The choice of mathematical representation when describing physical systems is of great consequence, and this choice is usually determined by the properties of the problem at hand. Here we examine the little-known wave operator representation of quantum dynamics and explore its connection to standard methods of quantum dynamics, such as the Wigner phase-space function. This method takes as its central object the square root of the density matrix and consequently enjoys several unusual advantages over standard representations. By combining this with purification techniques imported from quantum information, we are able to obtain a number of results. Not only is this formalism able to provide a natural bridge between phase- and Hilbert-space representations of both quantum and classical dynamics, we also find the wave operator representation leads to semiclassical approximations of both real and imaginary time dynamics, as well as a transparent correspondence to the classical limit. It is then demonstrated that there exist a number of scenarios (such as thermalization) in which the wave operator representation possesses an equivalent unitary evolution, which corresponds to nonlinear real-time dynamics for the density matrix. We argue that the wave operator provides a new perspective that links previously unrelated representations and is a natural candidate model for scenarios (such as hybrids) in which positivity cannot be otherwise guaranteed.
The choice of mathematical representation when describing physical systems is of great consequence, and this choice is usually determined by the properties of the problem at hand. Here we examine the little-known wave operator representation of quantum dynamics and explore its connection to standard methods of quantum dynamics, such as the Wigner phase-space function. This method takes as its central object the square root of the density matrix and consequently enjoys several unusual advantages over standard representations. By combining this with purification techniques imported from quantum information, we are able to obtain a number of results. Not only is this formalism able to provide a natural bridge between phase- and Hilbert-space representations of both quantum and classical dynamics, we also find the wave operator representation leads to semiclassical approximations of both real and imaginary time dynamics, as well as a transparent correspondence to the classical limit. It is then demonstrated that there exist a number of scenarios (such as thermalization) in which the wave operator representation possesses an equivalent unitary evolution, which corresponds to nonlinear real-time dynamics for the density matrix. We argue that the wave operator provides a new perspective that links previously unrelated representations and is a natural candidate model for scenarios (such as hybrids) in which positivity cannot be otherwise guaranteed.
A quantum mechanical representation suitable for studying the time evolution of quantum densities in phase space is proposed and examined in detail. This representation on ℒ2 (2) phase space is based on definitions of the operators P̂ and Q̂ in phase space that satisfy various correspondences for the Liouville equation in classical and quantum phase space, as well as quantum position and momentum ℒ2 (1) spaces. The definitions presented here, P̂=p/2−iℏ∂/∂q and Q̂=q/2+iℏ∂/∂p, are related to definitions that have been recently proposed [J. Chem. Phys. 93, 8862 (1990)]. The resulting quantum phase space representation shares many of the mathematical properties of usual representations in coordinate and momentum spaces. Within this representation, time evolution equations for complex-valued functions (wave functions) and their square magnitudes (distribution functions) are derived, and it is shown that the coordinate and momentum space time evolution equations can be recovered by a simple Fourier projection. The phase space quantum probability conservation equation obtained is a good illustration of the quantization rule that requires one to replace the classical Poisson bracket between the Hamiltonian and the probability density with the quantum commutator between the corresponding operators. The possible classical analogs to quantum probabilities densities are also considered and some of the present results are illustrated for the dynamics of the coherent state.
We discuss a phase space representation of quantum dynamics of systems with many degrees of freedom. This representation is based on a perturbative expansion in quantum fluctuations around one of the classical limits. We explicitly analyze expansions around three such limits: (i) corpuscular or Newtonian limit in the coordinate-momentum representation, (ii) wave or Gross-Pitaevskii limit for interacting bosons in the coherent state representation, and (iii) Bloch limit for the spin systems. We discuss both the semiclassical (truncated Wigner) approximation and further quantum corrections appearing in the form of either stochastic quantum jumps along the classical trajectories or the nonlinear response to such jumps. We also discuss how quantum jumps naturally emerge in the analysis of non-equal time correlation functions. This representation of quantum dynamics is closely related to the phase space methods based on the Wigner-Weyl quantization and to the Keldysh technique. We show how such concepts as the Wigner function, Weyl symbol, Moyal product, Bopp operators, and others automatically emerge from the Feynmann's path integral representation of the evolution in the Heisenberg representation. We illustrate the applicability of this expansion with various examples mostly in the context of cold atom systems including sine-Gordon model, one- and two-dimensional Bose Hubbard model, Dicke model and others.
This work presents a structural reformulation of quantum dynamics based on a scalar coherence functional defined over a general state space. The framework distinguishes two mathematically natural classes of dynamics generated by such a functional:(i) gradient flows, which monotonically increase coherence and correspond to stabilization or selection processes, and(ii) antisymmetric flows, which conserve coherence and generate reversible dynamics. We show that standard unitary quantum mechanics arises as a special case when the state space is a complex Hilbert space, the coherence functional is chosen as the negative energy expectation, and the antisymmetric structure corresponds to the canonical complex structure. In this setting, the Schrödinger equation follows directly from the formalism, without postulating unitarity as an independent axiom. The framework is extended to open systems using the density-operator formalism and completely positive trace-preserving maps. Under standard assumptions (Markovianity, continuity, and semigroup structure), the reduced dynamics takes the Gorini–Kossakowski–Sudarshan–Lindblad form, with dissipative terms interpreted as coherence-stabilizing dynamics. A supporting lemma demonstrates exponential suppression of off-diagonal density matrix elements under dephasing Lindblad operators. Using the Wigner phase-space representation, we further show that conservative coherence dynamics reduces to classical Liouville transport in the semiclassical regime, with quantum corrections governed by the Moyal bracket expansion. This work does not propose a modification of quantum theory. Rather, it offers a structural reorganization of existing formalisms. All results remain fully compatible with standard quantum mechanics while providing a unified perspective on unitary evolution, decoherence, and the emergence of classical behavior. Related work. A companion technical note, Structural Decomposition of SRG Recursion into Flow, Phase, and Closure (Halldórsson & ChatGPT, 2025, Zenodo), develops a discrete dynamical-systems formulation of SRG-style recursion and connects it explicitly to Lemmas 2.5, 2.7, and 2.9 of the present work.
Among the equivalent formulations of quantum mechanics, Heisenberg's matrix mechanics and quantum theory, based on the Schrödinger wave equation, are the most technically advanced.Since the advent of quantum mechanics, these two schemes have provided the mathematical tools and the primary basis for the description of quantum phenomena.The path integral method developed by Dirac and Feynman has important advantages in the quantisation of gauge theories.We discuss here the formulation of quantum mechanics in phase space, known as deformation quantisation.Deformation quantisation uses the Wigner-Weyl association rule (Weyl, 1927(Weyl, , 1929(Weyl, , 1931;;Wigner, 1932) to establish a one-to-one correspondence between the functions in the phase space and the operators in the Hilbert space.Wigner's function appears as the Weyl symbol of the density matrix.A consistent dynamical description of the systems with the help of the Wigner function leads to deformation quantization.A useful formulation of the Wigner-Weyl association rule was proposed by Groenewold (1946) andStratonovich (1957).Groenewold introduced a non-commutative associative -product (star-product) of the functions in the phase space (Groenewold, 1946).The evolution of the quantum systems is determined by the antisymmetric part of the -product (Groenewold, 1946;Moyal, 1949), known as the Moyal bracket.The Moyal bracket represents the quantum deformation of the Poisson bracket.Deformation quantisation preserves many features of classical Hamiltonian dynamics.The formulation of deformation quantisation is based on the Wigner function and the Moyal bracket (i.e., the -product).The Wigner-Weyl association rule is necessary to prove the equivalence of deformation quantisation and the standard formalisms of quantum mechanics.Extensive literature has reported on the formulation of quantum mechanics in the phase space and the -product.We refer the reader to excellent reviews by Bayen et al. (1978a, 1978b), Carruthers & Zachariasen (1983), Balazs & Jennings (1984), Hillery et al. (1983), Karasev & Maslov (1991), and Osborn & Molzahn (1995), where one may find additional references.Wigner's function, as a fundamental object of deformation quantisation, has numerous applications in many-body physics, kinetic theory, collision theory, and quantum chemistry.Transport models, originally created to simulate chemical reactions, have been modified and are widely used to describe heavy-ion collisions.www.intechopen.comSome Applications of Quantum Mechanics 68 Deformation quantisation does not have many recognised successful applications in quantum theory.Recently, attempts have been made to use specific properties of the formalism to investigate semiclassical expansion (Osborn & Molzahn, 1995;McQuarrie et al., 1998) and to calculate the determinants of one-loop operators in field theory (Pletnev & Banin, 1999;Banin et al., 2001) and the high-order corrections to the Bohr-Sommerfeld quantisation rule (Gracia-Saz, 2004;Cargo et al., 2005).Potential applications of deformation quantisation in transport models are presented in this review.Transport models for heavy-ion physics are designed for phenomenological descriptions of the complex dynamics of nuclear collisions.Several types of advanced transport models are based on the Boltzmann-Uhlenbeck-Ueling equations (BUU) (Blaettel et al., 1993), (relativistic) quantum molecular dynamics (QMD/RQMD) (Sorge et al., 1989;Aichelin, 1991;Faessler, 1992), or antisymmetrised molecular dynamics (AQMD) (Feldmeier & Schnack, 1997).These approaches have the correct classical limit and they contain special plug-ins and quantum-mechanical attributes, such as Pauli blocking for binary collisions of fermions.Numerical solutions are implemented through the distribution of test particles (BUU) or centroids of wave packets (QMD, AQMD) for classical trajectories in the phase space.For AQMD, the wave packets are antisymmetrised in their parameters.The transport models provide a solid basis for a phenomenological description of a variety of complex nuclear collisions phenomena.However, quantum coherence effects and non-localities are beyond the scope of these models.The internal consistencies of the approximations in the models remain a subject of debate, promoting further developments (see, for example, papers by Kohler (1995) andFeldmeier &Schnack (1997) and references therein).The most striking feature of the transport models is the depiction of the trajectories in the phase space, which are test particles or centroids of wave packets.The evolution of the system of classical particles can be calculated using standard programs to solve first-order ordinary differential equations (ODEs).At the same time, the evolution of wave functions of many-body systems is a field-theoretic problem with an infinite number of degrees of freedom that cannot be solved either analytically or numerically.Any simulation of many-body quantum dynamics must be based on a concept of trajectories, which is the only attribute allowing access to an approximate description of complex quantum systems.The concept of phase-space trajectories arises naturally in the formalism of deformation quantisation through the Wigner transformation of the operators of the canonical coordinates and momenta in the Heisenberg representation.These trajectories satisfy the quantum version of Hamilton's equations (Osborn & Molzahn, 1995;Krivoruchenko & Faessler, 2006b) and are the characteristics by which the time-dependent Weyl's symbols for the other operators can be determined (Krivoruchenko & Faessler, 2006b;Krivoruchenko et al., 2006c Krivoruchenko et al., , 2007)).In the classical limit, quantum characteristics reduce to classical trajectories.Knowledge of the quantum phase flow, i.e., the quantum trajectories, is equivalent to a complete knowledge of the quantum dynamics.In this chapter, we provide an introduction to deformation quantisation and demonstrate the usefulness of the formalism in solving the evolution problem for many-body systems in terms of semiclassical expansion.We show that, in any fixed order of expansion over the Planck's constant, the evolution problem can be reduced to a statistical-mechanics problem of calculating an ensemble of quantum characteristics in the phase space and their Jacobi fields.In comparison with the corresponding rules of classical statistical mechanics, the rules for computing the probabilities and time-dependent averages of observables are www.intechopen.com
Abstract For present purposes, the first thing to recall about quantum mechanics is that all dynamical quantities, instead of being functions of the location of a system in phase space as in classical mechanics, are now represented by operators in a Hilbert space of quantum states. In particular, the quantum analog of the classical phase space distribution function is the quantum mechanical density matrix. Since this is seldom discussed in introductory texts on either quantum mechanics or statistical mechanics, it may be helpful to summarize some of its basic properties.
The review of new formulation of conventional quantum mechanics where the quantum states are identified with probability distributions is presented. The invertible map of density operators and wave functions onto the probability distributions describing the quantum states in quantum mechanics is constructed both for systems with continuous variables and systems with discrete variables by using the Born's rule and recently suggested method of dequantizer-quantizer operators. Examples of discussed probability representations of qubits (spin-1/2, two-level atoms), harmonic oscillator and free particle are studied in detail. Schrödinger and von Neumann equations, as well as equations for the evolution of open systems, are written in the form of linear classical-like equations for the probability distributions determining the quantum system states. Relations to phase-space representation of quantum states (Wigner functions) with quantum tomography and classical mechanics are elucidated.