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arXiv:2207.05238 · Physical review. B./Physical review. B

Origin of the Coulomb pseudopotential

Tao Wang, Xiansheng Cai, Kun Chen, Boris V. Svistunov, Nikolay V. Prokof'ev

Published Apr 27, 2023• 11 citations
arXivHTMLPDF

Abstract

We address the outstanding problem of electron pairing in the presence of strong Coulomb repulsion at small to moderate values of the Coulomb parameter, ${r}_{s}\ensuremath{\lesssim}2$, and demonstrate that the pseudopotential framework is fundamentally biased and uncontrolled. Instead, one has to break the net result into two distinctively different effects: the Fermi liquid renormalization factor and the change in the effective low-energy coupling. The latter quantity is shown to behave nonmonotonically with an extremum at ${r}_{s}\ensuremath{\approx}0.75$. Within the random-phase approximation, Coulomb interaction starts to enhance the effective pairing coupling at ${r}_{s}>2$, and the suppression of the critical temperature is entirely due to the renormalized Fermi liquid properties. Leading vertex corrections change this picture only quantitatively. Our results call for radical reconsideration of the widely accepted repulsive pseudopotential approach and show the need for precise microscopic treatment of Coulomb interactions in the problem of superconducting instability.

DOI
10.1103/physrevb.107.l140507

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We address the outstanding problem of electron pairing in the presence of strong Coulomb repulsion at small to moderate values of the Coulomb parameter, rs\ensuremath≲2{r}_{s}\ensuremath{\lesssim}2rs​\ensuremath≲2, and demonstrate that the pseudopotential framework is fundamentally biased and uncontrolled. Instead, one has to break the net result into two distinctively different effects: the Fermi liquid renormalization factor and the change in the effective low-energy coupling. The latter quantity is shown to behave nonmonotonically with an extremum at rs\ensuremath≈0.75{r}_{s}\ensuremath{\approx}0.75rs​\ensuremath≈0.75. Within the random-phase approximation, Coulomb interaction starts to enhance the effective pairing coupling at rs>2{r}_{s}>2rs​>2, and the suppression of the critical temperature is entirely due to the renormalized Fermi liquid properties. Leading vertex corrections change this picture only quantitatively. Our results call for radical reconsideration of the widely accepted repulsive pseudopotential approach and show the need for precise microscopic treatment of Coulomb interactions in the problem of superconducting instability.
Motivation With few exceptions [131] it is widely accepted that the conventional Bardeen–Cooper–Schrieffer (BCS) theory [12] and its intermediate-coupling Eliashberg extension [14] do not suffice to explain high-temperature superconductivity. As shown in the preceding chapters the true origin of high-temperature superconductivity could be found in a proper combination of the bare Coulomb repulsion with the bare electron–phonon interaction in the framework of the many-body polaron theory [51] beyond the BCS–Eliashberg approximation. Nevertheless some researchers have maintained that the repulsive electron–electron interaction alone should provide pairing at high temperatures without phonons despite substantial experimental evidence that the EPI is an important player and needs to be included in the successful theory of high- T c superconductivity. Following the original proposal by P. W. Anderson, many authors [22, 74] argued that the electron–electron interaction in high-temperature superconductors was strong but repulsive providing high T c without phonons via superexchange and/or spin fluctuations in the d -wave pairing channel ( l = 2). A motivation for this concept can be found in the earlier works by Kohn and Luttinger (KL) [132, 133] who showed that the Cooper pairing of fermions with any weak repulsion was possible since the two-particle interaction induced by many-body effects is attractive for pairs with large orbital momenta, l ≫ 1.
We study the Cooper instability in jellium model in the controlled regime of small to intermediate values of the Coulomb parameter ${r}_{s}\ensuremath{\le}2$. We confirm that superconductivity naturally emerges from purely repulsive interactions described by the Kukkonen-Overhauser vertex function. By employing the implicit renormalization approach and the discrete Lehmann representation we reveal that even in the small-rs{r}_{s}rs​ limit, the dominant mechanism behind Cooper instability is based on dynamic screening of the Coulomb interaction---accurately captured by the random phase approximation, whereas the Kohn-Luttinger contribution is negligibly small and, thus, not relevant.
Near a quantum critical point in a metal, a strong fermion-fermion interaction, mediated by a soft boson, acts in two different directions: it destroys fermionic coherence and it gives rise to an attraction in one or more pairing channels. The two tendencies compete with each other. We analyze a class of quantum critical models, in which momentum integration and the selection of a particular pairing symmetry can be done explicitly, and the competition between non-Fermi liquid and pairing can be analyzed within an effective model with dynamical electron-electron interaction $V({\mathrm{\ensuremath{\Omega}}}_{m})\ensuremath{\propto}1/{|{\mathrm{\ensuremath{\Omega}}}_{m}|}^{\ensuremath{\gamma}}$ (the $\ensuremath{\gamma}$ model). In this paper, the first in the series, we consider the case T=0T=0T=0 and $0<\ensuremath{\gamma}<1$. We argue that tendency to pairing is stronger, and the ground state is a superconductor. We argue, however, that a superconducting state is highly nontrivial as there exists a discrete set of topologically distinct solutions for the pairing gap ${\mathrm{\ensuremath{\Delta}}}_{n}({\ensuremath{\omega}}_{m})$ ($n=0,1,2,...,\ensuremath{\infty}$). All solutions have the same spatial pairing symmetry, but differ in the time domain: ${\mathrm{\ensuremath{\Delta}}}_{n}({\ensuremath{\omega}}_{m})$ changes sign nnn times as a function of Matsubara frequency ${\ensuremath{\omega}}_{m}$. The n=0n=0n=0 solution ${\mathrm{\ensuremath{\Delta}}}_{0}({\ensuremath{\omega}}_{m})$ is sign preserving and tends to a finite value at ${\ensuremath{\omega}}_{m}=0$, like in BCS theory. The $n=\ensuremath{\infty}$ solution corresponds to an infinitesimally small $\mathrm{\ensuremath{\Delta}}({\ensuremath{\omega}}_{m})$, which oscillates down to the lowest frequencies as $\mathrm{\ensuremath{\Delta}}({\ensuremath{\omega}}_{m})\ensuremath{\propto}|{\ensuremath{\omega}}_{m}{|}^{\ensuremath{\gamma}/2}cos[2\ensuremath{\beta}\phantom{\rule{0.16em}{0ex}}log(|{\ensuremath{\omega}}_{m}|/{\ensuremath{\omega}}_{0})]$, where $\ensuremath{\beta}=O(1)$ and ${\ensuremath{\omega}}_{0}$ is of order of fermion-boson coupling. As a proof, we obtain the exact solution of the linearized gap equation at T=0T=0T=0 on the entire frequency axis for all $0<\ensuremath{\gamma}<1$, and an approximate solution of the nonlinear gap equation. We argue that the presence of an infinite set of solutions opens up a new channel of gap fluctuations. We extend the analysis to the case where the pairing component of the interaction has additional factor 1/N1/N1/N and show that there exists a critical Ncr>1{N}_{cr}>1Ncr​>1, above which superconductivity disappears, and the ground state becomes a non-Fermi liquid. We show that all solutions develop simultaneously once NNN gets smaller than Ncr{N}_{cr}Ncr​.
Strange metal behavior is traditionally associated with an underlying putative quantum critical point at zero temperature. However, in many correlated metals, e.g., high-Tc{T}_{c}Tc​ cuprate superconductors, strange metallicity persists at low temperatures over an extended range of microscopic parameters, suggesting the existence of an underlying quantum critical phase, whose possible physical origins remain poorly understood. Systematic investigations of physical scenarios giving rise to such a critical, non-Fermi liquid (NFL) phase are therefore crucial to better understand this puzzling behavior. In a previous study [Bashan et al., Phys. Rev. Lett. 132, 236501 (2024)], we considered a solvable large-NNN model consisting of itinerant electrons coupled to local two-level systems (TLSs) via spatially random interactions, inspired by the possibility of emergent metallic glassiness due to frustrated competing orders, and found that the system hosts an NFL phase with tunable exponents at intermediate couplings. In this paper, we expand our investigation to the following: (i) We study the extent to which this NFL phase is generic by considering various deformations of our theory, including coupling of electrons to multiple operators of the TLSs and arbitrarily directed TLS fields. We find that the physical picture obtained in Bashan et al. [Phys. Rev. Lett. 132, 236501 (2024)] qualitatively persist in a wide region of parameter space, showcasing the robustness of the NFL phase. (ii) We analyze the superconducting instability caused by the coupling of TLSs to electrons, and find a rich structure, including quantum critical pairing associated with the NFL phase and conventional BCS-like pairing in the weak and strong coupling limits. (iii) We elaborate on the analysis of Bashan et al. [Phys. Rev. Lett. 132, 236501 (2024)], including single-particle, transport, and thermodynamic properties.
The renormalization of the electron-phonon interaction by strong electronic correlations is studied using a one-band Hubbard model with infinite repulsion and nearest (t model) and nearest and second-nearest (tt\ensuremath{'} model) neighbor hopping terms and an on-site electron-phonon coupling. Using Hubbard's X operators and an extension from 2 to N degrees of freedom for the electrons the leading contributions for the electron self-energy and the vertex function in 1/N and the electron-phonon coupling constant are given and numerically evaluated for a square lattice. We find that the momentum dependence of the vertex function depends strongly on doping: For large dopings it is rather weak, with decreasing doping it becomes more and more pronounced leading to a strong reduction of the vertex at larger momentum transfers until, for very small dopings, the vertex essentially consists of a forward scattering peak with a width proportional to the doping. This behavior occurs both in the t and the tt\ensuremath{'} models and also in one dimension where analytic expressions are derived. Correlation effects also change ${\mathrm{\ensuremath{\alpha}}}^{2}$F in general: The full-symmetric component ${\mathrm{\ensuremath{\alpha}}}^{2}$F1{\mathit{F}}_{1}F1​ is in the t model somewhat, in the tt\ensuremath{'} model rather strongly suppressed, especially near half-filling; the other symmetry components ${\mathrm{\ensuremath{\alpha}}}^{2}$Fi{\mathit{F}}_{\mathit{i}}Fi​ with i=2,...,5 increase strongly with decreasing doping and are of similar magnitude as ${\mathrm{\ensuremath{\alpha}}}^{2}$F1{\mathit{F}}_{1}F1​ near half-filling.Including also direct Coulomb repulsion nontrivial symmetries such as d wave become more stable than the s-wave order parameter below a critical value for the doping even for the considered phonon-mediated superconductivity. Most dramatic, however, is the quenching of the resistivity due to electron-phonon scattering both in the t and the tt\ensuremath{'} models at intermediate and small dopings. This result may explain the absence of phonon features in the experimental transport coefficients of high-Tc{\mathit{T}}_{\mathit{c}}Tc​ compounds. \textcopyright{} 1996 The American Physical Society.
Superconductivity results from an instability of the Fermi surface---contour of poles of the single-particle propagator---to an infinitesimally small attraction between electrons. Here, we instead discuss the analogous problem on a model Luttinger surface, or contour of zeros of the Green function. At zero temperature $(\ensuremath{\beta}\ensuremath{\rightarrow}\ensuremath{\infty})$ and a critical interaction strength $({u}_{c\ensuremath{\infty}})$ characterized by the residue of self-energy pole, we find that the pair susceptibility diverges leading to a superconducting instability. We evaluate the pair fluctuation partition function and find that the spectral density in the normal state has an interaction-driven, power-law $\frac{1}{\sqrt{\ensuremath{\omega}}}$ type, van-Hove singularity (vHS), indicating non-Fermi liquid (NFL) physics. Crucially, in the strong coupling limit $(\ensuremath{\beta}u\ensuremath{\gg}1)$, the leading-order fluctuation free-energy terms in the normal state of this NFL-SC transition resembles the equivalent [O(1)]\left[O(1)\right][O(1)] terms of the Sachdev-Ye-Kitaev (SYK) model. This free-energy contribution takes a simple form $\ensuremath{-}\ensuremath{\beta}F=\ensuremath{\beta}{u}_{c\ensuremath{\infty}}\ensuremath{-}\ensuremath{\gamma}\phantom{\rule{0.16em}{0ex}}\text{ln}\left(\ensuremath{\beta}{u}_{c\ensuremath{\infty}}\right),$ where $\ensuremath{\gamma}$ is a constant equal to 12\frac{1}{2}21​. Weak impurity scattering $(\ensuremath{\tau}\ensuremath{\gg}{\ensuremath{\beta}}^{\ensuremath{-}1})$ leaves the low-energy spectral density unaffected but leads to an interaction-driven enhancement of superconductivity. Our results shed light on the role played by order-parameter fluctuations in providing the key missing link between Mott physics and strongly coupled toy models exhibiting gravity duals.