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arXiv:2208.04034 · New Journal of Physics

Activation of thermal states by coherently controlled thermalization processes

Kyrylo Simonov, Saptarshi Roy, Tamal Guha, Zoltán Zimborás, Giulio Chiribella

Published Jun 18, 2025• 10 citations
arXivHTMLPDF

Abstract

Abstract Thermalization processes degrade the states of any working medium, turning any initial state into a passive state from which no work can be extracted. Recently, it has been shown that this degradation can be avoided if two identical thermalization processes take place in coherently controlled order, in a scenario known as the quantum SWITCH. In some situations, control over the order even enables work extraction when the medium was initially in a passive state. This activation phenomenon, however, is subject to a limitation: to extract non-zero work, the initial temperature of the medium should be less than half of the temperature of the reservoirs. Here we analyze this limitation, showing that it still holds true even when the medium interacts with N ⩾ 2 reservoirs in a coherently-controlled order. Then, we show that the limitation can be lifted when the medium and the control systems are initially correlated. In particular, when the medium and control are entangled, work extraction becomes possible for every initial value of the local temperature of the medium.

DOI
10.1088/1367-2630/ade5c4

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Abstract Thermalization processes degrade the states of any working medium, turning any initial state into a passive state from which no work can be extracted. Recently, it has been shown that this degradation can be avoided if two identical thermalization processes take place in coherently controlled order, in a scenario known as the quantum SWITCH. In some situations, control over the order even enables work extraction when the medium was initially in a passive state. This activation phenomenon, however, is subject to a limitation: to extract non-zero work, the initial temperature of the medium should be less than half of the temperature of the reservoirs. Here we analyze this limitation, showing that it still holds true even when the medium interacts with N ⩾ 2 reservoirs in a coherently-controlled order. Then, we show that the limitation can be lifted when the medium and the control systems are initially correlated. In particular, when the medium and control are entangled, work extraction becomes possible for every initial value of the local temperature of the medium.
We characterize the impact that the application of two maps in a quantum-controlled order has on the process of work extraction via unitary cycles and its optimization. The control is based on the quantum switch model that applies maps in an order not necessarily compatible with the underlying causal structure and, in principle, can be implemented experimentally. First, we show that the activation of quantum maps through the quantum switch model always entails a non-negative gain in ergotropy compared to their consecutive application. We also establish a condition that the maps should fulfill in order to achieve a nonzero ergotropic gain. We then perform a thorough analysis of maps applied to a two-level system and provide general conditions for achieving a positive gain on the incoherent part of ergotropy. Our results are illustrated with several examples and applied to qubit and ddd-dimensional quantum systems. In particular, we demonstrate that a nonzero work can be extracted from a system thermalized by two coherently controlled reservoirs.
Abstract Allowing the order of quantum operations to exist in superposition is known to open new routes for thermodynamic tasks. We investigate a quantum heat engine where energy exchanges are driven by generalized measurements, and the sequence of these operations is coherently controlled in a superposition of causal orders. Our analysis explores how initial correlations between the working medium and the controller affect the engine’s performance. Considering uncorrelated, classically correlated, and entangled initial states, we show that entanglement enables the superposed causal order (SCO) to generate coherence in the working medium, thereby enhancing work extraction and efficiency beyond the separable and uncorrelated cases. Finally, we present a proof-of-principle simulation on the IBM Quantum Experience platform, realizing a quantum switch of two measurement channels with tunable strengths and experimentally confirming the predicted efficiency enhancement enabled by correlation-assisted SCO.
Indefinite causal order (ICO), in which the order of quantum operations is placed in a coherent superposition, has been demonstrated to enhance various information-processing tasks. Here, we investigate its impact on the thermodynamic processes generated by thermalizing quantum channels. We consider a two-level system interacting with two thermal baths under a quantum SWITCH, with the channel order controlled coherently by an ancillary qubit. We derive closed-form expressions for the effective inverse temperature βfβ_fβf​ of the postselected system state for both identical and distinct bath temperatures, and identify the control-qubit parameters that maximize heating or cooling. Our analysis reveals how the diagonal and coherent components of the control-qubit state contribute separately to the temperature shift, and how their interplay enables departures from the thermal response attainable under protocols with a definite causal order within the thermodynamic setting considered here. Bath asymmetry enhances these effects, while reduced purity of the control qubit state suppresses them. These results provide a systematic framework for assessing SWITCH-based thermalization in the setting of indefinite causal order, and identify control-qubit coherence as a tunable resource.
In recent years, many works have explored possible advantages of indefinite causal order, with the main focus on its controlled implementation known as quantum switch. In this paper, we tackle advantages in quantum thermodynamics, studying whether quantum switch is capable of activating a passive state, either alone or with extra resources (active control state) and/or operations (measurement of the control system). By disproving the first possibility and confirming the second one, we show that quantum switch is not a thermodynamic resource in the discussed context, though it can facilitate work extraction given external resources. We discuss our findings by considering specific examples: a qubit system subject to rotations around the x and y axes in the Bloch sphere, as well as general unitaries from the U(2) group; and the system as a quantum harmonic oscillator with displacement operators, as well as with a combination of displacement and squeeze operators.
The quantum switch has seen multiple applications in quantum information and thermodynamical tasks. As it is constructed by placing two quantum channels in a coherent superposition of alternating causal orders, a composition known as indefinite causal order, these enhancements are often attributed to this indefinite causality and coherent superposition. However, as recent works have shown that the quantum switch also features non-Markovian effects that can contribute to the enhancement of communication capacities and work extraction, we attempt to show in this work that these non-Markovian effects can also enhance heat extraction tasks. In particular, we compare the quantum switch to the superposition of independent channels where two quantum channels are placed in a superposition, which have no non-Markovian effects, and show that the quantum switch can only outperform the superposition of independent channels in the prethermalization regimes, which also depends on the presence and amount of non-Markovianity. Our work reveals that positive heat extraction is still possible even when the working body is at a higher temperature than the interacting baths, allowing us to construct a refrigeration cycle utilizing this feature.
The Mpemba effect (ME)—where hot systems cool faster than colder ones—has intrigued both classical and quantum thermodynamics. Compared to classical systems, quantum systems add complexity due to quantum correlations. Recent works have explored anomalous relaxation and Mpemba-like effects in several quantum systems, considering isolated systems at zero temperature or open systems in contact with reservoirs under Markovian or non-Markovian dynamics. However, these models typically assume an initial unentangled system–bath state, overlooking the role of initial system–environment correlations. Here we propose a type of quantum ME, distinct from the strong ME, originating solely from initial system–bath entanglement. It is shown that the degree of initial entanglement significantly influences the early relaxation dynamics, with certain conditions causing backflow and retarded thermalization. As an example, we investigate the spontaneous emission of a two-level atom in a photonic waveguide at zero temperature, where an initial atom-photon entangled state results in delayed relaxation and a pronounced ME. These findings highlight the crucial role of quantum correlations in thermalization processes and open new avenues for identifying and engineering quantum Mpemba phenomena. Controlling relaxation dynamics through system–environment entanglement may have potential applications in quantum thermal machines, state initialization protocols, and quantum information processing, where precise control over thermalization is essential.