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arXiv:2303.04977 · Physical review. E

Quantum ergotropy and quantum feedback control

Kenta Koshihara, Kazuya Yuasa

Published Jun 8, 2023• 12 citations
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Abstract

We study the energy extraction from and charging to a finite-dimensional quantum system by general quantum operations. We prove that the changes in energy induced by unital quantum operations are limited by the ergotropy and charging bounds for unitary quantum operations. This implies that, in order to break the ergotropy bound for unitary quantum operations, one needs to perform a quantum operation with feedback control. We also show that the ergotropy bound for unital quantum operations, applied to initial thermal equilibrium states, is tighter than the inequality representing the standard second law of thermodynamics without feedback control.

DOI
10.1103/physreve.107.064109

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We study the energy extraction from and charging to a finite-dimensional quantum system by general quantum operations. We prove that the changes in energy induced by unital quantum operations are limited by the ergotropy and charging bounds for unitary quantum operations. This implies that, in order to break the ergotropy bound for unitary quantum operations, one needs to perform a quantum operation with feedback control. We also show that the ergotropy bound for unital quantum operations, applied to initial thermal equilibrium states, is tighter than the inequality representing the standard second law of thermodynamics without feedback control.
We discuss the interplay between thermodynamics and magic resources in closed quantum dynamics by introducing Clifford ergotropy, the amount of extractable energy under the restriction to Clifford operations. We provide universal upper bounds on Clifford ergotropy, which decrease with increasing magic as quantified by the infinite-order filtered stabilizer Rényi entropy. We demonstrate the utility of this bound for one- and two-qubit systems, with the latter exhibiting a notable transition in the control landscape of Clifford ergotropy. Finally, we show that our analysis has nontrivial consequences even for many-body systems where the exact optimization is generally difficult to perform, including a form of the second law of thermodynamics under Clifford operations for typical quantum states.
We show that the maximum extractable work (ergotropy) from a quantum many-body system is constrained by "local athermality" of an initial state and "local entropy decrease" brought about by quantum operations. The obtained universal upper bound on ergotropy implies that the eigenstate thermalization hypothesis prohibits work extraction from energy eigenstates by means of finite-time unitary operations. This no-go property implies that Planck's principle, a form of the second law of thermodynamics, holds even for pure quantum states. Our result bridges two independently studied concepts of quantum thermodynamics, the second law and thermalization, via "intrasystem" correlations in many-body systems as a resource for work extraction.
The study of feedback control inspired by Maxwell's demon has yielded fundamental insights into the relationship between thermodynamics and information. However, its fully quantum formulation, where the controller holds quantum side information that cannot be treated as a classical record, remains incomplete. In this paper, we establish fundamental no-go limits for thermodynamic state conversion while allowing quantum side information to be fed back to the system coherently. From two basic operational principles respected by all physically admissible feedback-control schemes, we derive the tightest possible bounds on the single-shot work of formation and extractable work for arbitrary quantum systems conditioned on arbitrary quantum side information. In the asymptotic limit, these bounds yield a generalized second law of thermodynamics with quantum feedback, governed by a conditional free energy. We further show that this generalized second law is consistent with the traditional second law once the acquisition, processing, and reset of side information are accounted for. These results extend information thermodynamics to the fully quantum regime and provide precise thermodynamic meanings for the negativity of single-shot conditional entropies.
In classical thermodynamics, the optimal work is given by the free energy difference, what according to the result of Skrzypczyk et al. can be generalized for individual quantum systems. The saturation of this bound, however, requires an infinite bath and ideal energy storage that is able to extract work from coherences. Here we present the tight Second Law inequality, defined in terms of the ergotropy (rather than free energy), that incorporates both of those important microscopic effects - the locked energy in coherences and the locked energy due to the finite-size bath. The former is solely quantified by the so-called control-marginal state, whereas the latter is given by the free energy difference between the global passive state and the equilibrium state. Furthermore, we discuss the thermodynamic limit where the finite-size bath correction vanishes, and the locked energy in coherences takes the form of the entropy difference. We supplement our results by numerical simulations for the heat bath given by the collection of qubits and the Gaussian model of the work reservoir.
Quantum thermodynamics is often formulated as a theory with constrained access to operations and resources. In this manuscript, we find a closed formula for the Gaussian ergotropy, i.e. the maximum energy that can be extracted from bosonic systems governed by quadratic Hamiltonians by means of Gaussian unitaries only. This formula resembles the well-known eigenvalue-based expression for the standard ergotropy, but is instead formulated using symplectic eigenvalues. We further prove that the Gaussian ergotropy is additive, indicating that the multiple-copy scenario does not benefit from Gaussian entangling operations. Extending our analysis to the relationship between ergotropic and entropic functions, we establish bounds linking entropic measures of Gaussianity to extractable work. Finally, we generalise our framework to open systems by studying the optimal state preparation that minimises the energy output in a Gaussian channel.
Constraints on work extraction are fundamental to our operational understanding of the thermodynamics of both classical and quantum systems. In the quantum setting, finite-time control operations typically generate coherence in the instantaneous energy eigenbasis of the dynamical system. Thermodynamic cycles can, in principle, be designed to extract work from this nonequilibrium resource. Here, we isolate and study the quantum coherent component to the work yield in such protocols. Specifically, we identify a coherent contribution to the ergotropy (the maximum amount of unitarily extractable work via cyclical variation of Hamiltonian parameters). We show this by dividing the optimal transformation into an incoherent operation and a coherence extraction cycle. We obtain bounds for both the coherent and incoherent parts of the extractable work and discuss their saturation in specific settings. Our results are illustrated with several examples, including finite-dimensional systems and bosonic Gaussian states that describe recent experiments on quantum heat engines with a quantized load.