Modelling the evolution of a system using stochastic dynamics typically implies a greater subjective uncertainty in the adopted system coordinates as time progresses, and stochastic entropy production has been developed as a measure of this change. In some situations the evolution of stochastic entropy production can be described using an Itô process, but mathematical difficulties can emerge if diffusion in the system phase space is restricted to a subspace of lower dimension. This can arise if there are constants of the motion, for example, or more generally when there are functions of the coordinates that evolve without noise. We discuss such a case for an open three-level quantum system modelled within a framework of Markovian quantum state diffusion and show how the problem of computing the stochastic entropy production in such a situation can be overcome. We go on to illustrate how a nonequilibrium stationary state of the three-level system, with a constant mean production rate of stochastic entropy, can be established under suitable environmental couplings.
Modelling the evolution of a system using stochastic dynamics typically implies a greater subjective uncertainty in the adopted system coordinates as time progresses, and stochastic entropy production has been developed as a measure of this change. In some situations the evolution of stochastic entropy production can be described using an Itô process, but mathematical difficulties can emerge if diffusion in the system phase space is restricted to a subspace of lower dimension. This can arise if there are constants of the motion, for example, or more generally when there are functions of the coordinates that evolve without noise. We discuss such a case for an open three-level quantum system modelled within a framework of Markovian quantum state diffusion and show how the problem of computing the stochastic entropy production in such a situation can be overcome. We go on to illustrate how a nonequilibrium stationary state of the three-level system, with a constant mean production rate of stochastic entropy, can be established under suitable environmental couplings.
We investigate the entropic consequences of the relaxation of an open two-level quantum system towards a thermalised statistical state, using a framework of quantum state diffusion with evolution described by a minimal set of raising and lowering Lindblad operators. We demonstrate that thermalisation is typically accompanied by a persistent non-zero mean rate of change of the environmental component of stochastic entropy production. This thermodynamic signature can be associated with the purification of the reduced density matrix ρ of the randomly evolving state under these dynamics, which may be contrasted with the impurity of the more frequently considered ensemble average of ρ. The system adopts stationary statistics, with zero stochastic entropy production, after a further stage of relaxation once purity has been achieved. We show that apparent pathological mathematical difficulties in the computation of stochastic entropy production emerge in this evolution towards stationarity if ρ is represented using a certain set of coordinates, though these problems can be removed by choosing a different set. We conclude that frameworks for modelling open systems must be carefully selected to provide satisfactory thermodynamic as well as dynamic behaviour.
The reduced density matrix that characterises the state of an open quantum system is a projection from the full density matrix of the quantum system and its environment, and there are many full density matrices consistent with a given reduced version. Without a specification of relevant details of the environment, the time evolution of a reduced density matrix is therefore typically unpredictable, even if the dynamics of the full density matrix are deterministic. With this in mind, we investigate a two-level open quantum system using a framework of quantum state diffusion. We consider the pseudorandom evolution of its reduced density matrix when subjected to an environment-driven process that performs a continuous quantum measurement of a system observable, invoking dynamics that asymptotically send the system to one of the relevant eigenstates. The unpredictability is characterised by a stochastic entropy production, the average of which corresponds to an increase in the subjective uncertainty of the quantum state adopted by the system and environment, given the underspecified dynamics. This differs from a change in von Neumann entropy, and can continue indefinitely as the system is guided towards an eigenstate. As one would expect, the simultaneous measurement of two non-commuting observables within the same framework does not send the system to an eigenstate. Instead, the probability density function describing the reduced density matrix of the system becomes stationary over a continuum of pure states, a situation characterised by zero further stochastic entropy production. Transitions between such stationary states, brought about by changes in the relative strengths of the two measurement processes, give rise to finite positive mean stochastic entropy production. The framework investigated can offer useful perspectives on both the dynamics and irreversible thermodynamics of measurement in quantum systems.
Abstract We investigate the total stochastic entropy production of a two-level bosonic open quantum system under protocols of time dependent coupling to a harmonic environment. These processes are intended to represent the measurement of a system observable, and consequent selection of an eigenstate, whilst the system is also subjected to thermalising environmental noise. The entropy production depends on the evolution of the system variables and their probability density function, and is expressed through system and environmental contributions. The continuous stochastic dynamics of the open system is based on the Markovian approximation to the exact, noise-averaged stochastic Liouville-von Neumann equation, unravelled through the addition of stochastic environmental disturbance mimicking a measuring device. Under the thermalising influence of time independent coupling to the environment, the mean rate of entropy production vanishes asymptotically, indicating equilibrium. In contrast, a positive mean production of entropy as the system responds to time dependent coupling characterises the irreversibility of quantum measurement, and a comparison of its production for two coupling protocols, representing connection to and disconnection from the external measuring device, satisfies a detailed fluctuation theorem.
We investigate stochastic entropy production in a two-level quantum system that performs Rabi oscillations while undergoing quantum measurement brought about by continuous random disturbance by an external measuring device or environment. The dynamics produce quantum Zeno and anti-Zeno effects for certain measurement regimes, and the stochastic entropy production is a measure of the irreversibility of the behaviour. When the strength of the measurement disturbance is time-dependent, the stochastic entropy production separates into three components. Two represent relaxational behaviour, one being specific to systems represented by coordinates that are odd under time reversal symmetry, and a third characterises the nonequilibrium stationary state arising from breakage of detailed balance in the dynamics. The study illustrates how the ideas of stochastic thermodynamics may be applied in similar ways to both quantum and classical systems.
We discuss fundamental features of the local expression for the entropy production rate of the nonequilibrium quantum dynamics of open systems and its relations to memory effects and the spectrum of the generator of the dynamics. Defining the entropy production rate as negative rate of change of the relative entropy with respect to an instantaneous fixed point, it is shown that positivity of the entropy production rate for all possible initial states implies that the real parts of the eigenvalues of the time-local generator for the quantum master equation are always negative. It is further demonstrated that Markovian dynamics, identified as P-divisibility of the quantum dynamical map, implies positivity of entropy production rate, thus providing a kind of generalized second law in the nonequilibrium regime. We also prove by means of the counterexample of a phase covariant quantum master equation that the converse of this statement is not true, i.e., there are non-Markovian dynamics for which the entropy production rate is always positive. Thus, we conclude that the emergence of negative entropy production rates is a sufficient but not necessary condition for non-Markovianity of the quantum dynamics. Finally, we also consider a recently introduced map-based notion of entropy production and show the equivalence between its positivity and Markovianity for general finite-dimensional systems.
Irreversible behavior in open stochastic dynamical systems is quantified by stochastic entropy production, a property that measures the difference in likelihoods of forward and subsequent backward system evolution. But for a closed system, governed by deterministic dynamics, such an approach is not appropriate. Instead, we can consider the difference in likelihoods of forward and "obverse" behavior: the latter being a backward trajectory initiated at the same time as the forward trajectory. Such a comparison allows us to define "dissipation production," an analog of stochastic entropy production. It quantifies the breakage of a property of the evolution termed "obversibility" just as stochastic entropy production quantifies a breakage of reversibility. Both are manifestations of irreversibility. In this study we discuss dissipation production in a quantum system. We consider a simple, deterministic, two-level quantum system characterized by a statistical ensemble of state vectors, and we provide numerical results to illustrate the ideas. We consider cases that both do and do not satisfy an Evans-Searles Fluctuation Theorem for the dissipation production, and hence identify conditions under which the system displays time-asymmetric average behavior: an arrow of time.