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arXiv:2303.14619 · Physical Review Research

Finite-time optimization of a quantum Szilard heat engine

Tan-Ji Zhou, Yuhan Ma, C. P. Sun

Published Oct 1, 2024• 7 citations
arXivHTMLPDF

Abstract

We propose a finite-time quantum Szilard engine (QSE) with a spin-1/2 quantum particle as the working substance (WS) to accelerate the operation of information engines. We introduce a Maxwell's demon (MD) to probe the spin state within a finite measurement time t M to capture the which-way information of the particle, quantified by the mutual information I ( t M ) between WS and MD. We establish that the efficiency η of QSE is bounded by η ≤ 1 − ( 1 − η C ) ln 2 / I ( t M ) , where I ( t M ) / ln 2 characterizes the ideality of quantum measurement, and approaches 1 for the Carnot efficiency reached under ideal measurement in quasistatic regime. We find that the output power of QSE scales as P O ∝ t M 3 in the short-time regime and as P O ∝ t M − 1 in the long-time regime. Additionally, considering the energy cost for erasing the MD's memory required by Landauer's principle, there exists a threshold time that guarantees QSE to output positive work. Published by the American Physical Society 2024

DOI
10.1103/physrevresearch.6.043001

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We propose a finite-time quantum Szilard engine (QSE) with a spin-1/2 quantum particle as the working substance (WS) to accelerate the operation of information engines. We introduce a Maxwell's demon (MD) to probe the spin state within a finite measurement time t M to capture the which-way information of the particle, quantified by the mutual information I ( t M ) between WS and MD. We establish that the efficiency η of QSE is bounded by η ≤ 1 − ( 1 − η C ) ln 2 / I ( t M ) , where I ( t M ) / ln 2 characterizes the ideality of quantum measurement, and approaches 1 for the Carnot efficiency reached under ideal measurement in quasistatic regime. We find that the output power of QSE scales as P O ∝ t M 3 in the short-time regime and as P O ∝ t M − 1 in the long-time regime. Additionally, considering the energy cost for erasing the MD's memory required by Landauer's principle, there exists a threshold time that guarantees QSE to output positive work. Published by the American Physical Society 2024
Quantum Szilard engine constitutes an adequate interplay of thermodynamics, information theory and quantum mechanics. Szilard engines are in general operated by a Maxwell's Demon where Landauer's principle resolves the apparent paradoxes. Here we propose a Szilard engine setup without featuring an explicit Maxwell's demon. In a demonless Szilard engine, the acquisition of which-side information is not required, but the erasure and related heat dissipation still take place implicitly. We explore a quantum Szilard engine considering quantum size effects. We see that insertion of the partition does not localize the particle to one side, instead creating a superposition state of the particle being in both sides. To be able to extract work from the system, particle has to be localized at one side. The localization occurs as a result of quantum measurement on the particle, which shows the importance of the measurement process regardless of whether one uses the acquired information or not. In accordance with Landauer's principle, localization by quantum measurement corresponds to a logically irreversible operation and for this reason it must be accompanied by the corresponding heat dissipation. This shows the validity of Landauer's principle even in quantum Szilard engines without Maxwell's demon.
We present a complete-quantum description of a multiparticle Szilard engine that consists of a working substance and a Maxwell's demon. The demon is modeled as a multilevel quantum system with specific quantum control, and the working substance consists of identical particles obeying Bose-Einstein or Fermi-Dirac statistics. In this description, a reversible scheme to erase the demon's memory by a lower-temperature heat bath is used. We demonstrate that (1) the quantum control of the demon can be optimized for a single-particle Szilard engine so that the efficiency of the demon-assisted thermodynamic cycle could reach the Carnot cycle's efficiency and (2) the low-temperature behavior of the working substance is very sensitive to the quantum statistics of the particles and the insertion position of the partition.
We study the physical mechanism of Maxwell's demon (MD), which helps do extra work in thermodynamic cycles with the heat engine. This is exemplified with one molecule confined in an infinitely deep square potential with a movable solid wall. The MD is modeled as a two-level system (TLS) for measuring and controlling the motion of the molecule. The processes in the cycle are described in a quantum fashion. It is discovered that a MD with quantum coherence or one at a temperature lower than the molecule's heat bath can enhance the ability of the whole working substance, formed by the heat engine plus the MD, to do work outside. This observation reveals that the essential role of the MD is to drive the whole working substance off equilibrium, or equivalently, to work between two heat baths with different effective temperatures. The elaborate studies with this model explicitly reveal the effect of finite size off the classical limit or thermodynamic limit, which contradicts common sense on a Szilard heat engine (SHE). The quantum SHE's efficiency is evaluated in detail to prove the validity of the second law of thermodynamics.
We analyze an engine whose working fluid consists of a single quantum particle, paralleling Szilard's construction of a classical single-particle engine. Following his resolution of Maxwell's Second Law paradox using the latter, which turned on physically instantiating the demon (control subsystem), the quantum engine's design mirrors the classically-chaotic Szilard Map that operates a thermodynamic cycle of measurement, thermal-energy extraction, and memory reset. Focusing on the thermodynamic costs to observe and control the particle and comparing these in the quantum and classical limits, we detail the thermodynamic tradeoffs behind Landauer's Principle for information-processing-induced thermodynamic dissipation in the quantum and classical regimes. In particular, and as found with the classical engine, we show that the sum of the thermodynamic costs over a cycle obeys a generalized Landauer Principle, exactly balancing energy extraction from the heat bath. Thus, the quantum engine obeys the Second Law. However, the quantum engine does so via substantially different mechanisms: classically measurement and erasure determine the thermodynamics, while in the quantum implementation the cost of partition insertion is key.
Generally, quantum heat engines driven by Gibbs reservoirs achieve their maximum work and efficiency only in quasi-static processes, a constraint that hampers practical applications due to the resulting vanishing power output. To address this fundamental limitation, we propose a finite-time quantum Otto information engine (OIE) driven by a Maxwell's demon paired with a single Gibbs reservoir. We demonstrate that the demon's measurement and feedback control can preserve quantum coherence to extract coherent work, while harnessing quantum internal friction as a work source. Consequently, the OIE can produce work by only modulating the eigenstates of the Hamiltonian, and surpass the quasi-static limits of its conventional counterpart in the work output and the efficiency, which accounts for the energetic cost of the demon. Notably, the OIE can achieve near-perfect efficiency alongside positive work extraction in the rapid-driving regime.
Abstract We study the thermodynamic performance of a finite-time non-regenerative quantum Stirling-like cycle used as a heat engine. We consider specifically the case in which the working substance (WS) is a two-level system (TLS). The Stirling cycle is made of two isochoric transformations separated by a compression and an expansion stroke during which the WS is in contact with a thermal reservoir. To describe these two strokes we derive a non-Markovian master equation which allows to study the real-time dynamics of a driven open quantum system with arbitrary fast driving. Following the real-time dynamics of the WS using this master equation, the endpoints of the isotherms can deviate from the equilibrium thermal states. The role of this deviation in the performance of the heat engine is addressed. We found that the finite-time dynamics and thermodynamics of the cycle depend non-trivially on the different time scales at play. In particular, driving the WS at a time scale comparable to the resonance time of the bath enhances the performance of the cycle and allows for an efficiency higher than the efficiency of the quasistatic cycle, but still below the Carnot bound. However, by adding thermalization of the WS with the baths at the end of compression/expansion processes one recovers the conventional scenario in which efficiency decreases by speeding up the processes. In addition, the performance of the cycle is dependent on the compression/expansion speeds asymmetrically, which suggests new freedom in optimizing quantum heat engines. The maximum output power and the maximum efficiency are obtained almost simultaneously when the real-time endpoints of the compression/expansion processes are considered instead of the equilibrium thermal endpoint states. However, the net extractable work always declines by speeding up the drive.