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arXiv:2303.05524 · PRX Quantum

Quantum Dichotomies and Coherent Thermodynamics beyond First-Order Asymptotics

Patryk Lipka-Bartosik, Christopher T. Chubb, Joseph M. Renes, Marco Tomamichel, Kamil Korzekwa

Published May 15, 2024• 4 citations
arXivHTMLPDF

Abstract

We address the problem of exact and approximate transformation of quantum dichotomies in the asymptotic regime, i.e., the existence of a quantum channel E mapping ρ1⊗n into ρ2⊗Rnn with an error ϵn (measured by trace distance) and σ1⊗n into σ2⊗Rnn exactly, for a large number n . We derive second-order asymptotic expressions for the optimal transformation rate Rn in the small-, moderate-, and large-deviation error regimes, as well as the zero-error regime, for an arbitrary pair (ρ1,σ1) of initial states and a commuting pair (ρ2,σ2) of final states. We also prove that for σ1 and σ2 given by thermal Gibbs states, the derived optimal transformation rates in the first three regimes can be attained by thermal operations. This allows us, for the first time, to study the second-order asymptotics of thermodynamic state interconversion with fully general initial states that may have coherence between different energy eigenspaces. Thus, we discuss the optimal performance of thermodynamic protocols with coherent inputs and describe three novel resonance phenomena allowing one to significantly reduce transformation errors induced by finite-size effects. What is more, our result on quantum dichotomies can also be used to obtain, up to second-order asymptotic terms, optimal conversion rates between pure bipartite entangled states under local operations and classical communication. Published by the American Physical Society 2024

DOI
10.1103/prxquantum.5.020335

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We address the problem of exact and approximate transformation of quantum dichotomies in the asymptotic regime, i.e., the existence of a quantum channel E mapping ρ1⊗n into ρ2⊗Rnn with an error ϵn (measured by trace distance) and σ1⊗n into σ2⊗Rnn exactly, for a large number n . We derive second-order asymptotic expressions for the optimal transformation rate Rn in the small-, moderate-, and large-deviation error regimes, as well as the zero-error regime, for an arbitrary pair (ρ1,σ1) of initial states and a commuting pair (ρ2,σ2) of final states. We also prove that for σ1 and σ2 given by thermal Gibbs states, the derived optimal transformation rates in the first three regimes can be attained by thermal operations. This allows us, for the first time, to study the second-order asymptotics of thermodynamic state interconversion with fully general initial states that may have coherence between different energy eigenspaces. Thus, we discuss the optimal performance of thermodynamic protocols with coherent inputs and describe three novel resonance phenomena allowing one to significantly reduce transformation errors induced by finite-size effects. What is more, our result on quantum dichotomies can also be used to obtain, up to second-order asymptotic terms, optimal conversion rates between pure bipartite entangled states under local operations and classical communication. Published by the American Physical Society 2024
Quantum resource theories provide a mathematically rigorous way of understanding the nature of various quantum resources. An important problem in any quantum resource theory is to determine how quantum states can be converted into each other within the physical constraints of the theory. The standard approach to this problem is to study approximate or probabilistic transformations. Here, we investigate the intermediate regime, providing limits on both, the fidelity and the probability of state transformations. We derive limitations on the transformations, which are valid in all quantum resource theories, by providing bounds on the maximal transformation fidelity for a given transformation probability. As an application, we show that these bounds imply an upper bound on the asymptotic rates for various classes of states under probabilistic transformations. We also show that the deterministic version of the single copy bounds can be applied for drawing limitations on the manipulation of quantum channels, which goes beyond the previously known bounds of channel manipulations. Furthermore, we completely solve the question of stochastic-approximate state conversion via local operations and classical communication in the following two cases: (i) Both initial and target states are pure bipartite entangled states of arbitrary dimensions. (ii) The target state is a two-qubit entangled state and the initial state is a pure bipartite state.
What are the fundamental limits and advantages of using a catalyst to aid thermodynamic transformations between quantum systems? In this paper, we answer this question by focusing on transformations between energy-incoherent states under the most general energy-conserving interactions among the system, the catalyst, and a thermal environment. The sole constraint is that the catalyst must return unperturbed and uncorrelated with the other subsystems. More precisely, we first upper bound the set of states to which a given initial state can thermodynamically evolve (the catalyzable future) or from which it can evolve (the catalyzable past) with the help of a strict catalyst. Secondly, we derive lower bounds on the dimensionality required for the existence of catalysts under thermal process, along with bounds on the catalyst's state preparation. Finally, we quantify the catalytic advantage in terms of the volume of the catalyzable future and demonstrate its utility in an exemplary task of generating entanglement and cooling a quantum system using thermal resources. Published by the American Physical Society 2024
We introduce the resource-theoretic free energy of a quantum channel as the maximal work extractable from the channel as its output equilibrates to a thermal state and its reference system remains locally intact. It is proportional to the relative entropy between the given channel and the absolutely thermal channel. It attains a clear operational meaning as twice the asymptotic rates of athermality distillation and formation under Gibbs-preserving superchannels, which map one absolutely thermal channel to another for a given bath, thereby revealing the asymptotic reversibility of the resource theory of athermality for quantum channels. Consequently, we establish that the optimal extractable work in converting one channel to another through the asymptotic athermality distillation and formation tasks equals the difference in their free energies. We call this optimal work the thermodynamic work capacity of channel conversion. Quantum information processing and computing fundamentally concern the manipulation and transformation of quantum channels, which encompass quantum states, their transformations, and measurements. A quantitative characterization of the optimal thermodynamic work gain or expenditure in quantum information processing constitutes a key step toward formulating thermodynamics of quantum processes.
Information processing, quantum or classical, relies on channels transforming multiple input states to different corresponding outputs. Previous research has established bounds on the thermodynamic resources required for such operations, but no protocols have been specified for their optimal implementation. For the insightful case of qubits, we here develop explicit protocols to transform two states in an energetically optimal manner. We first prove conditions on the feasibility of carrying out such transformations at all, and then quantify the achievable work extraction. Our results uncover a fundamental incompatibility between the thermodynamic ideal of slow, quasistatic processes and the information-theoretic requirement to preserve distinguishability between different possible output states. Published by the American Physical Society 2024
We study channel interconversion under non-signalling superchannels, where the asymptotic conversion rate is given by the ratio of the channel capacities. Our main result determines the second-order expansion of the optimal target length. Namely, when each channel has a single capacity-achieving dispersion, the coefficient is given by the inverse sesquinormal distribution, with parameters determined by the capacities and dispersions. The result extends state-dichotomy theory to channels: one superchannel approximates the target uniformly over inputs and maps every reference channel whose output is independent of its input to another such channel. As in state dichotomies, there are finite-error resonances where the second-order term vanishes, leaving an O(log⁡n)O(\log n)O(logn) remainder. Crucially, our new characterization cannot be obtained by concatenating channel coding and simulation protocols [Cao {\it et al.}~IEEE Trans.~Inf.~Theory (2024)]. Instead, the proof combines comparisons of binary hypothesis testing experiments with uniform Gaussian estimates and a construction that uses symmetry within type classes to satisfy the non-signalling constraints. Shared randomness assistance already suffices at first order, but we show that its second-order behaviour can differ strictly from the non-signalling case.
We study entanglement distillation and dilution of states and channels in the single-shot regime. With the help of a recently introduced conversion distance, we provide compact closed-form expressions for the dilution and distillation of pure states and show how this can be used to efficiently calculate these quantities on multiple copies of pure states. These closed-form expressions also allow us to obtain second-order asymptotics. We then prove that the ε-single-shot entanglement cost of mixed states is given exactly in terms of an expression containing a suitably smoothed version of the conditional max-entropy. For pure states, this expression reduces to the smoothed max-entropy of the reduced state, for which we provide a closed-form expression. Analogously, we provide a closed-form expression for the smoothed min-entropy and connect it to the ε-single-shot distillable entanglement. Based on these results, we bound the single-shot entanglement cost of channels. We then turn to the one-way entanglement distillation of states and channels and provide bounds in terms of a quantity we denote coherent information of entanglement.