Quadratic light-matter interactions are nonlinear couplings such that quantum emitters interact with photonic or phononic modes exclusively via the exchange of excitation pairs.Implementable with atomic and solid-state systems, these couplings lead to a plethora of phenomena that have been characterized in the context of cavity QED, where quantum emitters interact with localized bosonic modes.Here, we explore quadratic interactions in a waveguide QED setting, where quantum emitters interact with propagating fields confined in a one-dimensional environment.We develop a general scattering theory under the Markov approximation and discuss paradigmatic examples for spontaneous emission and scattering of biphoton states.Our analytical and semianalytical results unveil fundamental differences with respect to conventional waveguide QED systems, such as the spontaneous emission frequency-entangled photon pairs or the full transparency of the emitter to single-photon inputs.This unlocks new opportunities in quantum information processing with propagating photons.As a striking example, we show that a single quadratically coupled emitter can implement a two-photon logic gate with unit fidelity, circumventing a no-go theorem derived for conventional waveguide-QED interactions.
Quadratic light-matter interactions are nonlinear couplings such that quantum emitters interact with photonic or phononic modes exclusively via the exchange of excitation pairs.Implementable with atomic and solid-state systems, these couplings lead to a plethora of phenomena that have been characterized in the context of cavity QED, where quantum emitters interact with localized bosonic modes.Here, we explore quadratic interactions in a waveguide QED setting, where quantum emitters interact with propagating fields confined in a one-dimensional environment.We develop a general scattering theory under the Markov approximation and discuss paradigmatic examples for spontaneous emission and scattering of biphoton states.Our analytical and semianalytical results unveil fundamental differences with respect to conventional waveguide QED systems, such as the spontaneous emission frequency-entangled photon pairs or the full transparency of the emitter to single-photon inputs.This unlocks new opportunities in quantum information processing with propagating photons.As a striking example, we show that a single quadratically coupled emitter can implement a two-photon logic gate with unit fidelity, circumventing a no-go theorem derived for conventional waveguide-QED interactions.
Waveguide quantum electrodynamics (waveguide QED) describes the interaction between an electromagnetic field confined to a one-dimensional waveguide with atom-like quantum emitters close by. The characteristics of these kinds of systems are the possibility for strong and even ultrastrong interactions between the photonic and atom-like systems, and practically infinite range interactions between the emitters. These properties are valuable for a wide range of quantum optical applications, like quantum communication, quantum networks and quantum metrology. In this thesis we focus on two challenges in quantum optics, namely the generation and scattering of multiphoton states. In the first part of this thesis we demonstrate how waveguide QED systems can be exploited for the generation of multiphoton states, in particular of single-mode Fock states and superpositions thereof as well as multi-mode photonic states with metrological applications. The basic setup for this goal is an ensemble of quantum emitters coupled to a waveguide. In the so-called atomic mirror configuration symmetric Dicke states (or a superposition thereof) decay superradiantly to the ground state and emit the desired multiphoton state, which can be efficiently collected at the ends of the waveguide. We propose various protocols for the preparation of these Dicke states in waveguide QED systems and characterize the emitted photonic state. It turns out that in the low excitation regime, that is, if the number of photons is much lower than the ensemble size, the photonic state is emitted into a single mode. This single-mode structure is fundamental to current proposals for applications in quantum metrology with optical interferometers. Outside the low excitation regime, a multi-mode photonic state is generated, for which the metrological capabilities were unknown. We were able to show that these states still lead to quantum-enhanced optical interferometry. In the second part of this thesis we demonstrate how the scattering of multiphoton states on a single quantum emitter coupled to the waveguide can be used for testing the limits of the light-matter interaction strength. In particular, we investigate systems in the so-called ultrastrong coupling regime, where the coupling strength between the photonic and atom-like system is of the order of the emitter's transition energy. In this regime, many methods and approximations used in quantum optics, especially the Rotating Wave Approximation, break down and one needs to develop new analytical and numerical methods to study these systems. One approach is the so-called polaron Transformation. We show how this transformation can be applied for predicting the scattering amplitude of few photons scattering on the emitter. The comparison of these results with numerical simulations using matrix product states shows a good agreement for moderate coupling strengths. Both parts together show that waveguide QED systems are promising candidates for the generation of multiphoton states as well as for the investigation of fundamental limits probed through the scattering of multiphoton states. The latter also finds application in the implementation of photon-photon nonlinearities induced by the interaction with the quantum emitters. Apart from these and many other theoretical predictions, waveguide QED systems are also undergoing rapid progress in experiments. Therefore, we expect these kinds of systems to bring forth several advances in the field of quantum optics.
Strong coupling between light and matter has been demonstrated both in classical cavity quantum electrodynamics (QED) systems and in more recent circuit-QED experiments. This enables the generation of strong nonlinear photon-photon interactions at the single-photon level, which is of great interest for the observation of quantum nonlinear optical phenomena, the control of light quanta in quantum information protocols such as quantum networking, as well as the study of strongly correlated quantum many-body systems using light. Recently, strong coupling has also been realized in a variety of one-dimensional (1D) waveguide- QED experimental systems, which in turn makes them promising candidates for quantum information processing. Compared to cavity-QED systems, there are two new features in waveguide-QED: the existence of a continuum of states and the restricted 1D phase space, which together bring in new physical effects, such as the bound-state effects. This thesis consists of two parts: 1) understanding the fundamental interaction between local quantum objects, such as two-level systems and four-level systems, and photons confined in the waveguide; 2) exploring its implications in quantum information processing, in particular photonic quantum computation and quantum key distribution. First, we demonstrate that by coupling a two-level system (TLS) or three/fourlevel system to a 1D continuum, strongly-correlated photons can be generated inside the waveguide. Photon-photon bound states, which decay exponentially as a function of the relative coordinates of photons, appear in multiphoton scattering processes. As a result, photon bunching and antibunching can be observed in the photon-photon correlation function, and nonclassical light source can be generated on demand. In the case of an N-type four-level system, we show that the effective photon-photon interaction mediated by the four-level system, gives rise to a variety of nonlinear optical phenomena, including photon blockade, photon-induced tunneling, and creation of single-photon states and photon pairs with a high degree of spectral entanglement, all in the absence of a cavity. However, to enable greater quantum networking potential using waveguide- QED, it is important to study systems having more than just one TLS/qubit. We develop a numerical Green function method to study cooperative effects in a system of two qubits coupled to a 1D waveguide. Quantum beats emerge in photon-photon correlations, and persist to much longer time scales because of non-Markovian processes. In addition, this system can be used to generate a high-degree of long-distance entanglement when one of the two qubits is driven by an on-resonance laser, further paving the way toward waveguide-QED-based quantum networks. Furthermore, based on our study of light-matter interactions in waveguide- QED, we investigate its implications in quantum information processing. First, we study quantum key distribution using the sub-Possonian single photon source obtained by scattering a coherent state off a two-level system. The rate for key generation is found to be twice as large as for other sources. Second, we propose a new scheme for scalable quantum computation using flying qubits--propagating photons in a one-dimensional waveguide--interacting with matter qubits. Photonphoton interactions are mediated by the coupling to a three- or four-level system, based on which photon-photon -phase gates (Controlled-NOT) can be implemented for universal quantum computation. We show that high gate fidelity is possible given recent dramatic experimental progress in superconducting circuits and photonic-crystal waveguides. The proposed system can be an important building block for future on-chip quantum networks.
Understanding physical properties of quantum emitters strongly interacting with quantized electromagnetic modes is one of the primary goals in the emergent field of waveguide quantum electrodynamics (QED). When the light-matter coupling strength is comparable to or even exceeds energies of elementary excitations, conventional approaches based on perturbative treatment of light-matter interactions, two-level description of matter excitations, and photon-number truncation are no longer sufficient. Here we study in and out of equilibrium properties of waveguide QED in such nonperturbative regimes on the basis of a comprehensive and rigorous theoretical approach using an asymptotic decoupling unitary transformation. We uncover several surprising features ranging from symmetry-protected many-body bound states in the continuum to strong renormalization of the effective mass and potential; the latter may explain recent experiments demonstrating cavity-induced changes in chemical reactivity as well as enhancements of ferromagnetism or superconductivity. To illustrate our general results with concrete examples, we use our formalism to study a model of coupled cavity arrays, which is relevant to experiments in superconducting qubits interacting with microwave resonators or atoms coupled to photonic crystals. We examine the relation between our results and delocalization-localization transition in the spin-boson model; notably, we point out that a reentrant transition can occur in the regimes where the coupling strength becomes the dominant energy scale. We also discuss applications of our results to other problems in different fields, including quantum optics, condensed matter physics, and quantum chemistry.
Quantum emitters coupled to a waveguide are a paradigm of quantum optics, whose essential properties are described by waveguide quantum electrodynamics (QED). We study the possibility of observing the typical features of the conventional waveguide QED scenario in a system where the role of the waveguide is played by a one-dimensional subwavelength atomic array. For the role of emitters, we propose to use antisymmetric states of atomic dimers---a pair of closely spaced atoms---as effective two-level systems, which significantly reduces the effect of free-space spontaneous emission. We solve the dynamics of the system both when the dimer frequency lies inside and when it lies outside the band of modes of the array. Along with well-known phenomena of collective emission into the guided modes and waveguide-mediated long-range dimer-dimer interactions, we uncover significant non-Markovian corrections which arise from both the finiteness of the array and through retardation effects.
Abstract The future of quantum information processing hinges on chip-scale nanophotonics, specifically cavity QED and waveguide QED. One of the foremost processes underpinning quantum photonic technologies is the phenomenon of Rabi oscillations, which manifests when a qubit is irradiated by an intense laser source. Departing from the conventional semiclassical framework, we explore the more general, quantum theoretical case where the optical excitation takes the form of a multiphoton Fock state, and the qubit couples to a continuum of radiation modes. By employing the real-space formalism, we analytically explore the scattering dynamics of the photonic Fock state as it interfaces with a two-level emitter. The resulting amplitude for atomic excitation features a linear superposition of various independent scattering events that are triggered by the potential of sequential, time-delayed photon absorptions and emissions. The lowest-order excitation event, initiated by the stochastic scattering of one of the several photons, appropriately characterizes the dynamics in a weak-field environment. This event is complemented by a multitude of higher-order scattering events ensuing from repeated atom–photon interactions. The temporal evolution of the qubit excitation in our configuration closely mirrors the semiclassical predictions, particularly in the strong-pumping limit where Rabi oscillations unfold. Notably, this compatibility with the semiclassical paradigm transcends beyond the strong-excitation regime and applies both to the weak-driving and large-detuning limits. In a nutshell, our analysis extends the existing results on quantum Rabi oscillations pertinent to single-mode cavity QED, to the multimode, waveguide-QED configurations wherein flying photons are the information carriers. Additionally, we delve into the dynamics of pulsed wave packets, shedding light on the potential to substantially enhance excitation efficiency, even in scenarios involving just a few photons. Beyond their theoretical merit, these findings should hold practical relevance for future Fock-state-based quantum computing and emerging waveguide-integrated photonic technologies such as those involving superconducting circuitry.
Light-matter interaction at the single-quantum level is the heart of many regimes of high fundamental importance to modern quantum technologies. Strong interaction of a qubit with a single photon of an electromagnetic field mode is described by the cavity/circuit electrodynamics (QED) regime which is one of the most advanced platforms for quantum computing. The opposite regime of the waveguide QED, where qubits interact with a continuum of modes in an infinite one-dimensional space, is also at the focus of recent research revealing novel quantum phenomena. Despite the demonstration of several key features of waveguide QED, the transition from an experimentally realizable finite-size system to the theoretically assumed infinite device size is neither rigorously justified nor fully understood. In this paper, we formulate a unifying theory which under a minimal set of standard approximations accounts for physical boundaries of a system in all parameter domains. Considering two qubits in a rectangular waveguide which naturally exhibits a low frequency cutoff we are able to account for infinite number of modes and obtain an accurate description of the waveguide transmission, a life-time of a qubit-photon bound state and the exchange interaction between two qubit-photon bounds states. For verification, we compare our theory to experimental data obtained for two superconducting qubits in a rectangular waveguide demonstrating how the infinite size limit of waveguide QED emerges in a finite-size system. Our theory can be straightforwardly extended to other waveguides such as the photonic crystal and coupled cavity arrays.