We study the thermodynamic behavior of attractive binary Bose mixtures using exact path-integral Monte Carlo methods. Our focus is on the regime of interspecies interactions where the ground state is in a self-bound liquid phase, stabilized by beyond mean-field effects. We calculate the isothermal curves in the pressure vs density plane for different values of the attraction strength and establish the extent of the coexistence region between liquid and vapor using the Maxwell construction. Notably, within the coexistence region, Bose-Einstein condensation occurs in a discontinuous way as the density jumps from the normal gas to the superfluid liquid phase. Furthermore, we determine the critical point where the line of first-order transition ends and investigate the behavior of the density discontinuity in its vicinity. We also point out that the density discontinuity at the transition could be observed in experiments of mixtures in traps.
We study the thermodynamic behavior of attractive binary Bose mixtures using exact path-integral Monte Carlo methods. Our focus is on the regime of interspecies interactions where the ground state is in a self-bound liquid phase, stabilized by beyond mean-field effects. We calculate the isothermal curves in the pressure vs density plane for different values of the attraction strength and establish the extent of the coexistence region between liquid and vapor using the Maxwell construction. Notably, within the coexistence region, Bose-Einstein condensation occurs in a discontinuous way as the density jumps from the normal gas to the superfluid liquid phase. Furthermore, we determine the critical point where the line of first-order transition ends and investigate the behavior of the density discontinuity in its vicinity. We also point out that the density discontinuity at the transition could be observed in experiments of mixtures in traps.
Quantum liquid, in the form of a self-bound droplet, is stabilized by a subtle balance between the mean-field contribution and quantum fluctuations. While a liquid-gas transition is expected when such a balance is broken, it remains elusive whether liquid-gas critical points exist in the quantum regime. Here, we study the quantum criticality in a binary Bose mixture undergoing the liquid-gas transition. We show that, beyond a narrow stability window of the self-bound liquid, a liquid-gas coexistence persists, which eventually transits into a homogeneous mixture. Importantly, we identify two distinct critical points where the liquid-gas coexistence terminates. These critical points are characterized by rich critical behaviors in their vicinity, including divergent susceptibility, unique phonon-mode softening, and enhanced density correlations. The liquid-gas transition and the critical points can be readily explored in ultracold atoms confined to a box potential. Our work highlights the thermodynamic approach as a powerful tool in revealing the quantum liquid-gas criticality, and paves the way for further studies of critical phenomena in quantum liquids.
By using exact quantum Monte Carlo methods we calculate the ground-state properties of the liquid phase in one-dimensional Bose mixtures with contact interactions. We find that the liquid state can be formed if the ratio of coupling strengths between interspecies attractive and intraspecies repulsive interactions exceeds a critical value. As a function of this ratio we determine the density where the energy per particle has a minimum and the one where the compressibility diverges, thereby identifying the equilibrium density and the spinodal point in the phase diagram of the homogeneous liquid. Furthermore, in the stable liquid state, we calculate the chemical potential, the speed of sound, as well as structural and coherence properties, such as the pair correlation function, the static structure factor, and the one-body density matrix, thus providing a detailed description of the bulk region in self-bound droplets.
Stability and the dynamical behavior of binary Bose-Einstein condensed mixtures trapped on the surface of a rigid spherical shell are investigated at the mean-field level, exploring the miscibility with and without vortex charges and considering repulsive and attractive interactions. To compute the critical points for stability, we follow the Bogoliubov--de Gennes method for the analysis of perturbed solutions, with the constraint that initially the stationary states are in a complete miscible configuration. For the perturbed equal-density mixture of a homogeneous uniform gas and when hidden vorticity is verified, with the species having opposite azimuthal circulation, we consider a small perturbation analysis for each unstable mode, providing a complete diagram with the intra- and interspecies interaction role on the stability of the miscible system. Finally, beyond small-perturbation analysis, we explore the dynamics of some repulsive and attractive interspecies states by full numerical solutions of the time-dependent Gross--Pitaevskii equation.
The thermodynamic behavior of the one-dimensional Bose-gas–attractive-δ impurity system is studied in this paper. The system is shown to undergo the Bose–Einstein condensation and the cause of the phase transition is attributed to the bound state introduced by the impurity in the free-particle energy spectrum. The condensed phase is composed of particles captured by the impurity, forming a drop of particles well localized in space. This gives to the Bose–Einstein condensation in this system the appearance of the ordinary vapor–liquid phase transition. The expression for the pressure is obtained and is plotted as a function of the temperature and the system length. The shapes of the isothermal curves reinforce the interpretation of a vapor–liquid transition. The evaluation of the heat capacity at constant length shows the existence of a finite discontinuity at the transition temperature.
We investigate the formation of quantum droplets at finite temperature in attractive Bose mixtures subject to a strong transverse harmonic confinement. By means of exact path-integral Monte Carlo methods we determine the equilibrium density of the gas and the liquid as well as the pressure vs volume dependence along isothermal curves. Results for the equation of state and for the gas-liquid coexistence region in quasi-2D configurations are compared with calculations in strictly two dimensions, finding excellent agreement. Within the pure 2D model we explore the relevance of the quantum scale anomaly and we determine the critical interaction strength for the occurrence of the first-order gas to liquid transition. Furthermore, we find that the superfluid response develops suddenly, following the density jump from the gas to the liquid state.
The miscibility of quantum liquids is an interesting topic in many-body physics, which has been intensively investigated in 3He-4He superfluids and the mixtures of ultracold atoms. In the context of dual species Bose-Einstein condensates, the mean-field description has been well established, according to which, the miscibility condition is density independent and determined only by the ratio of inter- and intra-species interaction strength. Recently, Nadion and Petrov proposed that [ Phys. Rev. Lett. 126 115301 ], in the vicinity of the mixing-demixing threshold, quantum fluctuations play an important role to affect the equilibrium stability, and as a result, the partially miscible state emerges. This new phase of quantum matter opens up new perspectives to explore the beyond mean-field effect in ultracold atomic gases. In this work, according to the equation of state taking the Lee-Huang-Yang correction into consideration, we investigate the ground state phase diagram of repulsive binary Bose mixtures in the interacting regime suffering a weak mean-field instability. Under the thermodynamic balance conditions, the phase boundaries between the immiscible state, partially miscible state and the homogenous state are determined. For the equal-mass case, these phase transitions only take place on condition that intra-species interactions are in an asymmetric form. In terms of interaction parameters, we explicitly derive analytical expressions of the phase boundaries, which are appropriate to describe the transitions in sufficiently dilute atomic gases. At the quantum critical point, where the partially miscible state terminates, the susceptibility tensor of the density response exhibits a divergent behavior. For the unequal-mass case, the beyond-mean-field equation of state cannot be written in a compact form, thus the determination of the phase boundaries is more involved. By expanding the Lee-Huang-Yang energy expression to the terms linear in the concentration of the minority species, we analytically obtain the threshold density for the partially miscible transition. We also propose a discriminant function, from which the configuration of the partially miscible state can be identified for the given mass ratio and interaction strength. Applications of these theoretical results to experimental systems, such as sodium, potassium, and rubidium gases, are presented.