Conversion of chemical energy into mechanical work is the fundamental mechanism of several natural phenomena at the nanoscale, like molecular machines and Brownian motors. Quantum mechanical effects are relevant for optimizing these processes and to implement them at the atomic scale. This paper focuses on engines that transform chemical work into mechanical work through energy and particle exchanges with thermal sources at different chemical potentials. Irreversibility is introduced by modeling the engine transformations with finite-time dynamics generated by a time-dependent quantum master equation. Quantum degenerate gases provide maximum efficiency for reversible engines, whereas the classical limit implies small efficiency. For irreversible engines, both the output power and the efficiency at maximum power are much larger in the quantum regime than in the classical limit. The analysis of ideal homogeneous gases grasps the impact of quantum statistics on the above performances, which are expected to persist in the presence of interactions and more general trapping. The performance dependence on different types of Bose-Einstein condensates (BECs) is also studied. The BECs under consideration are standard BECs with a finite fraction of particles in the ground state, and generalized BECs where eigenstates with parallel momenta, or those with coplanar momenta, are macroscopically occupied according to the confinement anisotropy. Quantum gases are therefore a resource for enhanced performances of converting chemical into mechanical work.
Conversion of chemical energy into mechanical work is the fundamental mechanism of several natural phenomena at the nanoscale, like molecular machines and Brownian motors. Quantum mechanical effects are relevant for optimizing these processes and to implement them at the atomic scale. This paper focuses on engines that transform chemical work into mechanical work through energy and particle exchanges with thermal sources at different chemical potentials. Irreversibility is introduced by modeling the engine transformations with finite-time dynamics generated by a time-dependent quantum master equation. Quantum degenerate gases provide maximum efficiency for reversible engines, whereas the classical limit implies small efficiency. For irreversible engines, both the output power and the efficiency at maximum power are much larger in the quantum regime than in the classical limit. The analysis of ideal homogeneous gases grasps the impact of quantum statistics on the above performances, which are expected to persist in the presence of interactions and more general trapping. The performance dependence on different types of Bose-Einstein condensates (BECs) is also studied. The BECs under consideration are standard BECs with a finite fraction of particles in the ground state, and generalized BECs where eigenstates with parallel momenta, or those with coplanar momenta, are macroscopically occupied according to the confinement anisotropy. Quantum gases are therefore a resource for enhanced performances of converting chemical into mechanical work.
Abstract Thermodynamic geometry provides a physically transparent framework to describe thermodynamic processes in meso- and micro-scale systems that are driven by slow variations of external control parameters. Focusing on periodic driving for thermal machines, we extend this framework to ideal quantum gases. To this end, we show that the standard approach of equilibrium physics, where a grand-canonical ensemble is used to model a canonical one by fixing the mean particle number through the chemical potential, can be extended to the slow driving regime in a thermodynamically consistent way. As a key application of our theory, we use a Lindblad-type quantum master equation to work out a dynamical model of a quantum many-body engine using a harmonically trapped Bose-gas. Our results provide a geometric picture of the Bose–Einstein condensate-induced power enhancement that was previously predicted for this type of engine on the basis of an endoreversible model (Myers et al 2022 New J. Phys. 24 025001). Using an earlier derived universal trade-off relation between power and efficiency as a benchmark, we further show that the Bose-gas engine can deliver significantly more power at given efficiency than an equally large collection of single-body engines. Our work paves the way for a more general thermodynamic framework that makes it possible to systematically assess the impact of quantum many-body effects on the performance of thermal machines.
We theoretically investigate the finite-time performance of a quantum thermochemical engine utilizing a harmonically trapped one-dimensional (1D) Bose gas in the quasicondensate regime as the working fluid. The proposed engine operates in an Otto cycle, where the unitary work strokes are simulated through a quench of the interatomic interactions of the 1D Bose gas. In the work strokes, the working fluid is treated as a closed quantum many-body system that undergoes dynamic evolution, beginning from an initial thermal equilibrium state at a nonzero temperature. On the other hand, during the thermalization strokes, the working fluid is treated as an open many-body quantum system in diffusive contact with a thermal reservoir, allowing particle exchange alongside the transfer of heat. Using a c-field approach, we demonstrate that the engine's operation is enabled by the chemical work done on the working fluid through the flow of particles from the hot reservoir. We examine the finite-time performance of the proposed quantum thermochemical engine in two extreme regimes: (i) the out-of-equilibrium regime (sudden quench), which yields near-maximum power (due to fast driving of the system) while compromising efficiency, and (ii) the quasistatic (near-adiabatic) limit, which approaches maximum efficiency but generates zero power output due to slow driving of the system. Notably, we show that using chemical work allows the engine to achieve efficiencies close to the near-maximum (quasistatic) limit, even in the out-of-equilibrium regime, while maintaining high power output. Thus, in the out-of-equilibrium operational regime, our proposed engine provides a favorable trade-off between efficiency and power output. We also draw connections to previous research, particularly the case of an adiabatic engine cycle operating at zero temperature. We show that this zero-temperature scenario establishes an upper bound on the efficiency and work of our proposed thermochemical engine operating at nonzero temperatures.
Bose-Einstein condensation is a quintessential characteristic of Bose systems. We investigate the finite-time performance of an endoreversible quantum Brayton heat engine operating with an ideal Bose gas with a finite number of particles confined in a d-dimensional harmonic trap. The working medium of these engines may work in the condensation, noncondensation, and near-critical point regimes, respectively. We demonstrate that the existence of the phase transition during the cycle leads to enhanced engine performance by increasing power output and efficiencies corresponding to maximum power and maximum efficient power. We also show that the quantum engine working across the Bose-Einstein condensation in N-particle Bose gas outperforms an ensemble of independent single-particle heat engines. The difference in the machine performance can be explained in terms of the behavior of specific heat at constant pressure near the critical point regime.
Abstract Heat engines convert thermal energy into mechanical work both in the classical and quantum regimes1. However, quantum theory offers genuine non-classical forms of energy, different from heat, which so far have not been exploited in cyclic engines. Here we experimentally realize a quantum many-body engine fuelled by the energy difference between fermionic and bosonic ensembles of ultracold particles that follows from the Pauli exclusion principle2. We employ a harmonically trapped superfluid gas of6Li atoms close to a magnetic Feshbach resonance3that allows us to effectively change the quantum statistics from Bose–Einstein to Fermi–Dirac, by tuning the gas between a Bose–Einstein condensate of bosonic molecules and a unitary Fermi gas (and back) through a magnetic field4–10. The quantum nature of such a Pauli engine is revealed by contrasting it with an engine in the classical thermal regime and with a purely interaction-driven device. We obtain a work output of several 106vibrational quanta per cycle with an efficiency of up to 25%. Our findings establish quantum statistics as a useful thermodynamic resource for work production.
It was reported that, if and only if the specific heat, correlation length, and dynamical exponents α,ν and z, fulfill the condition α−zν>0, the phase transitions can enable a quantum heat engine to approach Carnot efficiency at finite power. We start our analysis via a different approach in which the effects of interaction and fluctuations on the Hamiltonian of a trapped dilute Bose gas belonging to the same universality as XY model. Based on models of quantum Otto heat engines, we find the general expression of the efficiency which includes the correction due to interaction and fluctuations at the critical point, and show that, near the Bose-Einstein-condensation point with α−zν<0, energy fluctuations could enable attaintment of the Carnot efficiency with nonvanishing power. Such quantum heat engines can also be realized by changing the shape of the trap confining the ideal and weakly interacting Bose gas during the adiabatic processes of the cycle. These quantum heat engines working with the trapped Bose gases, which are based on techniques of cooling Bose condensates and could be realizable at present technology.
The development of the theory of thermodynamics dates back nearly two centuries, to when the need arose to comprehend and enhance the performance of a novel technology of that era, the heat engine. Extending the classical concepts related to the properties of heat and work into the quantum realm forms the foundation of an emerging field of research known as quantum thermodynamics. To unify the disparate theories of classical thermodynamics and quantum mechanics, a thoroughly developed theoretical framework is necessary. Quantum heat engines provide a fundamental platform for this purpose. Many-body quantum heat engines, in particular, can provide important insights into the potential utilisation of exotic quantum phenomena, such as entanglement and quantum coherence, for building quantum devices that can surpass their classical counterparts in performance. One-dimensional (1D) Bose gases are a paradigmatic example of an interacting quantum many-body system that can be used as a versatile platform for building heat engines to test the thermodynamic theories in the quantum regime. The versatility of this platform comes through the routine experimental realisability of 1D Bose gases, with precise control of their internal and external properties, such as the strength of inter-atomic interactions and external confinement, and the presence of quantum many-body effects. In recent years, there has been an increased focus on exploiting the unique properties of ultracold atomic gases to realize many-body quantum heat engines. Despite this heightened attention and the resulting significant advances at the level of theoretical proposals, experimental feasibility and practical utilization of such engines remains at its infancy. Achieving significant advances at the experimental level requires a deeper understanding of the fundamental components of quantum-gas heat engines. Motivated by this goal, in this thesis we propose a novel and experimentally realistic quantum many-body heat engine that operates in an Otto cycle and uses a weakly interacting harmonically trapped 1D Bose gas as a working fluid. To execute work during the work strokes, we use a quench of the strength of interparticle interactions; when the quench is sudden with respect to the longitudinal dynamics, it maximises the power output. The interaction-induced work strokes are implemented by treating the working fluid as an isolated quantum many-body system undergoing a dynamical evolution starting from a finite temperature thermal equilibrium state. Furthermore, to optimize the performance of this interaction-driven quantum Otto cycle in an experimental scenario, we undertake a comprehensive numerical investigation of the dynamics of the system-reservoir coupling during the heat transfer strokes. We model the heat transfer strokes by treating the working substance as an open quantum many-body system that is coupled to a reservoir.After providing an overview of recent advances in the field of quantum thermodynamics and the background theory of 1D Bose gases in Chapters 1 and 2 we present the main results of this thesis in Chapters 3, 4 and 5. In Chapter 3, we study the individual interaction-induced work strokes of the Otto cycle with a weakly interacting 1D Bose gas as the working fluid. We evaluate the instantaneity of the sudden quench, specifically, identifying the minimum timescales required to perform the sudden quench of the interaction strength without invoking the transverse dynamics. Knowledge of these timescales enables us to perform the sudden quench in an experimental setting while ensuring that the system retains its 1D characteristics and the theory of 1D Bose gas is applicable. Additionally, we determine the time scales governing the opposite scenario of near-adiabatic quench which corresponds to minimum irreversible work in the engine cycle and hence maximum efficiency. This will help us benchmark the sudden quench engine's performance compared to a nearly ideal (near-adiabatic) scenario corresponding to maximum efficiency.Next, in Chapter 4, we analyze the heat transfer strokes of the Otto cycle, where the system is coupled to a reservoir. Using the c-field approach, we simulate the coupling dynamics of the system with both finite and infinite-size reservoirs. During the heat transfer stroke of the quantum Otto cycle, we treat the working fluid as an open quantum many-body system that is in thermal and diffusive contact with another quantum many-body system serving as the reservoir. In our real-time dynamical simulations of the engine strokes, we use a c-field approach based on the stochastic projected Gross-Pitaevskii equation. This approach enables us to treat both the working fluid and the hot and cold reservoirs as independent quantum many-body systems with chemical potential and temperature imbalances. To model the heat transfer strokes of such an engine with a finite-size reservoir, we use a tunnel-coupled model of two quasicondensates that treats both the system and the reservoir microscopically. Our analysis incorporates the impact of both finite-time operation and finite-size reservoirs in the engine cycle to gain a deeper understanding of the operational feasibility of such engines. Our results indicate that, in contrast to the common assumption of near-instantaneous heat transfer between the system and the reservoir, the thermalisation time of the system during these heat transfer strokes is non-negligible when compared to the duration of work strokes even in the near-adiabatic quench. This observation holds true even in the case of coupling the system with an infinite reservoir during the heat transfer strokes. Moreover, we demonstrate that for a finite-size reservoir, the initial dynamics (namely fast initial energy transfer) in the tunnel-coupled model of two quasicondensates can be leveraged to reduce the total driving time and hence increase the power output of the engine. Finally, in Chapter 5, we explore an alternate protocol that involves performing chemical work on the system during the heat transfer strokes to boost the efficiency and power output of the quantum Otto engines with a 1D Bose gas as a working fluid. We compare the performance of the sudden quench engine with an engine driven by a near-adiabatic and a finite-time quench of the interaction strength with respect to the longitudinal dynamics. We then conclude the thesis by summarising our main findings and presenting open questions for future work in the final chapter, Chapter 6.