Adam DeAbreu, Camille Bowness, A. Alizadeh, Camille Chartrand, Nicholas A. Brunelle, E. R. MacQuarrie, N. R. Lee-Hone, Myles Ruether, M. Kazemi, A. T. K. Kurkjian, S. Roorda, Н.В. Абросимов, H.‐J. Pohl, Michael L. W. Thewalt, Daniel B. Higginbottom, Stephanie Simmons
The performance of modular, networked quantum technologies will be strongly dependent upon the quality of their quantum light-matter interconnects. Solid-state colour centres, and in particular T centres in silicon, offer competitive technological and commercial advantages as the basis for quantum networking technologies and distributed quantum computing. These newly rediscovered silicon defects offer direct telecommunications-band photonic emission, long-lived electron and nuclear spin qubits, and proven native integration into industry-standard, CMOS-compatible, silicon-on-insulator (SOI) photonic chips at scale. Here we demonstrate further levels of integration by characterizing T centre spin ensembles in single-mode waveguides in SOI. In addition to measuring long spin T 1 times, we report on the integrated centres’ optical properties. We find that the narrow homogeneous linewidth of these waveguide-integrated emitters is already sufficiently low to predict the future success of remote spin-entangling protocols with only modest cavity Purcell enhancements. We show that further improvements may still be possible by measuring nearly lifetime-limited homogeneous linewidths in isotopically pure bulk crystals. In each case the measured linewidths are more than an order of magnitude lower than previously reported and further support the view that high-performance, large-scale distributed quantum technologies based upon T centres in silicon may be attainable in the near term.
The performance of modular, networked quantum technologies will be strongly dependent upon the quality of their quantum light-matter interconnects. Solid-state colour centres, and in particular T centres in silicon, offer competitive technological and commercial advantages as the basis for quantum networking technologies and distributed quantum computing. These newly rediscovered silicon defects offer direct telecommunications-band photonic emission, long-lived electron and nuclear spin qubits, and proven native integration into industry-standard, CMOS-compatible, silicon-on-insulator (SOI) photonic chips at scale. Here we demonstrate further levels of integration by characterizing T centre spin ensembles in single-mode waveguides in SOI. In addition to measuring long spin T 1 times, we report on the integrated centres’ optical properties. We find that the narrow homogeneous linewidth of these waveguide-integrated emitters is already sufficiently low to predict the future success of remote spin-entangling protocols with only modest cavity Purcell enhancements. We show that further improvements may still be possible by measuring nearly lifetime-limited homogeneous linewidths in isotopically pure bulk crystals. In each case the measured linewidths are more than an order of magnitude lower than previously reported and further support the view that high-performance, large-scale distributed quantum technologies based upon T centres in silicon may be attainable in the near term.
Implementation of large-scale quantum networks have the potential to augment the capabilities of existing quantum information technologies. By linking quantum processors over photonic channels, future quantum networks could enable applications such as remote quantum sensing, distributed quantum computing, and secure quantum communication. Atomic defects in solids are readily integrated with photonic structures, making them promising candidates for use in quantum networking devices. In particular, the silicon material platform holds great promise due to the technologically mature silicon electronic and photonic industries. The T center defects in silicon possess telecom O-band optical transitions, as well as long-lived electronic and nuclear spins, making it the focus of particular interest. These spin and optical properties of single T centers, together with their accessibility to the existing integrated electronic and photonic technologies, opening the door to modular long-distance quantum networking technologies built on the T center platform. This work outlines the integration of single T centers with a silicon photonic crystal cavity; we observe cavity-enhanced fluorescence emission, resulting in a decay rate enhancement factor of F = 6.89 compared to the bulk emission rate. Through the use of silicon photonic circuits and an angle-polished fiber for light coupling, we achieve a maximum zero phonon line photon outcoupling rate of 73.3 kHz. The design and fabrication of the nanophotonic cavity used in experiment is detailed. This work represents a major step towards use of the silicon T center as a telecom spin-photon interface in future quantum networking applications.
Spin-photon interfaces based on silicon quantum emitters offer a scalable platform for quantum computing and networking. However, achieving coherent photon emission remains a primary challenge due to stringent material quality requirements. To overcome this, we utilise high-purity molecular-beam epitaxy (MBE) to epitaxially incorporate single T centres in silicon-on-insulator (SOI) wafers. We demonstrate single T-centre emission coupled to a nanophotonic waveguide and observe significant suppression of homogeneous broadening, yielding optical linewidths as narrow as 30 MHz using natural silicon for crystal growth. These results establish epitaxial T centres as a robust foundation for coherent spin-photon interfaces in silicon quantum photonics.
Quantum networks represent one of the most promising technologies for the future development of quantum information science (QIS), with broad applications that range from secure communication and distributed quantum computing to enhanced sensing. Solid-state platforms are ideal candidates for the implementation of such quantum networks, since they offer easy accessibility to device integration and spin-photon interfaces capable of processing and storing qubits, as well as connecting remote network nodes by sending photons through optical fibers. In this thesis, we focus on single T centers, which are a novel type of color centers in silicon. This quantum defect stands out as a promising candidate for quantum networking applications due to its telecom optical transition, superior spin performance, and its compatibility with the technologically mature silicon platform. Here, we present our initial studies on single T centers, including the design and fabrication of nanophotonic devices in a silicon-on-insulator (SOI) sample with integrated T centers, and the cavity-enhanced fluorescence emission of single T centers, which have achieved the highest Purcell factor (Pt = 43) to date. Moreover, our experimental and numerical results allow us to determine a lower bound to the T center quantum efficiency of η = 23.4%, which is a key optical parameter for T centers that is largely overlooked in the community. Additionally, we present preliminary bulk spectroscopy work on ensemble T centers. The same setup will be exploited towards the exploration of novel quantum defects in silicon, including the boron-carbon (B-C) complex defect and the Ti+ defect, which are expected to have similar or better optical properties than the T center.
Global quantum networks will benefit from the reliable creation and control of high-performance solid-state telecom photon-spin interfaces. T radiation damage centres in silicon provide a promising photon-spin interface due to their narrow O-band optical transition near 1326 nm and long-lived electron and nuclear spin lifetimes. To date, these defect centres have only been studied as ensembles in bulk silicon. Here, we demonstrate the reliable creation of high concentration T centre ensembles in the 220 nm device layer of silicon-on-insulator (SOI) wafers by ion implantation and subsequent annealing. We then develop a method that uses spin-dependent optical transitions to benchmark the characteristic optical spectral diffusion within these T centre ensembles. Using this new technique, we show that with minimal optimization to the fabrication process high densities of implanted T centres localized $\lesssim$100 nm from an interface display ~1 GHz characteristic levels of total spectral diffusion.
Solid-state quantum light sources offer a scalable pathway for interfacing stationary spin qubits with flying photonic qubits, forming the backbone of future quantum networks. Telecom-band spin-photonic qubits, operating in the 1260-1675 nm wavelength range, are particularly well-suited for long-distance quantum communication due to minimal loss in standard optical fibers. Achieving scalability, however, hinges on fulfilling several stringent criteria: coherent spin-state control, deterministic and indistinguishable single-photon emission, and integration with nanophotonic structures that enhance radiative properties, such as lifetime, coherence, and photon indistinguishability. This study explores the state-of-the-art spin-photonic qubits across solid-state platforms, including diamond color centers, silicon carbide defect centers, quantum dots, and two-dimensional materials. Special attention is given to silicon-based emitters, particularly G, T, C- and Ci-centers, which promise monolithic integration with complementary metal-oxide-semiconductor (CMOS) technology and telecom-band operation. We classify these systems based on spin-photon interface availability, CMOS process compatibility, and emitter scalability. We also discuss recent advances in cavity quantum electrodynamics (cQED), including Purcell enhancement and quality factor engineering in integrated photonic (circuits) environments. The work highlights emerging demonstrations of quantum networking over metropolitan scales and outlines the trajectory toward chip-scale quantum photonic integrated circuits (QPICs). It combines deterministic emitter creation, coherent spin manipulation, and quantum information processing. These developments pave the way for global quantum networks, enabling secure communication, distributed quantum computing, and quantum-enhanced sensing.
The global quantum internet will require long-lived, telecommunications band photon-matter interfaces manufactured at scale. Preliminary quantum networks based upon photon-matter interfaces which meet a subset of these demands are encouraging efforts to identify new high-performance alternatives. Silicon is an ideal host for commercial-scale solid-state quantum technologies. It is already an advanced platform within the global integrated photonics and microelectronics industries, as well as host to record-setting long-lived spin qubits. Despite the overwhelming potential of the silicon quantum platform, the optical detection of individually addressable photon-spin interfaces in silicon has remained elusive. In this work we produce tens of thousands of individually addressable `T centre' photon-spin qubits in integrated silicon photonic structures, and characterize their spin-dependent telecommunications-band optical transitions. These results unlock immediate opportunities to construct silicon-integrated, telecommunications-band quantum information networks.