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arXiv:2209.14012 · Physical review. B./Physical review. B

Enhancement of spin-to-charge conversion of diamond NV centers at ambient conditions using surface electrodes

Liam Hanlon, Michael Olney‐Fraser, Marcus W. Doherty, Lukas Razinkovas

Published Apr 18, 2023• 5 citations
arXivHTMLPDF

Abstract

The nitrogen-vacancy (NV) center in diamond is a heavily studied defect due to its potential applications to quantum metrology and computation, particularly in ambient conditions. The key mechanism to using the NV in any application lies in the ability to read out the spin state of the defect which is typically done optically. The optical contrast is then the key metric for electron spin readout fidelity and one of the key limiting factors in the NV's overall performance. We present a mechanism for high contrast readout using the spin-to-charge conversion mechanism in conjunction with an electrode to improve the spin contrast by altering the NV energy levels relative to the diamond conduction band. Theoretical modeling predicts an optical spin contrast at 42% which would be the highest optical contrast for the NV at room temperature and the technique opens up a range of alternative research pathways for the NV which are discussed.

DOI
10.1103/physrevb.107.134111

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The nitrogen-vacancy (NV) center in diamond is a heavily studied defect due to its potential applications to quantum metrology and computation, particularly in ambient conditions. The key mechanism to using the NV in any application lies in the ability to read out the spin state of the defect which is typically done optically. The optical contrast is then the key metric for electron spin readout fidelity and one of the key limiting factors in the NV's overall performance. We present a mechanism for high contrast readout using the spin-to-charge conversion mechanism in conjunction with an electrode to improve the spin contrast by altering the NV energy levels relative to the diamond conduction band. Theoretical modeling predicts an optical spin contrast at 42% which would be the highest optical contrast for the NV at room temperature and the technique opens up a range of alternative research pathways for the NV which are discussed.
The nitrogen-vacancy (N\mathrm{N}N-VVV) center in diamond has a wide range of potential applications in quantum metrology, communications, and computation. The key to its use lies in how large the optical spin contrast is and the associated fidelity of the spin-state readout. In this paper, we propose a mechanism for improving contrast with a spin-to-charge protocol that relies on the use of an external electrode and cryogenic temperatures to discretize the diamond conduction band for spin-selective resonant photoionization. We use effective-mass theory to calculate the discrete eigenenergies in this system and use them to formulate a spin-to-charge protocol that involves resonant photoionization out of the N\mathrm{N}N-VVV ground state into the diamond conduction band. The major sources of broadening, which guide the design of the experiment, are also addressed. With this mechanism, we calculate an optical spin contrast that and an associated spin-readout fidelity of 85%. This significant improvement can be applied to a number of cryogenic quantum technologies.
We propose and experimentally demonstrate a method to strongly increase the sensitivity of spin measurements on nitrogen-vacancy (NV) centers in diamond, which can be readily implemented in existing quantum sensing experiments. While charge state transitions of this defect are generally considered a parasitic effect to be avoided, we show here that these can be used to significantly increase the NV center's spin contrast, a key quantity for high sensitivity magnetometry and high fidelity state readout. The protocol consists of a two-step procedure, in which the charge state of the defect is first purified by a strong laser pulse, followed by weak illumination to obtain high spin polarization. We observe a relative improvement of the readout contrast by 17 %, and infer a reduction of the initialization error of more than 50 %. The contrast enhancement is accompanied by a beneficial increase of the readout signal. For long sequence durations, typically encountered in high-resolution magnetometry, a measurement speedup by a factor of >1.5 is extracted, and we find that the technique is beneficial for sequences of any duration. Additionally, our findings give detailed insight into the charge and spin polarization dynamics of the NV center, and provide actionable insights for direct optical, spin-to-charge, and electrical readout of solid-state spin centres.
Nanodiamonds containing nitrogen-vacancy (NV) centers offer a versatile platform for sensing applications spanning from nanomagnetism to in vivo monitoring of cellular processes. In many cases, however, weak optical signals and poor contrast demand long acquisition times that prevent the measurement of environmental dynamics. Here, we demonstrate the ability to perform fast, high-contrast optical measurements of charge distributions in ensembles of NV centers in nanodiamonds and use the technique to improve the spin-readout signal-to-noise ratio through spin-to-charge conversion. A study of 38 nanodiamonds with sizes ranging between 20 and 70 nm, each hosting a small ensemble of NV centers, uncovers complex, multiple time scale dynamics due to radiative and nonradiative ionization and recombination processes. Nonetheless, the NV-containing nanodiamonds universally exhibit charge-dependent photoluminescence contrasts and the potential for enhanced spin readout using spin-to-charge conversion. We use the technique to speed up a T 1 relaxometry measurement by a factor of 5.
We demonstrate the optical readout of ensembles of nitrogen-vacancy (NV) center spins in a bulk diamond sample via spin-to-charge conversion. A high power 594 nm laser is utilized to selectively ionize these paramagnetic defects in the mS=0 spin state with a contrast of up to 12%. In comparison to the conventional 520 nm spin readout, the spin-to-charge-conversion-based readout provides a higher signal-to-noise ratio, with tenfold sensing measurement speedup for millisecond long pulse sequences. This level of performance was achieved for an NV− ionization of only 25%, limited by the ionization and readout laser powers. These observations pave the way to a range of high-sensitivity metrology applications where the use of NV− ensembles in bulk diamond has proven useful, including sensing and imaging of target materials overlaid on the diamond surface.
Efficient readout of individual electronic spins associated with atomlike impurities in the solid state is essential for applications in quantum information processing and quantum metrology. We demonstrate a new method for efficient spin readout of nitrogen-vacancy (NV) centers in diamond. The method is based on conversion of the electronic spin state of the NV to a charge-state distribution, followed by single-shot readout of the charge state. Conversion is achieved through a spin-dependent photoionization process in diamond at room temperature. Using NVs in nanofabricated diamond beams, we demonstrate that the resulting spin readout noise is within a factor of 3 of the spin projection noise level. Applications of this technique for nanoscale magnetic sensing are discussed.