our framework generalizes to arbitrary dimensions. We lastly describe the adaptive stepwise optimal protocol that outperforms all standard procedures.
Cooling an arbitrary mixed state to a pure ground state requires transferring its entropy to an environment. Can a single coherent bath contact accomplish this without repeated bath resets? We develop a new cooling mechanism that transfers the input information into bath degrees of freedom that subsequently decouple, while the system and the remaining bath follow a ground-state path. The bath is discarded only at the end, and the system Hamiltonian remains on and unmodified throughout. We rigorously realize this mechanism for a class of weakly interacting, gapped fermionic systems with local interactions. Starting from any mixed state, our protocol prepares the interacting ground state in total physical time polylogarithmic in the system size and inverse global trace-norm error. It uses two initially empty bath modes per system mode and a single pulse shared across all onsite system--bath couplings. The same pulse prepares each admissible system's own ground state without knowledge of its microscopic parameters. The guarantees follow directly from a non-Markovian system--bath dynamics without an effective Lindbladian description.
It is known that the origin of the deviations from standard thermodynamics proceed from the strong coupling to the bath. Here, it is shown that these deviations are related to the power spectrum of the bath. Specifically, it is shown that the system thermal-equilibrium-state cannot be characterized by the canonical Boltzmann's distribution in quantum mechanics. This is because the uncertainty principle imposed a lower bound of the dispersion of the total energy of the system that is dominated by the spectral density of the bath. However, in the classical case, for a wide class of systems that interact via central forces with pairwise-self-interacting environment, the system thermal equilibrium state is exactly characterized by the canonical Boltzmann distribution. As a consequence of this analysis and taking into account all energy scales in the system and reservoir interaction, an effective coupling to the environment is introduced. Sample computations in different regimes predicted by this effective coupling are shown. Specifically, in the strong coupling effective regime, the system exhibits deviations from standard thermodynamics and in the weak coupling effective regime, quantum features such as stationary entanglement are possible at high temperatures. Moreover, it is known that the spectrum of thermal baths depends on the non-Markovian character. Hence, non-Markovian interactions have a important role in the thermal equilibrium state of physical systems. For example, in quantum optomechanics is looked up to cool the mechanical system through an auxiliary system which generally is a cavity. This cooling process takes into account the non-Markovian interaction and as it is shown here, it is more effective than if we use only the Markovian approximation in the equation of motion for the different modes.