This paper is aimed at studying the thermodynamic properties of quantum gases confined to a torus. To do that, we consider noninteracting gases within the grand canonical ensemble formalism. In this context, fermions and bosons are taken into account and the calculations are properly provided in both analytical and numerical manners. In particular, the system turns out to be sensitive to the topological parameter under consideration: the winding number. Furthermore, we also derive a model in order to take into account interacting quantum gases. To corroborate our results, we implement such a method for two different scenarios: a ring and a torus.
This paper is aimed at studying the thermodynamic properties of quantum gases confined to a torus. To do that, we consider noninteracting gases within the grand canonical ensemble formalism. In this context, fermions and bosons are taken into account and the calculations are properly provided in both analytical and numerical manners. In particular, the system turns out to be sensitive to the topological parameter under consideration: the winding number. Furthermore, we also derive a model in order to take into account interacting quantum gases. To corroborate our results, we implement such a method for two different scenarios: a ring and a torus.
In this work, we study the thermodynamic functions of quantum gases confined to spaces of various shapes, namely, a sphere, a cylinder and an ellipsoid. We start with the simplest situation, namely, a spinless gas treated within the canonical ensemble framework. As a next step, we consider noninteracting gases (fermions and bosons) with the usage of the grand canonical ensemble description. For this case, the calculations are performed numerically. We also observe that our results may possibly be applied to Bose–Einstein condensate and to helium dimer. Moreover, the bosonic sector, independently of the geometry, acquires entropy and internal energy greater than for the fermionic case. Finally, we also devise a model allowing us to perform analytically the calculations in the case of interacting quantum gases, and, afterwards, we apply it to a cubical box.
We analyze the general relation between canonical and grand canonical ensembles in the thermodynamic limit. We begin our discussion by deriving, with an alternative approach, some standard results first obtained by Kac and coworkers in the late 1970s. Then, motivated by the Bose-Einstein condensation (BEC) of trapped gases with a fixed number of atoms, which is well described by the canonical ensemble and by the recent groundbreaking experimental realization of BEC with photons in a dye-filled optical microcavity under genuine grand canonical conditions, we apply our formalism to a system of non-interacting Bose particles confined in a two-dimensional harmonic trap. We discuss in detail the mathematical origin of the inequivalence of ensembles observed in the condensed phase, giving place to the so-called grand canonical catastrophe of density fluctuations. We also provide explicit analytical expressions for the internal energy and specific heat and compare them with available experimental data. For these quantities, we show the equivalence of ensembles in the thermodynamic limit.
Bosonic atoms confined in optical lattices are described by the Bose-Hubbard model and can exist in two different phases, Mott insulator or superfluid, depending on the strength of the system parameters. In the vicinity of the phase boundary, there are degeneracies that occur between every two adjacent Mott lobes. Because of this, nondegenerate perturbation theory fails to give meaningful results for the condensate density: it predicts a phase transition in a point of the phase diagram where no transition occurs. Motivated by this, we develop two different degenerate perturbative methods to solve the degeneracy-related problems. Moreover, we study the one-dimensional repulsively interacting Bose gas under harmonic confinement, with special attention to the asymptotic behavior of the momentum distribution, which is a universal k−4 decay characterized by the Tan's contact. The latter constitutes a direct signature of the short-range correlations in such an interacting system and provides valuable insights about the role of the interparticle interactions. We investigate the system constituted of N interacting particles in the strongly interacting limit. In such a regime, the strong interparticle interaction makes the bosons behave similarly to the ideal Fermi gas. Because of the difficulty in analytically solving the system for N particles at finite interaction, the Tonks-Girardeau regime provides a favorable scenario to probe the contact. Therefore, we are able to provide an analytical formula for the Tan's contact. Furthermore, we analyze the scaling properties of the Tan's contact in terms of N in the high-temperature regime as well as in the strongly interacting regime. Finally, we compare our analytical calculations of the Tan's contact to quantum Monte Carlo simulations and discuss some fundamental differences between the canonical and the grand-canonical ensembles.
Abstract Chapter 11 presents a statistical mechanical treatment of the quantum ideal gases, i.e., the ideal Boltzmann, fermion, and boson gases. The discussion begins with the microscopic description and the solution of the eigenvalue problem for a quantum ideal gas. It is argued that calculating the partition function is most readily accomplished in the grand canonical ensemble using a second-quantized formulation. When the particles are distinguishable, the equation of state is identical to that of a classical ideal gas. For fermions and bosons, however, the problem of computing thermodynamic properties is significantly more complex and can only be solved exactly in certain limits. Away from these limits approximations are needed and are discussed in detail. The relevant distributions - the Fermi-Dirac and Bose-Einstein distributions are derived. The local density approximation of density functional theory is derived for the ideal electron gas. For the ideal boson gas, the phenomenon of Bose-Einstein condensation is discussed
In this work, improvements are introduced to the current models of the ideal Fermi gas and the ideal Bose gas by incorporating the quantum nature of phase space, which is directly linked to the uncertainty principle. These improved models build upon the recently developed concepts of quantum phase space (QPS) and the QPS representation of quantum mechanics. The Hamiltonian operator for a gas particle and its eigenstates are first determined, and quantum statistical mechanics is used to derive the thermodynamic properties of the ideal gas. Analytic expressions for thermodynamic quantities—including the grand canonical potential, particle number, internal energy, von Neumann entropy, and pressure—are derived, along with the corresponding thermodynamic equations of state for both bosons and fermions. These corrections are particularly significant at low temperatures and in confined volumes, where quantum effects related to system geometry, such as shape and size, become significant. The results also establish a direct link between thermodynamic functions and the quantum statistical variances of momentum. Importantly, the improved models recover well-known classical relations of the ideal gas in the high-temperature and large-volume limits, ensuring consistency with classical physics. By addressing quantum corrections and their thermodynamic implications, this work provides a foundation for further applications in nanoscale systems, quantum gases, low-temperature physics, ultracold physics, and astrophysics.
Following a recent experimental study [Wenz et al. Science 342, 457 (2013)] on the achievement of the thermodynamic limit in a system of one-dimensional (1D) fermions, the project aims to investigate theoretically a similar problem for 1D Bose gases. By considering a system of bosons confined in a 1D harmonic trap and interacting with a single impurity, the plan is to calculate the binding energy of the impurity as the number of bosons in the bath is increased. The analysis will be performed by varying both the coupling strength of the bath and the interspecies interactio